Direct electrochemical investigations of 17-electron complexes of CpM(CO)3 · (M = Mo, W, and Cr)

Inorganic Chemistry

Volumn 35, Issue 13, 1996, Pages 4017-4022

  Barbini, Denis C ^a   Tanner, Pamela S ^a   Francone, Todd D ^a   Furst, Kenneth B ^a   Jones Jr , Wayne E ^a  

^a BINGHAMTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002642857     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951303a     Document Type: Article

References (50)

1. (a) Organometallic Radical Processes; Trogler, W. C., Ed.; Elsevier: New York, 1990
2. (b) Astrac, D. Chem Rev. 1988, 88, 1189.
3. (c) Kaim, W. Coord. Chem. 1987, 76, 187.
4. (d) Geoffrey, G. L.; Wrighton, M. S Organometallic Photochemistry; Academic Press: New York, 1979
5. Tyler, D. R. In Organometallic Radical Processes; Trogler, W. C., Ed.; Elsevier: New York, 1990; p 338.
6. Baird, M. C. In Organometallic Radical Processes; Trogler, W. C., Ed ; Elsevier: New York, 1990; p 49.
7. Baird, M. C. Chem. Rev. 1988, 88, 1217.
8. Brown, T. L. In Organometallic Radical Processes; Trogler, W. C., Ed.; Elsevier: New York, 1990; p 67.
9. Meyer, T J.; Caspar, J. V. Chem. Rev. 1985, 85, 187.
10. (a) Scott, S. L.; Espenson, J. H.; Zhu, Z. J. Am. Chem. Soc. 1993, 115, 1789.
11. (b) Knorr, J. R.; Brown, T. L. J. Am. Chem. Soc. 1993, 115, 4087.
12. (c) Van Vlierberge, B. A.; Abrahamson, H. B, J. Photochem. Photobiol. 1990, 52, 69.
13. (a) Trogler, W. C. In Organometallic Radical Processes, Trogler. W. C., Ed.; Elsevier: New York, 1990: p 338.
14. (b) Coville, N J. In Organometallic Radical Processes, Trogler, W C., Ed.; Elsevier: New York, 1990; p 338.
15. (c) Schwarz, C. L ; Bullock, R. M.; Creutz, C. J. Am. Chem. Soc. 1991, 113, 1225.
16. (d) Tyler, D R.; Sur, S. K.; Fei, M. Organomerallics 1991, 10, 419.
17. (a) Photoinduced Electron Transfer, Part b; Fox. M. A., Channon, M., Eds.; Elsevier: New York, 1988.
18. (b) Lakowicz, J R. Principles of Fluorescence Spectroscopy: Plenum Press: New York, 1983.
19. Creation and Deletion of the Excited Stale; Lamola. A. A., Ware, W. R., Eds.: M. Dekker: New York. 1971.
20. Peters, J.; George, M. W.: Turner, J. J. Organometallics 1995, 14, 1503.
21. Kadish, K. M.; Lacombe, D. A., Anderson, J. E. Inorg. Chem. 1986, 25, 2246
22. Hepp, A. F., Wrighton, M. S. J. Am. Chem. Soc. 1981, 103, 1258.
23. Pugh, J. R., Meyer, T. J. J. Am. Chem Soc. 1992, 114, 3784.
24. Protasiewicz, J. D.; Theopold, K. H J. Am. Chem. Soc. 1993, 115, 5559.
25. (a) Tilset, M.; Parker, V. D. J. Am. Chem. Soc. 1989, 111, 6711.
26. (b) Tibet, M. Inorg. Chem 1994, 33, 3121.
27. (a) Wayner, D. D. M.; McPhee, D. J., Griller, D. J. Am. Chem Soc. 1988, 110, 132.
28. (b) Nagaoka, T.; Griller, D.; Wayner, D. D. M. J. Phys. Chem. 1991, 95, 6264.
29. (a) On the basis of the pseudo-first-order simulation data from ref 17b, the phase shift (φ) for a first order reaction at the surface of the electrode is limited to -45°. This suggests that a factor of 2 be included in eq 6 as shown, (b) Jones, W. E.; Fox, M A. J. Phys. Chem. 1994, 98, 5095.
30. Birdwhistell, R.; Hackett, P.; Manning, A. R. J. Organomet Chem. 1978, 757, 239.
31. Manning, A. R., Hackett, P ; Birdwhistell, R.; Soye, P. Inorg. Synth. 1990, 28, 148.
32. Birdwhistell, R. The University of West Florida. Personnal communication. 1995.
33. Hackett, P.; O'Neill, P S ; Manning, A. R. J. Chem Soc., Dalton Trans. 1974, 1625.
34. Cooley, N. A., MacConnachie, P. T. F.; Baird, M. C. Polyhedron 1988, 19, 1965.
35. Adams, R. D.; Collins, D. E.; Cotton, F A. J. Am. Chem. Soc. 1974, 96, 149.
36. Smith, D. K.; Strohben, W. E.; Evans, D. H. J. Electroanal. Chem. 1990, 288, 111.
37. (a) Drake, P. R.; Baird, M. C. J. Organomet. Chem 1989, 363, 131.
38. (b) McLain, S. J. J. Am. Chem. Soc. 1988, 110, 643.
39. (a) Richards, T. C.; Geiger, W. E.; Baird, M. C. Organometallics 1994, 13, 4494.
40. (b) Geiger, W. E. In Organometallic Radical Processes; Trogler, W C , Ed.; Elsevier: New York, 1990; p 142.
41. 12
42. Madach, T.; Vahrenkamp, H. Z. Naturfarsch. 1978, 33B, 1301.
43. O'Callaghan, K. A. E.; Brown. S J.; Page, J A.; Baird, M. C.; Richards, T. C.; Geiger. W. E. Orsanomeiallics 1991, 10, 3119.
44. In ref 18, this resulted in an error in the literature value sited for the Triphenylene reduction which is -2.46 V vs SCE. In this paper we have used a ferrocene internal reference for assigning all potentials, see Experimental Section.
45. Bard, A. J.; Faulkner, L. R Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 1980.
46. (a) Kristjansdottir. S. S.; Boody, A. E.; Weberg, R. T.; Norton, J. R. Organometallics 1988, 7, 1983
47. (b) Moore, E J., Sullivan, J. M.; Norton, J. R J. Am. Chem. Soc . 1986, 108, 2257
48. Landrum, J. T.; Hoff, C. D. J Organomet. Chem. 1985, 282, 215
49. Richards, T. C.; Geiger, W. E.; Baird, M. C. Organometallics 1994, 13, 3394.
50. Scott, S. L.; Espenson. J. H., Chen, W. J. Organometallics 1993, 12, 4017.