Size distribution and chemical composition of secondary organic aerosol formed from Cl-initiated oxidation of toluene

Journal of Environmental Sciences

Volumn 24, Issue 5, 2012, Pages 860-864

  Huang, Mingqiang ^a,b   Zhang, Weijun ^a   Gu, Xuejun ^a   Hu, Changjin ^a   Zhao, Weixiong ^a   Wang, Zhenya ^a   Fang, Li ^a  

^a ANHUI INSTITUTE OF OPTICS AND FINE MECHANICS   (China)

^b XIAMEN UNIVERSITY   (China)

Author keywords

Cl initiated oxidation; Laser desorption ionization; Secondary organic aerosol; Smog chamber; Toluene

Indexed keywords

AERODYNAMIC PARTICLE SIZER; BENZOIC ACID; BENZOQUINONES; BENZYL ALCOHOL; CHEMICAL COMPOSITIONS; FINE PARTICLES; GLYOXAL; HYDROPEROXIDES; LASER DESORPTION/IONIZATION; MASS SPECTRA; METHYL NITRATE; OXIDATION OF TOLUENES; REACTION MECHANISM; SECONDARY ORGANIC AEROSOLS; SMOG CHAMBERS; TIME-OF-FLIGHT MASS SPECTROMETERS;

AIR POLLUTION; ALDEHYDES; ATMOSPHERIC AEROSOLS; CARBOXYLIC ACIDS; DESORPTION; MASS SPECTROMETERS; MASS SPECTROMETRY; OXIDATION; SIZE DISTRIBUTION; TOLUENE;

ORGANIC LASERS;

CHLORIDE; ORGANIC COMPOUND; TOLUENE;

AEROSOL; CHEMICAL COMPOSITION; CHLORINE; DESORPTION; EXPERIMENTAL STUDY; IONIZATION; OXIDATION; PARTICLE SIZE; SIZE DISTRIBUTION; TOLUENE;

AEROSOL; ARTICLE; CHEMISTRY; LASER; LIGHT; MASS SPECTROMETRY; OXIDATION REDUCTION REACTION; PARTICLE SIZE; RADIATION EXPOSURE; TIME;

AEROSOLS; CHLORIDES; LASERS; LIGHT; MASS SPECTROMETRY; ORGANIC CHEMICALS; OXIDATION-REDUCTION; PARTICLE SIZE; TIME FACTORS; TOLUENE;

EID: 84860878134     PISSN: 10010742     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1001-0742(11)60840-1     Document Type: Article

References (22)

1. Ariya PA, Niki H, Harris GW, Anlauf KG, Worthy DEJ Polar sunrise experiment 1995: hydrocarbon measurements and tropospheric Cl and Br-atoms chemistry. Atmospheric Environment 1999, 33(6):931-938.
2. Atkinson R, Arey J Atmospheric degradation of volatile organic compounds. Chemical Reviews 2003, 103(12):4605-4638.
3. Atkinson R, Aschmann SM Kinetics of the gas phase reaction of Cl atoms with a series of organics at 296 ± 2 K and atmospheric pressure. International Journal of Chemical Kinetics 1985, 17(1):33-41.
4. Bowman FM, Odum JR, Seinfeld JH, Pandis SN Mathematical model for gas-particle partitioning of secondary organic aerosols. Atmospheric Environment 1997, 31(23):3921-3931.
5. Cai XY, Ziemba LD, Griffin RJ Secondary aerosol formation from the oxidation of toluene by chlorine atoms. Atmospheric Environment 2008, 42(32):7348-7359.
6. Fantechi G, Jensen NR, Saastad O, Hjorth J, Peeters J Reactions of Cl atoms with selected VOCs: kinetics, products and mechanisms. Journal of Atmospheric Chemistry 1998, 31(3):247-267.
7. Hao LQ, Wang ZY, Huang MQ, Fang L, Zhang WJ Effects of seed aerosols on the growth of secondary organic aerosols from the photooxidation of toluene. Journal of Environmental Sciences 2007, 19(6):704-708.
8. Hao LQ, Wang ZY, Huang MQ, Pei SX, Yang Y, Zhang WJ Size distribution of the secondary organic aerosol particles from the photooxidation of toluene. Journal of Environmental Sciences 2005, 17(16):912-916.
9. Huang MQ, Zhang WJ, Hao LQ, Wang ZY, Fang L, Kong RH, et al. Experimental study of photooxidation products of ethylbenzene. Journal of Environmental Sciences 2010, 22(10):1570-1575.
10. x and 1-propene. Environmental Science and Technology 2001, 35(18):3626-3639.
11. Karlsson RS, SzenteJ J, Ball JC, Maricq MM Homogeneous aerosol formation by the chlorine atom initiated oxidation of toluene. Journal of Physical Chemistry A 2001, 105(1):82-96.
12. Kercher JP, Riedel TP, Thorton JA Chlorine activation by N2O5: simultaneous, in situ detection of ClNO2 and N2O5 by chemical ionization mass spectrometry. Atmospheric Measurement Techniques 2009, 2(1):193-204.
13. Notario A, Mellouki A, Le Bars G Rate constants for the gas-phase reactions of chlorine atoms with a series of ketones. International Journal of Chemical Kinetics 2000, 32(1):62-66.
14. Odum JR, Hoffman T, Bowman F, Collins D, Flagan RC, Seinfeld JH Gas/particle partitioning and secondary organic aerosol yields. Environmental Science and Technology 1996, 30(8):2580-2585.
15. Odum JR, Jungkamp TPW, Griffin RJ, Flagan RC, Seinfeld JH The atmospheric aerosol-forming potential of whole gasoline vapor. Science 1997, 276(5309):96-99.
16. Oum KW, Lakin MJ, Dehaan DO, Brauers T, Finlayson-Pitts BJ Formation of molecular chlorine from the photolysis of ozone and aqueous sea-salt particles. Science 1998, 279(5347):74-76.
17. Ramacher B, Rudolph J, Koppmann R Hydrocarbon measurements in the spring arctic troposphere during the ARCTOC 95 campaign. Tellus Series B 1997, 49B(5):466-485.
18. Shi JC, Bernhard MJ Kinetic studies of Cl-atom reactions with selected aromatic compounds using the photochemical reactor-FTIR spectroscopy technique. International Journal of Chemical Kinetics 1997, 29(5):349-358.
19. Spicer CW, Chapman EG, Finlayson-Pitts BJ, Plastridge RA, Hubbe JM, Fast JD, et al. Unexpectedly high concentrations of molecular chlorine in coastal air. Nature 1998, 394(6691):353-356.
20. Thiault G, Mellouki A, Le Bras G Kinetics of gas phase reactions of OH and Cl with aromatic aldehydes. Physical Chemistry Chemical Physics 2002, 4(11):2194-2199.
21. Wang L, Arey J, Atkinson R Reactions of chlorine atoms with a series of aromatic hydrocarbons. Environmental Science and Technology 2005, 39(14):5302-5310.
22. Wingenter OW, Blake DR, Blake NJ, Sive BC, Rowland FS, Atlas E, et al. Tropospheric hydroxyl and atomic chlorine concentrations, and mixing timescales determined from hydrocarbon and halocarbon measurements made over the Southern Ocean. Journal of Geophysical Research 1999, 104(D17):21819-21828.