Understanding the reactivity of strained sandwich compounds with aluminum or gallium in bridging positions: Experiments and DFT calculations

Journal of the American Chemical Society

Volumn 134, Issue 18, 2012, Pages 7924-7936

  Bagh, Bidraha ^a   Schatte, Gabriele ^b   Green, Jennifer C ^c   Müller, Jens ^a  

^a UNIVERSITY OF SASKATCHEWAN   (Canada)

^b UNIVERSITY OF SASKATCHEWAN   (Canada)

^c UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC LIGANDS; DFT CALCULATION; DIHYDRIDES; FERROCENOPHANES; FERROCENYL; FORMATION REACTION; HIGH REACTIVITY; HYDROGENOLYSIS REACTIONS; ISODESMIC REACTIONS; KARSTEDT'S CATALYSTS; METALLOCENOPHANES; METALLOPOLYMERS; MODEL COMPOUND; NMR PROBE; OPTIMIZED GEOMETRIES; ORTHO POSITION; REACTION CONDITIONS; REACTION MIXTURE; SANDWICH MOIETY; SINGLE CRYSTAL X-RAY ANALYSIS; STERIC REPULSIONS; STRUCTURAL CHANGE; STRUCTURAL EFFECT; STRUCTURAL INFLUENCES; TACTICITIES; TRIMETHYLSILYL;

DENSITY FUNCTIONAL THEORY; GALLIUM; HEXANE; LIGANDS; MOLECULAR STRUCTURE; OPTIMIZATION; POLYMERS;

ALUMINUM;

[(DIMETHYLAMINO)DIMETHYLSILYL]BIS(TRIMETHYLSILYL)METHYL; ALUMINUM; DILITHIOFERROCENE; DILITHIORUTHENOCENE; FERROCENE DERIVATIVE; FERROCENOPHANE DERIVATIVE; GALLIUM; RUTHENOCENE DERIVATIVE; RUTHENOCENOPHANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PRECIPITATION;

EID: 84860847336     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3019274     Document Type: Article

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