Pointed-oval-shaped micelles from crystalline-coil block copolymers by crystallization-driven living self-assembly

Angewandte Chemie - International Edition

Volumn 49, Issue 44, 2010, Pages 8220-8223

  Presa Soto, Alejandro ^a   Gilroy, Joe B ^a   Winnik, Mitchell A ^b   Manners, Ian ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b UNIVERSITY OF TORONTO   (Canada)

Author keywords

Block copolymers; Living polymerization; Metallopolymers; Micelles; Self assembly

Indexed keywords

CRYSTALLINE CORE; DIBLOCK COPOLYMER; METALLOPOLYMERS; POLY(2-VINYLPYRIDINE) (P2VP); POLYFERROCENYLSILANES; POLYPHOSPHAZENES; SELF-ASSEMBLY METHOD; TEM IMAGES; UNIFORM SIZE;

BLOCK COPOLYMERS; COPOLYMERIZATION; CRYSTALLINE MATERIALS; CRYSTALLIZATION; MICELLES; SELF ASSEMBLY;

LIVING POLYMERIZATION;

POLYMER;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CRYSTALLIZATION; MICELLE; TRANSMISSION ELECTRON MICROSCOPY;

CRYSTALLIZATION; MICELLES; MICROSCOPY, ELECTRON, TRANSMISSION; MOLECULAR STRUCTURE; POLYMERS;

EID: 78249262072     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201003066     Document Type: Article

References (66)

1. I. W. Hamley, Angew. Chem. 2003, 115, 1730 - 1752
2. Angew. Chem. Int. Ed. 2003, 42, 1692 - 1712
3. D. E. Discher, A. Eisenberg, Science 2002, 297, 967 - 973
4. M. Lazzari, M. A. López-Quintela, Adv. Mater. 2003, 15, 1583 - 1594
5. J.-F. Gohy, Adv. Polym. Sci. 2005, 190, 65 - 136
6. Y. Kim, P. Dalhaimer, D. A. Christian, D. E. Discher, Nanotechnology 2005, 16, S 484 -S 491
7. L. Cao, J. A. Massey, M. A. Winnik, I. Manners, S. Riethmüller, F. Banhart, J. P. Spatz, M. Möller, Adv. Funct. Mater. 2003, 13, 271 - 276.
8. N. S. Cameron, M. K. Corbierre, A. Eisenberg, Can. J. Chem. 1999, 77, 1311 - 1326
9. E. B. Zhulina, M. Adam, I. LaRue, S. S. Sheiko, M. Rubinstein, Macromolecules 2005, 38, 5330 - 5351
10. J. Qian, M. Zhang, I. Manners, M. A. Winnik, Trends Biotechnol. 2010, 28, 84 - 92
11. R. C. Hayward, D. J. Pochan, Macromolecules 2010, 43, 3577 - 3584.
12. M. Antonietti, S. Heinz, M. Schmidt, C. Rosenauer, Macromolecules 1994, 27, 3276 - 3281
13. L. Zhang, A. Eisenberg, Science 1995, 268, 1728 - 1731
14. J. P. Spatz, S. Mößmer, M. Möller, Angew. Chem. 1996, 108, 1673 - 1676
15. Angew. Chem. Int. Ed. Engl. 1996, 35, 1510 - 1512
16. G. Liu, J. Ding, L. Qiao, A. Guo, B. P. Dymov, J. T. Gleeson, T. Hashimoto, K. Saijo, Chem. Eur. J. 1999, 5, 2740 - 2749
17. I. Korczagin, M. A. Hempenius, R. G. Fokkink, M. A. Cohen Stuart, M. Al-Hussein, P. H. H. Bomans, P. M. Frederik, G. J. Vancso, Macromolecules 2006, 39, 2306 - 2315.
18. J. A. Massey, K. Temple, L. Cao, Y. Rharbi, J. Raez, M. A. Winnik, I. Manners, J. Am. Chem. Soc. 2000, 122, 11577 - 11584
19. L. Cao, I. Manners, M. A. Winnik, Macromolecules 2002, 35, 8258 - 8260
20. F. Wurm, S. Hilf, H. Frey, Chem. Eur. J. 2009, 15, 9068 - 9077.
21. S. Jain, F. S. Bates, Science 2003, 300, 460 - 464
22. S. Jain, F. S. Bates, Macromolecules 2004, 37, 1511 - 1523.
23. Z. Li, Z. Chen, H. Cui, K. Hales, K. Qi, K. L. Wooley, D. J. Pochan, Langmuir 2005, 21, 7533 - 7539
24. T. W. Schleuss, R. Abbel, M. Gross, D. Schollmeyer, H. Frey, M. Maskos, R. Berger, A. F. M. Kilbinger, Angew. Chem. 2006, 118, 3036 - 3042
25. Angew. Chem. Int. Ed. 2006, 45, 2969 - 2975.
26. J. J. L. M. Cornelissen, M. Fischer, N. A. J. M. Sommerdijk, R. J. M. Nolte, Science 1998, 280, 1427 - 1430
27. J. Dupont, G. Liu, K.-I. Niihara, R. Kimoto, H. Jinnai, Angew. Chem. 2009, 121, 6260 - 6263
28. Angew. Chem. Int. Ed. 2009, 48, 6144 - 6147.
29. A. Walther, M. Drechsler, S. Rosenfeldt, L. Harnau, M. Ballauff, V. Abetz, A. H. E. Müller, J. Am. Chem. Soc. 2009, 131, 4720 - 4728
30. I. K. Voets, A. de Keizer, P. deWaard, P. M. Frederik, P. H. H. Bomans, H. Schmalz, A. Walther, S. M. King, F. A. M. Leermakers, M. A. Cohen Stuart, Angew. Chem. 2006, 118, 6825 - 6828
31. Angew. Chem. Int. Ed. 2006, 45, 6673 - 6676.
32. D. J. Pochan, Z. Chen, H. Cui, K. Hales, K. Qi, K. L. Wooley, Science 2004, 306, 94 - 97.
33. K. Yu, L. Zhang, A. Eisenberg, Langmuir 1996, 12, 5980 - 5984
34. S. Stewart, G. Liu, Angew. Chem. 2000, 112, 348 - 352
35. Angew. Chem. Int. Ed. 2000, 39, 340 - 344.
36. Z. Li, E. Kesselman, Y. Talmon, M. A. Hillmyer, T. P. Lodge, Science 2004, 306, 98 - 101
37. S. Kubowicz, J.-F. Baussard, J.-F. Lutz, A. F. Thünemann, H. von Berlepsch, A. Laschewsky, Angew. Chem. 2005, 117, 5397 - 5400
38. Angew. Chem. Int. Ed. 2005, 44, 5262 - 5265.
39. L. Zhang, C. Bartels, Y. Yu, H. Shen, A. Eisenberg, Phys. Rev. Lett. 1997, 79, 5034 - 5037
40. I. C. Riegel, A. Eisenberg, C. L. Petzhold, D. Samios, Langmuir 2002, 18, 3358 - 3363.
41. J.-K. Kim, M.-K. Hong, J.-H. Ahn, M. Lee, Angew. Chem. 2005, 117, 332 - 336
42. Angew. Chem. Int. Ed. 2005, 44, 328 - 332.
43. For work on the solution self-assembly of organic crystalline-coil block copolymers see
44. T. Vilgis, A. Halperin, Macromolecules 1991, 24, 2090 - 2095
45. J. Fu, B. Luan, X. Yu, Y. Cong, J. Li, C. Pan, Y. Han, Y. Yang, B. Li, Macromolecules 2004, 37, 976 - 986
46. J. Zhang, L.-Q. Wang, H. Wang, K. Tu, Biomacromolecules 2006, 7, 2492 - 2500
47. M. Lazzari, D. Scalarone, C. E. Hoppe, C. Vazquez-Vazquez, M. A. Lopez-Quintela, Chem. Mater. 2007, 19, 5818 - 5820
48. Z.-X. Du, J.-T. Xu, Z.-Q. Fan, Macromolecules 2007, 40, 7633 - 7637
49. D. Portinha, F. Boue, L. Bouteiller, G. Carrot, C. Chassenieux, S. Pensec, G. Reiter, Macromolecules 2007, 40, 4037 - 4042
50. Z.-X. Du, J.-T. Xu, Z.-Q. Fan, Macromol. Rapid Commun. 2008, 29, 467 - 471
51. M. Lazzari, D. Scalarone, C. Vazquez-Vazquez, M. A. López- Quintela, Macromol. Rapid Commun. 2008, 29, 352 - 357
52. H. Schmalz, J. Schmelz, M. Drechsler, J. Yuan, A. Walther, K. Schweimer, A. M. Mihut, Macromolecules 2008, 41, 3235 - 3242
53. A. M. Mihut, M. Drechsler, M. Möller, M. Ballauff, Macromol. Rapid Commun. 2010, 31, 449 - 453.
54. X. Wang, G. Guerin, H. Wang, Y. Wang, I. Manners, M. A. Winnik, Science 2007, 317, 644 - 647
55. T. Gädt, N. S. Ieong, G. Cambridge, M. A. Winnik, I. Manners, Nat. Mater. 2009, 8, 144 - 150
56. J. B. Gilroy, T. Gädt, G. R. Whittell, L. Chabanne, J. M. Mitchels, R. M. Richardson, M. A. Winnik, I. Manners, Nat. Chem. 2010, 2, 566 - 570.
57. H. Wang, W. Lin, K. P. Fritz, G. D. Scholes, M. A. Winnik, I. Manners, J. Am. Chem. Soc. 2007, 129, 12924 - 12925
58. H. Wang, A. J. Patil, K. Liu, S. Petrov, S. Mann, M. A. Winnik, I. Manners, Adv. Mater. 2009, 21, 1805 - 1808.
59. H. Wang, M. A. Winnik, I. Manners, Macromolecules 2007, 40, 3784 - 3789.
60. A. P. Soto, I. Manners, Macromolecules 2009, 42, 40 - 42
61. H. R. Allcock, S. D. Reeves, J. M. Nelson, C. A. Crane, I. Manners, Macromolecules 1997, 30, 2213 - 2215.
62. For full experimental details see the Supporting Information.
63. 290 in iPrOH (selective for the PP block) gave a mixture of spheres and platelets whereas in MeOH only spheres were formed (Figure S1).
64. See, for example
65. P. Dimitrov, A. Porjazoska, C. P. Novakov, M. Cvetkovska, C. B. Tsvetanov, Polymer 2005, 46, 6820 - 6828
66. T. Arai, J. Ogawa, E. Mouri, M. P. I. Bhuiyan, N. Nishino, Macromolecules 2006, 39, 1607 - 1613.