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Volumn 48, Issue 27, 2009, Pages 4961-4964

Synthesis and reactivity of a strained silicon-bridged [1]ferrocenophanium ion

Author keywords

Iron; Metallocenophanes; Oxidation; Ring strain; Ring opening polymerization

Indexed keywords

CRYSTALLINE SALTS; FERROCENIUM; METALLOCENOPHANES; RING OPENING REACTION; RING STRAIN; STRAINED SILICON;

EID: 70349971357     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901213     Document Type: Article
Times cited : (18)

References (43)
  • 34
    • 27844487254 scopus 로고
    • - was a non-innocent anion acting as a source of HF, presumably formed by hydrolysis (see R. Fernandez-Galan, B. R. Manzano, A. Otero, M. Lanfranchi, M. A. Pellinghelli, Inorg. Chem. 1994, 33, 2309), which cleaves the Si-Cp bond and opens the ring with formation of the fluorosilane ferrocenium derivative.
    • (1994) Inorg. Chem. , vol.33 , pp. 2309
    • Fernandez-Galan, R.1    Manzano, B.R.2    Otero, A.3    Lanfranchi, M.4    Pellinghelli, M.A.5
  • 35
    • 70349957044 scopus 로고    scopus 로고
    • Synthetic procedures and characterization data can be found in the Supporting Information
    • Synthetic procedures and characterization data can be found in the Supporting Information.
  • 36
    • 70349963493 scopus 로고    scopus 로고
    • -3. CCDC 690321 (4) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www. ccdc.cam.ac.uk/data- request/cif.
  • 37
    • 70349936914 scopus 로고    scopus 로고
    • - counteranion
    • - counteranion.
  • 42
    • 0001633955 scopus 로고
    • For 1.1'-trimethylene-bridged carba[3]ferrocenophanium salts, no such perturbations are observed and LMCT bands shift to lower energy. The effect of the three-carbon bridge in the electron absorption spectra is consistent with simple alkylation of the Cp ring and reflected in the moderate tilt angles (α≈9-14°) of such species. See: M. D. Duggan, D. N. Hendrickson, Inorg. Chem. 1975, 14, 955 ;
    • (1975) Inorg. Chem. , vol.14 , pp. 955
    • Duggan, M.D.1    Hendrickson, D.N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.