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Angewandte Chemie - International Edition

Volumn 51, Issue 18, 2012, Pages 4421-4425

The origins of dramatic axial ligand effects: Closed-shell Mn VO complexes use exchange-enhanced open-shell states to mediate efficient H abstraction reactions

(3) Janardanan, Deepa a Usharani, Dandamudi a Shaik, Sason a

a HEBREW UNIVERSITY OF JERUSALEM (Israel)

Author keywords

density functional calculations; exchange enhanced reactivity; high valent Mn oxo; hydrogen atom abstraction

Indexed keywords

AXIAL LIGAND; CLOSED SHELLS; H-ABSTRACTION; HIGH-VALENT MN-OXO; HYDROGEN ATOM ABSTRACTION; OPEN-SHELL; OPEN-SHELL STATE; REACTIVE STATE; SPIN-STATE; TRANSITION STATE;

ABSTRACTING; DENSITY FUNCTIONAL THEORY; HYDROGEN; LIGANDS; MANGANESE COMPOUNDS;

MANGANESE;

LIGAND; MANGANESE DERIVATIVE; MANGANESE OXIDE; ORGANOMETALLIC COMPOUND; OXIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; THERMODYNAMICS;

LIGANDS; MANGANESE COMPOUNDS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDES; THERMODYNAMICS;

EID: 84860212540 PISSN: 14337851 EISSN: 15213773 Source Type: Journal
DOI: 10.1002/anie.201200689 Document Type: Article

Times cited : (39)

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