Hydrocarbon-soluble, isolable ziegler-type Ir(0) n nanoparticle catalysts made from [(1,5-COD)Ir(μ-O 2C 8H 15)] 2 and 2-5 equivalents of AlEt 3: Their high catalytic activity, long lifetime, and AlEt 3-dependent, exceptional, 200 °c thermal stability

ACS Catalysis

Volumn 2, Issue 4, 2012, Pages 632-641

  Hamdemir, Isil K ^a   Özkar, Saim ^b   Yih, Kuang Hway ^c   Mondloch, Joseph E ^a   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

^c HUNGKUANG UNIVERSITY   (Taiwan)

Author keywords

Ir(0) nanoparticles; olefin hydrogenation; stabilization; Ziegler type nanoparticle catalysis

Indexed keywords

A-STABILITY; BULK METALS; CATALYTIC LIFETIME; CATALYTIC PROPERTIES; CYCLOHEXENE HYDROGENATION; HIGH THERMAL STABILITY; HYDROCARBON SOLUBILITY; HYDROCARBON SOLUTIONS; HYDROGENATION CATALYST; LEWIS ACID; LEWIS ACIDS; LONG LIFETIME; NANOPARTICLE CATALYSTS; OLEFIN HYDROGENATION; OTHER APPLICATIONS; PRECATALYSTS; SURFACE DERIVATIVES; SURFACE SPECIES; TOTAL TURNOVER;

CATALYSIS; CATALYST ACTIVITY; HYDROGENATION; NANOPARTICLES; OLEFINS; ORGANIC COMPOUNDS; STABILIZATION; THERMODYNAMIC STABILITY;

IRIDIUM;

EID: 84859584565     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs200688g     Document Type: Article

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