Photochemistry of furyl- and thienyldiazomethanes: Spectroscopic characterization of triplet 3-thienylcarbene

Journal of the American Chemical Society

Volumn 134, Issue 14, 2012, Pages 6443-6454

  Pharr, Caroline R ^a   Kopff, Laura A ^a   Bennett, Brian ^b   Reid, Scott A ^c   McMahon, Robert J ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b MEDICAL COLLEGE OF WISCONSIN   (United States)

^c Marquette University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIBONDING; CARBENES; CONFORMATIONAL ISOMERS; ELECTRONIC ABSORPTION; ELECTRONIC ABSORPTION SPECTRA; EPR SPECTRA; EPR SPECTROSCOPY; EXPERIMENTAL CONDITIONS; INTERCONVERSIONS; NATURAL BOND ORBITAL; ONE-FACTOR; ROTAMERS; SPECTROSCOPIC CHARACTERIZATION; SPECTROSCOPIC DETECTION; SPIN DENSITIES; STABILIZING INTERACTIONS; TRIPLET CARBENES; VISIBLE SPECTRA; ZERO-FIELD SPLITTING PARAMETERS;

CHEMICAL DETECTION; ISOMERS; ORGANIC COMPOUNDS; PHOTOLYSIS; SULFUR;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

2 FURYLCARBENE; 2 FURYLDIAZOMETHANE; 2 THIENYLCARBENE; 2 THIENYLDIAZOMETHANE; 3 FURYLCARBENE; 3 FURYLDIAZOMETHANE; 3 THIENYLCARBENE; CARBENE; CARBENOID; CARBON; UNCLASSIFIED DRUG;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL INTERACTION; CYCLIZATION; ELECTRON SPIN RESONANCE; ENERGY; ENERGY ABSORPTION; INFRARED SPECTROSCOPY; ISOMER; ISOMERISM; PHOTOCHEMISTRY; PHOTOLYSIS; ULTRAVIOLET SPECTROSCOPY;

CARBON; COMPUTER SIMULATION; DIAZOMETHANE; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; MAGNETIC RESONANCE SPECTROSCOPY; METHANE; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PHOTOCHEMISTRY; SOFTWARE; SPECTROPHOTOMETRY;

EID: 84859564605     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja300927d     Document Type: Article

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