2-Thienylchlorocarbene: Reactivity toward alkenes

Tetrahedron Letters

Volumn 44, Issue 4, 2003, Pages 773-776

  Moss, Robert A ^a   Fu, Xiaolin ^a   Ma, Yan ^a   Sauers, Ronald R ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2 THIENYLCHLOROCARBENE; ALKENE DERIVATIVE; CARBENOID; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CHEMICAL STRUCTURE; MEASUREMENT; REACTION ANALYSIS;

EID: 0037454992     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)02698-9     Document Type: Article

References (30)

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16. 3): 7.27 (d, J=4.5 Hz, 1H), 6.98 (dd, J=4.5, 3.6 Hz, 1H), 6.75 (d, J=3.6 Hz, 1H).
17. 4.
18. For a description of our LFP system, see Moss, R. A.; Johnson, L. A.; Merrer, D. C.; Lee, G. E., Jr. J. Am. Chem. Soc. 1999, 121, 5940. The system has been upgraded by the incorporation of a 150 W pulsed Xe monitoring lamp.
19. See below for further computational results and details.
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24. rel(exp) values reflect the reactivity of both syn- and anti-7.
25. 7d.
26. 7d.
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30. 7.