Difference between 1H NMR signals of primary amide protons as a simple spectral index of the amide intramolecular hydrogen bond strength

Journal of Physical Organic Chemistry

Volumn 25, Issue 4, 2012, Pages 287-295

  Gorobets, Nikolay Yu ^a,b   Yermolayev, Sergey A ^a,c   Gurley, Thomas ^a   Gurinov, Andrey A ^b,d   Tolstoy, Peter M ^b,d,e   Shenderovich, Ilya G ^b,d   Leadbeater, Nicholas E ^c  

^a INSTITUTE FOR SINGLE CRYSTALS   (Ukraine)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

^c UNIVERSITY OF CONNECTICUT   (United States)

^d ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^e MAX BORN INSTITUT   (Germany)

Author keywords

1H NMR and 15N NMR chemical shift; amide group reactivity; concentration influence; intramolecular and intermolecular hydrogen bond; solvent influence; substituent influence

Indexed keywords

1H NMR AND 15N NMR CHEMICAL SHIFT; AMIDE GROUP REACTIVITY; INTERMOLECULAR HYDROGEN BONDS; SOLVENT INFLUENCE; SUBSTITUENT INFLUENCE;

BOND STRENGTH (MATERIALS); CARRIER CONCENTRATION; CHEMICAL SHIFT; ELECTRON DENSITY MEASUREMENT; HYDROGEN BONDS; NITROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTONS; REACTION RATES;

AMIDES;

EID: 84859158645     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1910     Document Type: Article

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