Elucidating the early steps in photoinitiated radical polymerization via femtosecond pump-probe experiments and DFT calculations

Macromolecules

Volumn 45, Issue 5, 2012, Pages 2257-2266

  Wolf, Thomas J A ^a   Voll, Dominik ^a   Barner Kowollik, Christopher ^a   Unterreiner, Andreas Neil ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CRITICAL PARAMETER; DEACTIVATION CHANNEL; DEACTIVATION PROCESS; DENSITY FUNCTIONAL THEORY METHODS; DFT CALCULATION; EXCITED SINGLET STATE; EXCITED TRIPLET STATE; FEMTOSECOND TRANSIENT ABSORPTION; FEMTOSECONDS; INITIATION EFFICIENCY; INTERNAL CONVERSIONS; INTERSYSTEM CROSSING; METHACRYLATE MONOMERS; PHOTO-INITIATOR; PHOTOINITIATION; PICOSECOND TIME SCALE; PULSED LASER POLYMERIZATION; PUMP-PROBE EXPERIMENTS; RADICAL PHOTOINITIATORS; TRIPLET STATE; ULTRA-FAST; UNDERLYING MECHANISM;

DENSITY FUNCTIONAL THEORY; DYNAMICS; EXPERIMENTS; OPTICAL PUMPING; POLYMERIZATION; PULSED LASERS;

EXCITED STATES;

EID: 84858181821     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma202673q     Document Type: Article

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