메뉴 건너뛰기




Volumn 12, Issue 2, 2012, Pages 804-810

Intermolecular hydrogen-bond networks and physical properties of BF 4 - and TCNQ •- salts of three-fold symmetric tris(alkylamino) phenalenyliums

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; ALKYLAMINO GROUP; AMINO GROUP; ANION SPECIES; CHARGE-TRANSFER SALTS; COLUMNAR STRUCTURES; COULOMB REPULSIONS; DELOCALIZATIONS; ELECTROCHEMICAL MEASUREMENTS; ELECTRON-DONATING; HYDROGEN BOND NETWORKS; INTERMOLECULAR HYDROGEN BONDS; IONIC SALTS; IRREVERSIBLE REDUCTION; METATHESIS METHOD; MOLECULAR PLANES; NEGATIVE SHIFT; NETWORK STRUCTURES; NEUTRAL RADICAL; POSITIVE CHARGES; RADICAL ANIONS; REDOX PROPERTY; REDUCTION POTENTIAL; TETRACYANOQUINODIMETHANE;

EID: 84858067573     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg201120s     Document Type: Article
Times cited : (6)

References (51)
  • 8
    • 84886179128 scopus 로고    scopus 로고
    • Phenalenyls, cyclopentadienyls, and other carbon-centered radicals
    • Recent overviews of the phenalenyl chemistry: Hicks, R., Ed.; Chichester, U.K.; Chapter 3
    • Recent overviews of the phenalenyl chemistry: Morita, Y.; Nishida, S. Phenalenyls, Cyclopentadienyls, and Other Carbon-Centered Radicals. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds; Hicks, R., Ed.; Chichester, U.K., 2010; Chapter 3, pp 81-145.
    • (2010) Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds , pp. 81-145
    • Morita, Y.1    Nishida, S.2
  • 17
    • 0016789773 scopus 로고
    • Haddon, R. C. Nature 1975, 256, 394-396.
    • (1975) Nature , vol.256 , pp. 394-396
    • Haddon, R.C.1
  • 23
    • 10244264738 scopus 로고    scopus 로고
    • For a recent comprehensive overview of H-bonded CT complexes and salts
    • For a recent comprehensive overview of H-bonded CT complexes and salts, see: Fourmigué, M.; Batail, P. Chem. Rev. 2004, 104, 5379-5418.
    • (2004) Chem. Rev. , vol.104 , pp. 5379-5418
    • Fourmigué, M.1    Batail, P.2
  • 40
    • 21544435239 scopus 로고
    • The CN stretching frequency of TCNQ derivatives is known to exhibit a lower frequency shift with the increase of ionicity and has been utilized as a simple tool to estimate the ionicity and electronic structure of a CT complex. However, the CN stretching frequency is sensitive also to environmental perturbations such as H-bonds, and the estimation of ionicity often gives an inaccurate value. Furthermore, the appearance of a symmetric mode causes the inaccurate estimation for the ionicity to be more negative than ca. -0.5
    • Chappell, J. S.; Bloch, A. N.; Bryden, W. A.; Maxfield, M.; Poehler, T. O.; Cowan, D. O. J. Am. Chem. Soc. 1981, 103, 2442-2443, The CN stretching frequency of TCNQ derivatives is known to exhibit a lower frequency shift with the increase of ionicity and has been utilized as a simple tool to estimate the ionicity and electronic structure of a CT complex. However, the CN stretching frequency is sensitive also to environmental perturbations such as H-bonds, and the estimation of ionicity often gives an inaccurate value. Furthermore, the appearance of a symmetric mode causes the inaccurate estimation for the ionicity to be more negative than ca. -0.5.
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 2442-2443
    • Chappell, J.S.1    Bloch, A.N.2    Bryden, W.A.3    Maxfield, M.4    Poehler, T.O.5    Cowan, D.O.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.