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Volumn 8, Issue 8, 2008, Pages 3058-3065

Hydrogen-bond architectures of protonated 4,4′-biimidazolium derivatives and oligo(imidazolium)s in charge-transfer salts with tetracyanoquinodimethane

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EID: 61549127912     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg800202n     Document Type: Article
Times cited : (23)

References (49)
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    • Recent overviews of supramolecular assemblies based on H-bond: Crystal Design: Structure and Function; Desiraju, G. R., Ed.; Perspectives in Supramolecular Chemistry; John Wiley & Sons: Chichester, U.K., 2003.
    • (a) Recent overviews of supramolecular assemblies based on H-bond: Crystal Design: Structure and Function; Desiraju, G. R., Ed.; Perspectives in Supramolecular Chemistry; John Wiley & Sons: Chichester, U.K., 2003.
  • 2
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    • Alajarin, M.; Aliev, A. E.; Burrows, A. D.; Harris, K. D. M.; Pastor, A.; Steed, J. W.; Turner, D. R. Supramolecular Assembly Via Hydrogen Bonds I; Mingos, D. M. P., Ed.; Structure and Bonding; Springer-Verlag: Berlin, 2004; 108.
    • (b) Alajarin, M.; Aliev, A. E.; Burrows, A. D.; Harris, K. D. M.; Pastor, A.; Steed, J. W.; Turner, D. R. Supramolecular Assembly Via Hydrogen Bonds I; Mingos, D. M. P., Ed.; Structure and Bonding; Springer-Verlag: Berlin, 2004; Vol. 108.
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    • 10244264738 scopus 로고    scopus 로고
    • Recent comprehensive overview of TTF derivatives with H-bond functionalities, see
    • Recent comprehensive overview of TTF derivatives with H-bond functionalities, see: Fourmigué, M.; Batail, P. Chem. Rev. 2004, 104, 5379-5418.
    • (2004) Chem. Rev , vol.104 , pp. 5379-5418
    • Fourmigué, M.1    Batail, P.2
  • 7
    • 19944374438 scopus 로고    scopus 로고
    • Our recent studies on H-bond-functionalized TTF derivatives, see: Murata, T, Morita, Y, Fukui, K, Sato, K, Shiomi, D, Takui, T, Maesato, M, Yamochi, H, Saito, G, Nakasuji, K. Angew Chem, Int. Ed. 2004, 43, 6343-6346
    • (a) Our recent studies on H-bond-functionalized TTF derivatives, see: Murata, T.; Morita, Y.; Fukui, K.; Sato, K.; Shiomi, D.; Takui, T.; Maesato, M.; Yamochi, H.; Saito, G.; Nakasuji, K. Angew Chem., Int. Ed. 2004, 43, 6343-6346.
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    • Examples of conductive CT salts of TCNQ with H-bond functionalized countercations, see
    • (a) Examples of conductive CT salts of TCNQ with H-bond functionalized countercations, see: Kobayashi, H.; Ohashi, Y.; Marumo, F.; Saito, Y. Acta Crystallogr., Sect. B 1970, 26, 459-467.
    • (1970) Acta Crystallogr., Sect. B , vol.26 , pp. 459-467
    • Kobayashi, H.1    Ohashi, Y.2    Marumo, F.3    Saito, Y.4
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    • 85168786571 scopus 로고    scopus 로고
    • Murata, T.; Morita, Y.; Nishimura, Y.; Nakasuji, K. Polyhedron 2005, 24, 2625-2631, See also.
    • (a) Murata, T.; Morita, Y.; Nishimura, Y.; Nakasuji, K. Polyhedron 2005, 24, 2625-2631, See also.
  • 40
    • 0033063340 scopus 로고    scopus 로고
    • 2Bim derivatives are soluble to alcohols (MeOH and EtOH); however, TCNQ acceptors easily decompose by the reaction with alcohols. See: Tanemura, K.; Nishida, Y.; Suzuki, T.; Satsumabayashi, K.; Horaguchi, T. J. Chem. Res., Synop. 1999, 40-41.
    • 2Bim derivatives are soluble to alcohols (MeOH and EtOH); however, TCNQ acceptors easily decompose by the reaction with alcohols. See: Tanemura, K.; Nishida, Y.; Suzuki, T.; Satsumabayashi, K.; Horaguchi, T. J. Chem. Res., Synop. 1999, 40-41.
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    • Chappell, J. S.; Bloch, A. N.; Bryden, W. A.; Maxfield, M.; Poehler, T. O.; Cowan, D. O. J. Am. Chem. Soc. 1981, 103, 2442-2443; C≡N stretching frequency of TCNQ derivatives is known to exhibit lower-frequency shift with increase of ionicity and has been utilized as a simple tool to estimate ionicity and electronic structure of CT complexes. However, C≡N stretching frequency is also sensitive to environmental perturbations such as the H-bond, and the estimation of ionicity often gives an inaccurate value. Furthermore, the appearance of a symmetric mode causes inaccurate estimation for ionicity more negative than ca.-0.5.
    • Chappell, J. S.; Bloch, A. N.; Bryden, W. A.; Maxfield, M.; Poehler, T. O.; Cowan, D. O. J. Am. Chem. Soc. 1981, 103, 2442-2443; C≡N stretching frequency of TCNQ derivatives is known to exhibit lower-frequency shift with increase of ionicity and has been utilized as a simple tool to estimate ionicity and electronic structure of CT complexes. However, C≡N stretching frequency is also sensitive to environmental perturbations such as the H-bond, and the estimation of ionicity often gives an inaccurate value. Furthermore, the appearance of a symmetric mode causes inaccurate estimation for ionicity more negative than ca.-0.5.
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    • 2/3•-)3, see: Fritchie, C. J., Jr.; Arthur, P., Jr. Acta Crystallogr. 1966, 21, 139-145.
    • 2/3•-)3, see: Fritchie, C. J., Jr.; Arthur, P., Jr. Acta Crystallogr. 1966, 21, 139-145.
  • 49
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    • See the Supporting Information for general experimental methods
    • See the Supporting Information for general experimental methods.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.