Transition-metal-catalyzed enantioselective propargylic substitution reactions of propargylic alcohol derivatives with nucleophiles

Synthesis

Volumn 44, Issue 4, 2012, Pages 489-503

  Nishibayashi, Yoshiaki ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

alkylation; enantioselective reaction; nucleophile; organocatalyst; propargylic alcohol; propargylic substitution reaction

Indexed keywords

2-NAPHTHOLS; ASYMMETRIC REACTION; COPPER CATALYST; CYCLOADDITIONS; ENANTIOSELECTIVE; ENANTIOSELECTIVE REACTIONS; ETHYNYL; LEWIS ACID CATALYSTS; MISCELLANEOUS REACTIONS; ORGANOCATALYSTS; PROPARGYLATION; PROPARGYLIC ALCOHOLS; PROPARGYLIC SUBSTITUTION REACTIONS; RING OPENING REACTION; RUTHENIUM CATALYSTS; TRANSITION METAL CATALYSTS;

ALCOHOLS; ALKYLATION; CATALYSIS; CATALYSTS; NUCLEOPHILES; OLEFINS; RUTHENIUM; SUBSTITUTION REACTIONS; TRANSITION METALS;

ENANTIOSELECTIVITY;

COPPER; FURAN DERIVATIVE; INDOLE DERIVATIVE; LEWIS ACID; N,N DIMETHYLANILINE; NUCLEOPHILE; RUTHENIUM DERIVATIVE; TRANSITION ELEMENT;

ALKYLATION; AMINATION; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; NUCLEOPHILICITY; PROPARGYLATION; PROTON NUCLEAR MAGNETIC RESONANCE; RACEMIZATION; REVIEW; STOICHIOMETRY; X RAY CRYSTALLOGRAPHY;

EID: 84857033087     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1290158     Document Type: Review

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