Metal activation of a germylenoid, a new approach to metalgermanium triple bonds: Synthesis and reactions of the germylidyne complexes [cp(co) 2m=gec(sime3)3] (m = mo, w)

Organometallics

Volumn 31, Issue 2, 2012, Pages 748-755

  Filippou, Alexander C ^a   Stumpf, Kai W ^a   Chernov, Oleg ^a   Schnakenburg, Gregor ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

GERMANIUM CENTERS; METAL-GERMANIUM; SINGLE CRYSTAL X-RAY DIFFRACTION; SPECTROSCOPIC FEATURES; TRIPLE BONDS;

GERMANIUM; MOLYBDENUM; MOLYBDENUM COMPOUNDS; TOLUENE; X RAY DIFFRACTION;

TUNGSTEN COMPOUNDS;

EID: 84856859131     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om201176n     Document Type: Article

References (89)

1. Filippou, A. C.; Chernov, O.; Stumpf, K. W.; Schnakenburg, G. Angew. Chem. 2010, 122, 3368
2. Angew. Chem., Int. Ed. 2010, 49, 3296.
3. Filippou, A. C.; Chernov, O.; Schnakenburg, G. Angew. Chem. 2011, 123, 1154
4. Angew. Chem., Int. Ed. 2011, 50, 1122.
5. Simons, R. S.; Power, P. P. J. Am. Chem. Soc. 1996, 118, 11966.
6. Pu, L.; Twamley, B.; Haubrich, S. T.; Olmstead, M. M.; Mork, B. V.; Simons, R. S.; Power, P. P. J. Am. Chem. Soc. 2000, 122, 650.
7. Filippou, A. C.; Philippopoulos, A. I.; Portius, P.; Neumann, D. U. Angew. Chem. 2000, 112, 2881
8. Angew. Chem., Int. Ed. 2000, 39, 2778.
9. Filippou, A. C.; Portius, P.; Philippopoulos, A. I. Organometallics 2002, 21, 653.
10. Filippou, A. C.; Portius, P.; Philippopoulos, A. I.; Rohde, H. Angew. Chem. 2003, 115, 461
11. Angew. Chem., Int. Ed. 2003, 42, 445.
12. Filippou, A. C.; Philippopoulos, A. I.; Schnakenburg, G. Organometallics 2003, 22, 3339.
13. Filippou, A. C.; Rohde, H.; Schnakenburg, G. Angew. Chem. 2004, 116, 2293
14. Angew. Chem., Int. Ed. 2004, 43, 2243.
15. Filippou, A. C.; Weidemann, N.; Schnakenburg, G.; Rohde, H.; Philippopoulos, A. I. Angew. Chem. 2004, 116, 6674
16. Angew. Chem., Int. Ed. 2004, 43, 6512.
17. Filippou, A. C.; Philippopoulos, A. I.; Portius, P.; Schnakenburg, G. Organometallics 2004, 23, 4503.
18. Filippou, A. C.; Schnakenburg, G.; Philippopoulos, A. I.; Weidemann, N. Angew. Chem. 2005, 117, 6133
19. Angew. Chem., Int. Ed. 2005, 44, 5979.
20. Filippou, A. C.; Weidemann, N.; Philippopoulos, A. I.; Schnakenburg, G. Angew. Chem. 2006, 118, 6133
21. Angew. Chem., Int. Ed. 2006, 45, 5987.
22. Filippou, A. C.; Weidemann, N.; Schnakenburg, G. Angew. Chem. 2008, 120, 5883
23. Angew. Chem., Int. Ed. 2008, 47, 5799.
24. Kohl, F. X.; Jutzi, P. J. Organomet. Chem. 1983, 243, 31.
25. Jutzi, P.; Leue, C. Organometallics 1994, 13, 2898.
26. Simons, R. S.; Pu, L.; Olmstead, M. M.; Power, P. P. Organometallics 1997, 16, 1920.
27. Winter, J. G.; Portius, P.; Kociok-Köhn, G.; Steck, R.; Filippou, A. C. Organometallics 1998, 7, 4176.
28. Pu, L.; Twamley, B.; Power, P. P. J. Am. Chem. Soc. 2000, 122, 3524.
29. Khrustalev, V. N.; Glukhov, I. V.; Borisova, I. V.; Zemlyansky, N. N. Appl. Organomet. Chem. 2007, 21, 551.
30. Filippou, A. C.; Chernov, O.; Blom, B.; Stumpf, K. W.; Schnakenburg, G. Chem. Eur. J. 2010, 16, 2866.
31. Boche, G; Lohrenz, J. C. W. Chem. Rev. 2001, 101, 697.
32. Capriati, V.; Florio, S. Chem. Eur. J. 2010, 16, 4152.
33. Oehme, H.; Weiss, H. J. Organomet. Chem. 1987, 319, C16.
34. Tamao, K.; Kawachi, A. Angew. Chem. 1995, 107, 886
35. Angew. Chem., Int. Ed. 1995, 34, 818.
36. Kawachi, A.; Tamao, K. Bull. Chem. Soc. Jpn. 1997, 70, 945.
37. Tamao, K.; Kawachi, A.; Asahara, M.; Toshimitsu, A. Pure Appl. Chem. 1999, 71, 393.
38. Sekiguchi, A.; Lee, V. Y.; Nanjo, M. Coord. Chem. Rev. 2000, 210, 11.
39. Hatano, K.; Tokitoh, N.; Takagi, N.; Nagase, S. J. Am. Chem. Soc. 2000, 122, 4829.
40. Wiberg, N.; Niedermayer, W. J. Organomet. Chem. 2001, 628, 57.
41. Lee, M. E.; Cho, H. M.; Lim, Y. M.; Choi, J. K.; Park, C. H.; Jeong, S. E.; Lee, U. Chem. Eur. J. 2004, 10, 377.
42. Likhar, R.; Zirngast, M.; Baumgartner, J.; Marshner, C. Chem. Commun. 2004, 1764.
43. Antolini, F.; Gehrhus, B.; Hitchcock, P. B.; Lappert, M. F. Chem. Commun. 2005, 5112.
44. Flock, M.; Marschner, C. Chem. Eur. J. 2005, 11, 4635.
45. Molev, G.; Bravo-Zhivotoskii, D.; Karni, M.; Tumanskii, B.; Botoshansky, M.; Apeloig, Y. J. Am. Chem. Soc. 2006, 128, 2784.
46. Ohtaki, T.; Ando, W. Organometallics 1996, 15, 3103.
47. Sekiguchi, A.; Lee, V. Y. Chem. Rev. 2003, 103, 1429.
48. Tajima, T.; Sasamori, T.; Takeda, N.; Tokitoh, N.; Yoshida, K.; Nakahara, M. Organometallics 2006, 25, 230.
49. Sasamori, T.; Tokitoh, N. Organometallics 2006, 25, 3522.
50. Cook, M. A.; Eaborn, C.; Jukes, A. E.; Walton, D. R. M. J. Organomet. Chem. 1970, 24, 529.
51. Eaborn C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc. Chem. Commun. 1983, 827.
52. Aiube, Z. H.; Eaborn, C. J. Organomet. Chem. 1984, 269, 217.
53. Schnakenburg, G. Dissertation, Universität Bonn, 2008.
54. Pyykkö, P.; Riedel, S.; Patschke, M. Chem. Eur. J. 2005, 11, 3511.
55. Filippou, A. C.; Grünleitner, W. J. Organomet. Chem. 1991, 407, 61.
56. Filippou, A. C.; Grünleitner, W.; Kiprof, P. J. Organomet. Chem. 1991, 410, 175.
57. Filippou, A. C.; Grünleitner, W.; Völkl, C.; Kiprof, P. J. Organomet. Chem. 1991, 413, 181.
58. Filippou, A. C.; Völkl, C.; Kiprof, P. J. Organomet. Chem. 1991, 415, 375.
59. Filippou, A. C.; Wanninger, K.; Mehnert, C. J. Organomet. Chem. 1993, 461, 99.
60. Filippou, A. C.; Wössner, D.; Kociok-Köhn, G.; Hinz, I. J. Organomet. Chem. 1997, 541, 333.
61. Barraclough, C. C.; Lewis, J.; Nyholm, R. S. J. Chem. Soc. 1961, 2582.
62. de Witt-Horrocks, W. Jr.; Mann, R. H. Spectrochim. Acta 1965, 21, 349.
63. Foffani, A.; Poletti, A.; Cataliotti, R. Spectrochim. Acta A 1968, 24, 1437.
64. Gould, N. J.; Parker, D. J. Spectrochim. Acta A 1975, 31, 1785.
65. Gutmann, V. Mon. Chem. 1977, 108, 429.
66. Creaser, C. S.; Fey, M. A.; Stephenson, G. R. Spectrochim. Acta A 1994, 50, 1295.
67. Dossett, S. J.; Hill, A. F.; Jeffrey, J. C.; Marken, F.; Sherwood, P.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1988, 2453.
68. Fischer, E. O.; Lindner, T. L.; Huttner, G.; Friedrich, P.; Kreißl, F. R.; Besenhard, J. O. Chem. Ber. 1977, 110, 3397.
69. Uedelhoven, W. Dissertation, Technische Universität München, 1979.
70. Griffith, C. S.; Koutsantonis, G. A.; Skelton, B. W.; White, A. H. J. Organomet. Chem. 2003, 672, 17.
71. Avent, A. G.; Bott, S. G.; Ladd, J. A.; Lickiss, P. D.; Pidcock, A. J. Organomet. Chem. 1992, 427, 9.
72. Kuhn, N.; Kratz, T. Synthesis 1993, 561.
73. Kuhl, O.; Lönnecke, P.; Heinicke, J. Inorg. Chem. 2003, 42, 2836.
74. Zabula, V.; Hahn, F. E.; Pape, T.; Hepp, A. Organometallics 2007, 26, 1972.
75. Shinohara, A.; McBee, J.; Tilley, T. D. Inorg. Chem. 2009, 48, 8081.
76. Huttner, G.; Weber, U.; Sigwarth, B.; Scheidsteger, O.; Lang, H.; Zsolnai, L. J. Organomet. Chem. 1985, 282, 331.
77. Jutzi, P.; Hampel, B.; Stroppel, K.; Krüger, C.; Angermund, K.; Hofman, P. Chem. Ber. 1985, 118, 2789.
78. Jutzi, P.; Hampel, B.; Hursthouse, M. B.; Howes, A. J. J. Organomet. Chem. 1986, 299, 19.
79. Du Mont, W.-W.; Lange, L.; Pohl, S.; Saak, W. Organometallics 1990, 9, 1395.
80. Tokitoh, N.; Manmaru, K.; Okazaki, R. Organometallics 1994, 13, 167.
81. Ueno, K.; Yamaguchi, K.; Ogino, H. Organometallics 1999, 18, 4468.
82. Hashimoto, H.; Tsubota, T.; Fukuda, T.; Tobita, H. Chem. Lett. 2009, 38, 1196.
83. Filippou, A. C.; Stumpf, K. W.; Schnakenburg, G., Personal communication. Filippou, A. C.; Stumpf, K. W.; Chernov, O.; Schnakenburg, G. Private communication to the Cambridge Structural Database, deposition numbers CCDC 855235-855239, 2011.
84. Cowley, A. H.; Norman, N. C.; Pakulski, M.; Becker, G.; Layh, M.; Kirchner, E.; Schmidt, M. Inorg. Synth. 1990, 27, 235.
85. Kouvetakis, J.; Haaland, A.; Shorokhov, D. J.; Volden, H. V.; Girichev, G. V.; Sokolov, V. I.; Matsunaga, P. J. Am. Chem. Soc. 1998, 120, 6738.
86. Filippou A. C.; Winter, J. G.; Kociok-Köhn, G.; Hinz, I. J. Chem. Soc., Dalton Trans. 1998, 2029.
87. Blessing, R. H. Acta Crystallogr., Sect. A 1995, 51, 33.
88. Sheldrick, G. M. SHELXS97 and SHELXL97; University of Göttingen, Göttingen, Germany, 1997.
89. Brandenburg, K. DIAMOND 2.1.c; Crystal Impact GbR, Bonn, Germany, 1999.