Diastereoselective synthesis of cycloheptadienol derivatives by a formal [5+2] carbocyclization reaction of α,β,γ,δ-diunsaturated (methoxy)carbene complexes with methyl ketone lithium enolates

Angewandte Chemie - International Edition

Volumn 43, Issue 41, 2004, Pages 5510-5513

  Barluenga, José ^a   Alonso, Jorge ^a   Fañanás, Francisco J ^a   Borge, Javier ^a   García Granda, Santiago ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

Carbene ligands; Cyclization; Cycloheptadienols; Medium ring compounds; Tungsten

Indexed keywords

KETONES; LITHIUM;

CARBOCYCLES; ENOLATES;

DERIVATIVES;

CARBENE; CARBONYL DERIVATIVE; CHROMIUM; CYCLOHEPTADIENOL DERIVATIVE; DIENYLMETHOXYCARBENE COMPLEX; HETEROCYCLIC COMPOUND; KETONE; LITHIUM; METHYL KETONE LITHIUM ENOLATE; TUNGSTEN; UNCLASSIFIED DRUG;

ARTICLE; COLUMN CHROMATOGRAPHY; CRYSTAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; HYDROLYSIS; ISOMERIZATION; MICHAEL ADDITION; STEREOCHEMISTRY; SYNTHESIS; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; CYCLOHEPTANES; HYDROCARBONS; KETONES; LITHIUM; METHANE; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 8444246793     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460547     Document Type: Article

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