Mononuclear-dinuclear equilibrium of grafted copper complexes confined in the nanochannels of MCM-41 silica

Chemistry - A European Journal

Volumn 17, Issue 50, 2011, Pages 14258-14266

  Zhang, Kun ^a   Lam, Koon Fung ^c   Albela, Belén ^b   Xue, Teng ^a   Khrouz, Lhoussain ^b   Hou, Qiong Wei ^a   Yuan, En Hui ^a   He, Ming Yuan ^a   Bonneviot, Laurent ^b  

^a EAST CHINA NORMAL UNIVERSITY   (China)

^b UNIVERSITÉ DE LYON   (France)

^c UNIVERSITÉ LYON 1   (France)

Author keywords

bio inspired catalysis; bioinorganic chemistry; enzyme models; mesoporous silica; surface grafting

Indexed keywords

BIOINORGANIC CHEMISTRY; BRIDGING LIGANDS; CONFINEMENT EFFECTS; COORDINATION MODES; COPPER COMPLEXES; COPPER PRECURSORS; COUNTERIONS; CROSS POLARIZATIONS; CU COMPLEXES; DINUCLEAR; DINUCLEAR COPPER; DINUCLEAR COPPER COMPLEXES; DYNAMIC NATURE; ENZYME MODELS; EPR SPECTROSCOPY; HYDROGEN BONDING NETWORK; MAGIC ANGLE SPINNING; MCM-41 SILICA; MESOPOROUS SILICA; MULTI-STEP; NANO CHANNELS; PERCHLORATE IONS; PROTON-TRANSFER MECHANISM; SEQUENTIAL GRAFTING; SILICA MATRIX; STRUCTURAL CONCEPT; SURFACE GRAFTING; UV/ VIS SPECTROSCOPY;

BIOCHEMISTRY; BIOLOGICAL SYSTEMS; CHLORINE; CHLORINE COMPOUNDS; COPPER; DIMERS; ELECTRON SPIN RESONANCE SPECTROSCOPY; GRAFTING (CHEMICAL); HYDROGEN; INORGANIC COMPOUNDS; MESOPOROUS MATERIALS; POLYACRYLONITRILES; SILICA; ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

COPPER COMPOUNDS;

COPPER; MCM 41; MCM-41; ORGANOMETALLIC COMPOUND; PROTON; SILICON DIOXIDE;

ARTICLE; CATALYSIS; CHEMISTRY; CONFORMATION; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ULTRAVIOLET SPECTROPHOTOMETRY; X RAY CRYSTALLOGRAPHY; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYSIS; COPPER; CRYSTALLOGRAPHY, X-RAY; HYDROGEN BONDING; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; PHOTOELECTRON SPECTROSCOPY; PROTONS; SILICON DIOXIDE; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 82955222314     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201102026     Document Type: Article

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