Highly stereoselective titanium-mediated aldol reaction from (S)-4-benzyloxy-3-methyl-2-butanone

Journal of Organic Chemistry

Volumn 76, Issue 21, 2011, Pages 8575-8587

  Zambrana, Joana ^a   Romea, Pedro ^a   Urpí, Fèlix ^a   Luján, Cristina ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALDOL REACTIONS; ASYMMETRIC INDUCTION; CHIRAL ALDEHYDE; DIASTEREO-SELECTIVITY; HIGH YIELD; NATURAL PRODUCTS; REACTING SPECIES; SPECTROSCOPIC STUDIES; STEREO-SELECTIVE;

ALDEHYDES; CONDENSATION REACTIONS; KETONES; SPECTROSCOPIC ANALYSIS; STEREOCHEMISTRY; STEREOSELECTIVITY; SYNTHESIS (CHEMICAL);

TITANIUM;

1 BENZYLOXY 2 METHYL 5 PHENYL 3,5 PENTANEDIOL; 1 BENZYLOXY 2,6 DIMETHYL 3,5 HEPTANEDIOL; 1 BENZYLOXY 3,5 ISOPROPYLIDENEDIOXY 2,6 DIMETHYLHEPTANE; 1 BENZYLOXY 5 HYDROXY 2 METHYL 3 OCTANONE; 1 BENZYLOXY 5 HYDROXY 2 METHYL 6 OCTEN 3 ONE; 1 BENZYLOXY 5 HYDROXY 2 METHYL 7 PHENYL 6 HEPTEN 3 ON; 1 BENZYLOXY 5 HYDROXY 2,6 DIMETHYL 3 HEPTANONE; 1 BENZYLOXY 5 HYDROXY 2,6 DIMETHYL 3 OCTANONE; 1 BENZYLOXY 5 HYDROXY 2,6 DIMETHYL 6 HEPTEN 3 ONE; 1 BENZYLOXY 6 TERT BUTYLDIPHENYLSILYLOXY 5 HYDROXY 2 METHYL 3 HEPTANONE; 1 BENZYLOXY 6 TERT BUTYLDIPHENYLSILYLOXY 5 HYDROXY 2,6 DIIMETHYL 3 HEPTANONE; 1 BENZYLOXY 7 TERT BUTYLDIPHENYLSILYLOXY 5 HYDROXY 2,6 DIIMETHYL 3 HEPTANONE; 4 [2 HYDROXY 3 METHYL 1 BUTYL] 5 METHYL 2 PHENYL 1,3 DIOXANE; 4 BENZYLOXY 3 METHYL 2 BUTANONE; 5 BENZYLOXY 1 HYDROXY 1 (4 METHOXYPHENYL) 4 METHYL 3 PENTANONE; 5 BENZYLOXY 1 HYDROXY 4 METHYL 1 (4 NITROPHENYL) 3 PENTANONE; 5 BENZYLOXY 1 HYDROXY 4 METHYL 1 PHENYL 3 PENTANONE; 5 BENZYLOXY 1,3 ISOPROPYLIDENEDIOXY 4 METHYL 1 PHENYLPENTANE; 5 METHYL 2 PHENYL 4 (2 PHENYL 2 OXOETHYL) 1,3 DIOXANE; ALDEHYDE; LEWIS ACID; TITANIUM; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHIRALITY; ENOLIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION TIME; STEREOCHEMISTRY;

EID: 80055098715     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo201021z     Document Type: Article

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