Comprehensive thermochemistry of W-H bonding in the metal hydrides CpW(CO)2(IMes)H, [CpW(CO)2(IMes)H]•+, and [CpW(CO)2(IMes)(H)2]+. Influence of an N-heterocyclic carbene ligand on metal hydride bond energies

Journal of the American Chemical Society

Volumn 133, Issue 37, 2011, Pages 14604-14613

  Roberts, John A S ^a   Appel, Aaron M ^a   Dubois, Daniel L ^a   Bullock, R Morris ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND ENERGIES; BOND-DISSOCIATION FREE ENERGIES; CHEMICAL EQUILIBRIUMS; DIHYDRIDES; DONOR ABILITY; ELECTROCHEMICAL DATA; ELECTRON DONORS; EXPERIMENTAL UNCERTAINTY; FREE ENERGY CHANGE; HIGH-PRESSURE NMR; HOMOLYSIS; HYDRIDE ABSTRACTION; LOWER BOND STRENGTH; METAL HYDRIDES; N-HETEROCYCLIC CARBENE LIGANDS; PHOSPHINE COMPLEX; RADICAL CATIONS; SCAN RATES; TUNGSTEN COMPLEX;

CARBON INORGANIC COMPOUNDS; CHEMICAL BONDS; COMPLEXATION; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL OXIDATION; ELECTRONS; EXPERIMENTS; FREE ENERGY; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; POSITIVE IONS; THERMOCHEMISTRY; TUNGSTEN; TUNGSTEN COMPOUNDS;

HYDRIDES;

1,3 BIS(2,4,6 TRIMETHYLPHENYL)IMIDAZOL 2 YLIDENE; CARBENE; CARBON DIOXIDE; CATION; HYDROGEN; IMIDAZOLE DERIVATIVE; LIGAND; METAL; PHOSPHINE; TUNGSTEN; UNCLASSIFIED DRUG;

ACIDITY; ARTICLE; CHEMICAL BOND; CYCLIC POTENTIOMETRY; DISSOCIATION; ELECTROCHEMISTRY; ELECTRON; ENERGY; EXPERIMENT; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PKA;

EID: 80052814349     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja202830w     Document Type: Article

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