Disproportionating versus nondisproportionating solvent effect in the SET-LRP of methyl acrylate during catalysis with nonactivated and activated cu(0) wire

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 49, Issue 19, 2011, Pages 4227-4240

  Nguyen, Nga H ^a   Percec, Virgil ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

disproportionation; kinetics; methyl acrylate; radical polymerization; single electron transfer living radical polymerization (SET LRP)

Indexed keywords

BROAD MOLECULAR WEIGHT DISTRIBUTION; COMPETING EFFECTS; DISPROPORTIONATIONS; ETHYLENE CARBONATE; FIRST ORDER KINETICS; HIGH FIDELITY; LIVING RADICAL POLYMERIZATION; METHYL ACRYLATES; RAPID ACTIVATION; RATE ENHANCEMENT; SET-LRP; SINGLE ELECTRON TRANSFER; SOLVENT EFFECTS;

ACRYLIC MONOMERS; ATOM TRANSFER RADICAL POLYMERIZATION; BROMINE COMPOUNDS; CATALYSIS; DIMETHYL SULFOXIDE; ELECTRON TRANSITIONS; ETHYLENE; FREE RADICAL POLYMERIZATION; FUNCTIONAL POLYMERS; KINETICS; MOLECULAR WEIGHT DISTRIBUTION; SINGLE ELECTRON TRANSISTORS; SOLVENTS; TRANSIENTS; WIRE;

LIVING POLYMERIZATION;

EID: 80052212426     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.24865     Document Type: Article

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