Implications of monomer and initiator structure on the dissociative electron-transfer step of SET-LRP

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 46, Issue 16, 2008, Pages 5663-5697

  Rosen, Brad M ^a   Percec, Virgil ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

Bond dissociation energy; Living radical polymerization; Molecular modeling; SET LRP; Single electron transfer

Indexed keywords

ACTIVATION BARRIERS; ALKYL HALIDES; BOND DISSOCIATION ENERGY; DISSOCIATION PATHWAYS; ELECTRON TRANSFERS; ELECTRON-RICH; ELECTRON-TRANSFER STEP; ELECTRON-WITHDRAWING; ELECTRON-WITHDRAWING GROUPS; ENERGY PROFILING; EQUILIBRIUM BOND LENGTH; GLOBAL MINIMUM; HETEROLYTIC DISSOCIATION; LIVING RADICAL POLYMERIZATION; LOCAL MINIMUMS; MACRO-RADICALS; MOLECULAR MODELING; POSITIVE CHARGE DENSITY; RADICAL PAIRS; RATE ENHANCEMENT; SET-LRP; SINGLE ELECTRON-TRANSFER; SINGLE ELECTRONS; VINYL HALIDES;

ALKYLATION; BOND LENGTH; CHARGE DENSITY; CHEMICAL REACTIONS; DISSOCIATION; ELECTRONS; IONS; LIVING POLYMERIZATION; MONOMERS; PHOTODISSOCIATION; POLYMERS; POLYSILANES; STYRENE; TURBULENT FLOW;

ACTIVATION ENERGY;

EID: 49149126512     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.22888     Document Type: Article

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