Complexes containing phosphorus and arsenic as terminal ligands

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 21, 1996, Pages 2492-2496

  Scheer, Manfred ^a   Müller, Jan ^a   Häser, Marco ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Arsenido complexes; Complexes with elements of group 15; Phosphido complexes; Tungsten compounds

Indexed keywords

EID: 0030460899     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199624921     Document Type: Article

References (29)

1. M. Scheer, S. Gremler, E. Herrmann, U. Grünhagen, M. Dargatz, E. Kleinpeter, Z. Anorg. Allg. Chem. 1991, 600, 203-210;
2. M. Scheer, F. Uhlig, T. T. Nam, M. Dargatz, H.-D. Schädler, E. Herrmann, ibid. 1990, 585, 177-188;
3. M. Scheer, S. Gremler, E. Herrmann, P. G. Jones, J. Organomet. Chem. 1991, 414, 337-349;
4. M. Scheer, S. Gremler, Z. Anorg. Allg. Chem. 1993, 619, 471-475.
5. K. Schuster, Diplomarbeit, Universität Halle-Wittenberg, 1991; M. Scheer, K. Schuster, J. Müller, E. Matern, unpublished results.
6. K.-Y. Shih, K. Totland, S. W. Seidel, R. R. Schrock, J. Am. Chem. Soc. 1994, 116, 12103.
7. Z. Duan, J. G. Verkade, Inorg. Chem. 1995, 34, 1576-1578.
8. N. Zanetti, R. R. Schrock, W. M. Davis, Angew. Chem. 1995, 107, 2184-2186; Angew. Chem. Int. Ed. Engl. 1995, 34, 2044-2046.
9. N. Zanetti, R. R. Schrock, W. M. Davis, Angew. Chem. 1995, 107, 2184-2186; Angew. Chem. Int. Ed. Engl. 1995, 34, 2044-2046.
10. C. E. Laplaza, W. M. Davis, C. C. Cummins, Angew. Chem. 1995, 107, 2181-2183; Angew. Chem. Int. Ed. Engl. 1995, 34, 2042-2043.
11. C. E. Laplaza, W. M. Davis, C. C. Cummins, Angew. Chem. 1995, 107, 2181-2183; Angew. Chem. Int. Ed. Engl. 1995, 34, 2042-2043.
12. M. Scheer, K. Schuster, T. A. Budzichowski, M. H. Chisholm, W. E. Streib, J. Chem. Soc. Chem. Commun. 1995, 1671-1672.
13. Highlight: M. Scheer, Angew. Chem. 1995, 107, 2151-2153; Angew. Chem. Int. Ed. Engl. 1995, 34, 1997-1999; some of the results were presented in a lecture: M. Scheer, lecture at the 211th ACS Meeting, New Orleans 1996, see INOR 222 in the book of abstracts.
14. Highlight: M. Scheer, Angew. Chem. 1995, 107, 2151-2153; Angew. Chem. Int. Ed. Engl. 1995, 34, 1997-1999; some of the results were presented in a lecture: M. Scheer, lecture at the 211th ACS Meeting, New Orleans 1996, see INOR 222 in the book of abstracts.
15. Highlight: M. Scheer, Angew. Chem. 1995, 107, 2151-2153; Angew. Chem. Int. Ed. Engl. 1995, 34, 1997-1999; some of the results were presented in a lecture: M. Scheer, lecture at the 211th ACS Meeting, New Orleans 1996, see INOR 222 in the book of abstracts.
16. 2, evidently caused by hydrolysis at the inner wall of the tube, remain constant.
17. R. R. Schrock, lecture at the 211th ACS Meeting, New Orleans 1996, see INOR 517 in book of abstracts.
18. 31P NMR spectroscopy between -40°C and ambient temperature. Intensities of the products showed that the complexes 7 are only intermediates; complexes 8 are formed as the main products with an increase in temperature and time. After 48 h 8 is formed quantitatively.
19. +.
20. R. R. Schrock, personal communication; J. A. Johnson-Carr, N. Zanetti, R. R. Schrock, M. D. Hopkins, J. Am. Chem. Soc., in press.
21. R. R. Schrock, personal communication; J. A. Johnson-Carr, N. Zanetti, R. R. Schrock, M. D. Hopkins, J. Am. Chem. Soc., in press.
22. 2 = 0.1278. All calculations were performed by using the SHELXS-86 [29], SHELXL-93 [29] and Schakal-92 programs. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344, Eggenstein-Leopoldshafen, on quoting the depository numbers CSD-405518, CSD-405519, and CSD-405520.
23. F. A. Cotton, D. J. Darensbourg, B. W. S. Kolthammer, Inorg. Chem. 1981, 20, 4440-4442.
24. E. Fluck, P. Kuhn, A. Müller, H. Bögge, Z. Anorg. Allg. Chem. 1988, 567, 13-22.
25. The analysis of bonding was based on Kohn-Sham Orbitals from the B-P86/SVP calculations. Conclusions regarding electronic delocalization remain valid only in as far as electronic correlations are of minor importance.
26. F. Uhlig, S. Gremler, M. Dargatz, M. Scheer, E. Herrmann, Z. Anorg. Allg. Chem. 1991, 606, 105-103.
27. G. Becker, G. Gutekunst, H.-J. Wessely, Z. Anorg. Allg. Chem. 1980, 462, 113-129.
28. G. M. Sheldrick, SHELXS-86, Universität Göttingen, 1986; SHELXL-93, Universität Göttingen, 1993.
29. G. M. Sheldrick, SHELXS-86, Universität Göttingen, 1986; SHELXL-93, Universität Göttingen, 1993.