Large-area graphene films by simple solution casting of edge-selectively functionalized graphite

ACS Nano

Volumn 5, Issue 6, 2011, Pages 4974-4980

  Bae, Seo Yoon ^a   Jeon, In Yup ^a   Yang, Jieun ^a   Park, Noejung ^a   Shin, Hyeon Suk ^a   Park, Sungjin ^b   Ruoff, Rodney S ^c   Dai, Liming ^d   Baek, Jong Beom ^a  

^a Ulsan National Institute of Science and Technology   (South Korea)

^b Inha University   (South Korea)

^c The University of Texas at Austin   (United States)

^d Case Western Reserve University   (United States)

Author keywords

annealing; edge selective functionalization; graphene film; optical transmittance; sheet resistance; solution processing

Indexed keywords

ELECTRICALLY CONDUCTIVE; FUNCTIONALIZATIONS; FUNCTIONALIZED; SCALABLE PRODUCTION; SILICON OXIDE SUBSTRATES; SOLUTION CASTING; SOLUTION PROCESSING;

CONDUCTIVE FILMS; DICHLOROMETHANE; ELECTRIC RESISTANCE; GRAPHENE; GRAPHITE; OPACITY; OXIDE FILMS; PROCESSING; SHEET RESISTANCE; SILICON COMPOUNDS; SILICON OXIDES; TRANSPORT PROPERTIES;

OPTICAL FILMS;

GRAPHITE; NANOMATERIAL;

ARTICLE; ATOMIC FORCE MICROSCOPY; CHEMISTRY; CRYSTALLIZATION; ELECTRIC CONDUCTIVITY; ELECTROCHEMISTRY; METHODOLOGY; NANOTECHNOLOGY; OPTICS; SCANNING ELECTRON MICROSCOPY; SURFACE PROPERTY;

CRYSTALLIZATION; ELECTRIC CONDUCTIVITY; ELECTROCHEMISTRY; GRAPHITE; MICROSCOPY, ATOMIC FORCE; MICROSCOPY, ELECTRON, SCANNING; NANOSTRUCTURES; NANOTECHNOLOGY; OPTICS AND PHOTONICS; SURFACE PROPERTIES;

EID: 79959776290     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn201072m     Document Type: Article

References (28)

1. Lee, C.; Wei, X.; Kysar, J. W.; Hone, J. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Science 2008, 321, 385-388 (Pubitemid 352029970)
2. Balandin, A. A.; Ghosh, S.; Bao, W.; Calizo, I.; Teweldebrhan, D.; Miao, F.; Lau, C. N. Superior Thermal Conductivity of Single-layer Graphene Nano Lett. 2008, 8, 902-907
3. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric Field in Atomically Thin Carbon Films Science 2004, 306, 666-669 (Pubitemid 39440910)
4. Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Graphene-Based Composite Materials Nature 2006, 442, 282-286 (Pubitemid 44114900)
5. Stoller, M. D.; Park, S.; Yanwu, Z.; An, J.; Ruoff, R. S. Graphene-Based Ultracapacitors Nano Lett. 2008, 8, 3498-3502
6. Mohanty, N.; Berry, V. Graphene-Based Single-Bacterium Resolution Biodevice and DNA Transistor: Interfacing Graphene Derivatives with Nanoscale and Microscale Biocomponents Nano Lett. 2008, 8, 4469-4476
7. Freitag, M. Graphene: Nanoelectronics Goes Flat Out Nat. Nanotechnol. 2008, 3, 455-457
8. Geim, A. K.; Novoselov, K. S. The Rise of Graphene Nat. Mater. 2007, 6, 183-191 (Pubitemid 46353764)
9. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Two-dimensional Gas of Massless Dirac Fermions in Graphene Nature 2005, 438, 197-200 (Pubitemid 41599867)
10. Kim, K. S.; Zhao, Y.; Jang, H.; Lee, S. Y.; Kim, J. M.; Ahn, J. H.; Kim, P.; Choi, J. Y.; Hong, B. H. Large-Scale Pattern Growth of Graphene Films for Stretchable Transparent Electrodes Nature 2009, 457, 706-710
11. Minami, T. Transparent Conducting Oxide Semiconductors for Transparent Electrodes Semicond. Sci. Technol. 2005, 20, S35-S44
12. Bae, S.; Kim, H.; Lee, Y.; Xu, X.; Park, J. S.; Zheng, Y.; Balakrishnan, J.; Lei, T.; Ri Kim, H.; Song, Y. I. et al. Roll-to-roll Production of 30-in. Graphene Films for Transparent Electrodes Nat. Nanotechnol. 2010, 5, 574-578
13. Li, X.; Cai, W.; An, J.; Kim, S.; Nah, J.; Yang, D.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E. et al. Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Science 2009, 324, 1312-1314
14. De, S.; Coleman, J. N. Are There Fundamental Limitations on the Sheet Resistance and Transmittance of Thin Graphene Films? 2010, 5, 2713-2720.
15. Hummers, W. S., Jr.; Offeman, R. E. Preparation of Graphitic Oxide J. Am. Chem. Soc. 1958, 80, 1339
16. Boukhvalov, D. W.; Katsnelson, M. I. Modeling of Graphite Oxide J. Am. Chem. Soc. 2008, 130, 10697-10701
17. Choi, E. K.; Jeon, I. Y.; Bae, S.-Y.; Shin, H. S.; Dai, L.; Baek, J. B. High-Yield Exfoliation of the Three-Dimensional Graphite into Graphene-like Sheets Chem. Commun. 2010, 46, 6320-6322
18. Chen, J.; Shan, J. Y.; Tsukada, T.; Munekane, F.; Kuno, A.; Matsuo, M.; Hayashi, T.; Kim, Y. A.; Endo, M. The Structural Evolution of Thin Multiwalled Carbon Nanotubes during Isothermal Annealing Carbon 2007, 45, 274-280 (Pubitemid 44879398)
19. Stankovich, S.; Piner, R. D.; Chen, X.; Wu, N.; Nguyen, S. T.; Ruoff, R. S. Stable Aqueous Dispersions of Graphitic Nanoplatelets via the Reduction of Exfoliated Graphite Oxide in the Presence of Poly(sodium 4-styrenesulfonate) J. Mater. Chem. 2006, 16, 155-158 (Pubitemid 43324471)
20. Suslick, K. S. Sonochemistry Science 1990, 247, 1439-1445 (Pubitemid 120007653)
21. Hernandez, Y.; Nicolosi, V.; Lotya, M.; Blighe, F. M.; Sun, Z.; De, S.; McGovern, I. T.; Holland, B.; Byrne, M.; Gunko, Y. K. et al. High-Yield Production of Graphene by Liquid-Phase Exfoliation of Graphite Nat. Nanotechnol. 2008, 3, 563-568
22. Li, X.; Wang, H.; Robinson, J. T.; Sanchez, H.; Diankov, G.; Dai, H. Simultaneous Nitrogen Doping and Reduction of Graphene Oxide J. Am. Chem. Soc. 2009, 131, 15939-15944
23. Blake, P.; Hill, E. W.; Castro Neto, A. H.; Novoselov, K. S.; Jiang, D.; Yang, R.; Booth, T. J.; Geim, A. K. Making Graphene Visible Appl. Phys. Lett. 2007, 91
24. Stolyarova, E.; Kwang, T. R.; Ryu, S.; Maultzsch, J.; Kim, P.; Brus, L. E.; Heinz, T. F.; Hybertsen, M. S.; Flynn, G. W. High-Resolution Scanning Tunneling Microscopy Imaging of Mesoscopic Graphene Sheets on an Insulating Surface Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 9209-9212 (Pubitemid 47185759)
25. Gao, W.; Alemany, L. B.; Ci, L.; Ajayan, P. M. New Insights into the Structure and Reduction of Graphite Oxide Nat. Chem. 2009, 1, 403-408
26. Park, S.; Ruoff, R. S. Chemical Methods for the Production of Graphenes Nat. Nanotechnol. 2009, 4, 217-224
27. Heersche, H. B.; Jarillo-Herrero, P.; Oostinga, J. B.; Vandersypen, L. M. K.; Morpurgo, A. F. Bipolar Supercurrent in Graphene Nature 2007, 446, 56-59 (Pubitemid 46350681)
28. Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set Phys. Rev. B 1996, 54, 11169-11186