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This intensity ratio can be observed if the carrier frequency (O1) is taken just at the same distance of the central peak and one of the satellite peaks, i.e., 0 ppm, see insert of Figure 2. (The homogeneous excitation profile cannot be managed due to the huge spectral window needed to record the "quasitriplet", but the above-mentioned position of the carrier frequency ensures equal excitation of the two signals shown in the insert.)
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This intensity ratio can be observed if the carrier frequency (O1) is taken just at the same distance of the central peak and one of the satellite peaks, i.e., 0 ppm, see insert of Figure 2. (The homogeneous excitation profile cannot be managed due to the huge spectral window needed to record the "quasitriplet", but the above-mentioned position of the carrier frequency ensures equal excitation of the two signals shown in the insert.)
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-1 characteristic of the Pt-Tl bond in aqueous solution cannot be observed in dmso. The absence of the Raman band might be a consequence of the lowered symmetry of the Pt-Tl bonded complex in dmso compared to the related species in an aqueous system.
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205Tl NMR spectra had been recorded at least one day after mixing.
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205Tl NMR spectra had been recorded at least one day after mixing.
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