Novel Pentacyano Complexes of Tri-and Tetravalent Platinum

Inorganic Chemistry

Volumn 37, Issue 21, 1998, Pages 5452-5459

  Maliarik, Mikhail ^a   Glaser, Julius ^b   Tóth, Imre ^c  

^a KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^b ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^c UNIVERSITY OF DEBRECEN   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000084330     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980186r     Document Type: Article

References (61)

1. Sharpe, A. G. The Chemistry of Cyano Complexes of Transition Metals: Academic Press: London, 1976.
2. Weiss, J. Z. Naturforsch. B: Anorg. Chem. 1974, 29B, 119.
3. Siebert, H.; Weise, M. Z. Naturforsch. 1975, 30B, 33-39.
4. Yanovskii, A. I.; Vaskes, K. K.; Babkov, A. V.; Antipin, M. Y.; Struchkov, Y. T. Koord. Khim. 1984, 10, 1706.
5. Weigand, W.; Nagel, U.; Beck, W. Z. Naturforsch. B: Anorg. Chem. 1988, 438, 328.
6. Potekhin, K. A.; Maleev, A. V.; Babkov, A. V.; Struchkov, Y. T. Koord. Khim. 1989, 15, 974.
7. Miller, J. S.; Epstein, A. J. Prog. Inorg. Chem. 1976, 20, 1.
8. Babkov, A. V. Dokl. Akad. Nauk SSSK 1967, 177, 337-339.
9. Busev, A. I.; Babkov, A. V.; Busurmanovu, B. T. Kinet. Kutal. 1973, 14, 1154.
10. Osso, R.; Rund, J. V. J. Coord. Chem, 1978, 8, 169.
11. Busev, A. I.; Babkov, A. V.; Busurmanovu, B. T. Kinet. Katal. 1975, 16, 45.
12. Baranovskii, I. B.; Babaeva, A. V. Russ. J. Inorg. Chem. 1966, 11, 926.
13. Brown, C.; Heaton, B. T.; Sabounchei, J. J. Organomet. Chem. 1977, 142, 413-421.
14. Baranovskii, I. B.; Evstafeva, O. N.; Babaeva, A. V. Doki. Akad. Nauk SSSR 1965, 163, 642.
15. Memering, M. N.; Jones, L. H.; Bailor, J. C. Inorg. Chem. 1973, 12, 2793-2801.
16. Griffith, W. P.; Mockford, M. J.; Skapski, A. C. Inorg. Chim. Acta 1987, 126, 179-186.
17. Piccinin, A.; Toussaint, J. Bull. Soc. R. Sci. 1967, 36, 122-126.
18. Levy, L. A. J. Chem. Soc. 1912, 101, 1081.
19. Berg, K. E.; Glaser, J.; Read, M. C.; Tóth, I. J. Am. Chem. Soc. 1995, 117, 7550-7551.
20. Maliarik, M.; Berg, K.; Glaser, J.; Sandstrom, M.; Tóth, I. Inorg. Chem. 1998, 37, 2910-2919.
21. Maliarik, M.; Glaser, J.; Tóth, I.; Webba da Silva, M.; Zékány, L. Eur. J. Inorg. Chem. 1998, 565-570.
22. Biedermann, G. Arkiv Kemi 1953, 441.
23. Blixt, J.; Györi, B.; Glaser, J. J. Am. Chem. Soc. 1989, 111, 7784-7791.
24. Irving, H. M.; Miles, M. G.; Petit, L. D. Anal. Chim. Acta 1967, 38, 475-488.
25. Pregosin, P. S. Transition Metal Nuclear Magnetic Resonance; Elsevier: Amsterdam, 1991; Vol. 13, p 351.
26. Goodfellow, R. G. In Multinuclear NMR; Mason, J., Ed.; Plenum Press; New York, 1987; pp 521-561.
27. 2- signal is observed.
28. Appleton, T. G.; Hall, J. R.; Neale, D. W. Inorg. Chim. Acta 1985, 104, 19-31.
29. Appleton, T. G.; Byriel, K. A.; Garrett, J. M.; Hall, J. R.; Kennard, C. H. L.; Mathieson, M. T.; Stranger, R. Inorg. Chem. 1995, 34, 5646-5655.
30. Appleton, T. G.; Barnham, K. J.; Byriel, K. A.; Hall, J. R.; Kennard, C. H. L.; Mathieson, M. T.; Penman, K. G. Inorg. Chem. 1995, 34, 6040-6052.
31. Che, C.-M.; Schaefer, P.; Gray, H. B. J. Am. Chem. Soc. 1982, 104, 4253-4255.
32. (a) Some other polynuclear platinum compounds with the metaloxidation state 0 or +1 exhibit also second-order NMR spectra, see rets 32b-d.
33. (b) Green, M.; Howard, J. A. K.; Murray, M.; Spencer, J. L.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1977, 1509-1514.
34. Kiffen, A. A.; Masters, C.; Visser, J. P. J. Chem. Soc., Dalton Trans. 1975, 1311-1315.
35. Boag, N. M.; Browning, J.; Crocker, C.; Goggin, P. L.; Goodfellow, R. J.; Murray, M.; Spencer, J. L. J. Chem. Res. (M) 1978, 2962-2983.
36. NMR spectra of the studied Pt-CN solution recorded at different magnetic fields (SF = 42.8 and 85.6 MHz) result in the same multiplet type confirming that it is not an exact superposition of separate multiplets at both chemical shifts.
37. Prenzler, P. D.; Heath, G. A.; Lee, S. B.; Raptis, R. G. Chem. Commun. 1996, 2271-2272.
38. Umakoshi, K.; Sasaki, Y. Adv. Inorg. Chem. 1994, 40, 187-239.
39. Cotton, F. A.; Walton, R. A. Multiple Bonds between Metal Atoms, 2nd ed.; Clarendon Press: Oxford, 1993; p 787.
40. Cini, R.; Fanizzi, F. P.; Intini, F. P.; Natile, G. J. Am. Chem. Soc. 1991, 113, 7805-7806.
41. Baxter, L. A. M.; Heath, G. A.; Raptis, R. G.; Willis, A. C. J. Am. Chem. Soc. 1992, 114, 6944-6946.
42. Paul, R. L. Thesis, Australian National University, 1996.
43. Due to superposition of at least two spin systems, overlapping peaks do not allow this value to be refined with better accuracy than 100 Hz.
44. (a) Stranger, R.; Nissen, S. C.; Mathieson, T.; Appleton, T. G. Inorg. Chem, 1997, 36,937-939.
45. (b) Crouch, E. C. C.; Pratt, J. M. J. Chem. Soc., Chem. Commun. 1969, 1243-1244.
46. Simon, G. L.; Adamson, A. W.; Dahl, L. F. J. Am. Chem. Soc. 1972, 94, 7654-7663.
47. Brown, L. D.; Raymond, K. N.; Goldberg, S. Z. J. Am. Chem. Soc. 1972, 94, 7664-7674.
48. 2- the decomposition reaction is so fast (a few minutes) that in some cases not even Pt-Tl-Pt could be detected, only Pt-Pt.
49. 3-. Currently, we are studying if the photochemical decomposition of the binuclear compounds can be related to this equilibrium.
50. 2- can be detected in the solutions containing excess of cyanide ion.
51. (b) Chernyaev, I. I.; Babkov, A. V. Dokl. Akad. Nauk SSSR 1963, 152, 882.
52. -.
53. 6 complexes prefer six-coordinate geometry.
54. Shipachev, V. A.; Zemskov, S. V.; Al't, L. Y. Koord. Khim. 1980, 6, 932-935.
55. Carr, C.; Goggin, P. L.; Goodfellow, R. Inorg. Chim. Acta 1984, 81, L25-26.
56. - ion.
57. 2- is kinetically hindered.
58. (b) Babkov, A. V. Dokl. Akad. Nauk 1981, 267, 889-891.
59. 13,16
60. (a) Levin, A. A.; Dyachkov, P. N. Electronic Structure, Geometry, Isomerism ana Transformations in Hereroligand Molecules; Nauka: Moscow, 1990; p 256.
61. 5X] compounds, cf. ref 19.