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Volumn 42, Issue 21, 2003, Pages 6907-6914

Kinetics and Mechanism of Formation of the Platinum-Thallium Bond: The [(CN)5Pt-Tl(CN)3]3- Complex

Author keywords

[No Author keywords available]

Indexed keywords

CYANIDE; METAL; PLATINUM COMPLEX; THALLIUM;

EID: 10744233745     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034676h     Document Type: Article
Times cited : (5)

References (53)
  • 22
    • 0142133802 scopus 로고    scopus 로고
    • note
    • In the following text, square brackets, [], are consequently used to indicate actual concentration in the kinetic equations or equlibrium concentrations in the formation constants when the charges are inside and mark complexes when the charges are outside.
  • 23
    • 0142133803 scopus 로고    scopus 로고
    • note
    • - stand for the apparent forward and reverse rate constants of reaction 1 throughout this paper and are dependent on the conditions applied.
  • 26
    • 0142038594 scopus 로고    scopus 로고
    • note
    • -1. This value is about two times higher than the stability constant of the complex (reaction 1). However, this seems to still be in an acceptable agreement taking into account the experimental limitations, i.e., the limited applicable concentration ranges and the difficulties with controlling the pH in an unbuffered solution.
  • 30
    • 0001741394 scopus 로고
    • King, R. B., Ed.; John Willey & Sons: Chichester
    • Tóth, I.; Gyõri, B. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; John Willey & Sons: Chichester, 1995; Vol. 8, pp 4134-4142.
    • (1995) Encyclopedia of Inorganic Chemistry , vol.8 , pp. 4134-4142
    • Tóth, I.1    Gyõri, B.2
  • 31
    • 77954703707 scopus 로고
    • Sykes, A. G., Ed.; Advances in Inorganic Chemistry 43; Academic Press: San Diego
    • Glaser. J. Advances in Thallium Aqueous Solution Chemistry; Sykes, A. G., Ed.; Advances in Inorganic Chemistry 43; Academic Press: San Diego, 1995; pp 1-69.
    • (1995) Advances in Thallium Aqueous Solution Chemistry , pp. 1-69
    • Glaser, J.1
  • 49
    • 0142038596 scopus 로고    scopus 로고
    • note
    • 3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.