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+ species is outside the scope of this paper, to be published.
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note
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3CN) system is outside the scope of this paper.
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34
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85085783705
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note
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3 in the range 3.5-4.5 ppm, depending on the salt concentration.
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35
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85085784305
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note
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4 carbons of bipy coordinated to thallium have close values of chemical shift and collapse into one broad signal.
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36
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85085785264
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note
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205Tl NMR chemical shift of the solvated thallium(m) complexes is very sensitive to the change of solvent. Thus, the chemical shift of bis(bipy) species in acetonitrile is 2530 ppm compared to 2134 ppm in dimethyl sulfoxide.
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37
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85085783462
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note
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5Pt-Tl](s) and 2,2′-bipyridine in aqueous solution, followed by the solid product being dissolved in dimethyl sulfoxide (cf. the Experimental Section).
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85085784616
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note
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13C NMR signals of the various cyanide ligands was thoroughly discussed in a recent paper from this laboratory.3b
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85085783954
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note
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n- in dmso appear at 1602, 2007, and 2148 ppm for n = 1, 2, and 3, respectively.
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n- shows that, in a full model, taking into account all (both metal-metal and metal-ligand) vibrational modes, about 92% is attributed to the purely diatomic Pt-Tl stretch.3b,c
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