Synthesis and reactivity of a transition metal complex containing exclusively TEMPO ligands: Ni(η2-TEMPO)2

Inorganic Chemistry

Volumn 50, Issue 13, 2011, Pages 5864-5866

  Isrow, Derek ^a   Captain, Burjor ^a  

^a University of Miami   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE OXIDE; LIGAND; NICKEL; ORGANOMETALLIC COMPOUND; TEMPO;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; STEREOISOMERISM; SYNTHESIS;

CYCLIC N-OXIDES; LIGANDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NICKEL; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 79959735671     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic2007342     Document Type: Article

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42. Alternatively, a mechanism based on the oxidative addition of HCCPh could also occur, followed by H atom migration to the nitrogen of TEMPO. This mechanism is not preferred, because oxidative addition would entail that the H and CCPh groups add on to give an octahedral complex as an intermediate which would be highly strained, as the methyl groups of TEMPO shield the Ni atom (axial sites), as seen in Figure 4.