Coordination-induced spin crossover (CISCO) through axial bonding of substituted pyridines to nickel-porphyrins: σ-Donor versus π-acceptor effects

Chemistry - A European Journal

Volumn 16, Issue 33, 2010, Pages 10074-10083

  Thies, Steffen ^a   Bornholdt, Claudia ^a   Köhler, Felix ^a   Sönnichsen, Frank D ^a   Näther, Christian ^a   Tuczek, Felix ^a   Herges, Rainer ^a  

^a UNIVERSITY OF KIEL   (Germany)

Author keywords

Donor acceptor systems; Nickel; Porphyrinoids; Pyridine; Spin crossover

Indexed keywords

ASSOCIATION CONSTANT; ASSOCIATION ENTHALPY; AXIAL LIGAND; BACK DONATION; BINDING ENTHALPIES; COORDINATION FRAMEWORKS; CYANOPYRIDINES; DIFFERENT ORDER; DIMETHYLAMINOPYRIDINE; DONOR-ACCEPTOR SYSTEM; INTERNAL ROTATIONS; IR SPECTROSCOPY; METAL CENTERS; NITROPYRIDINE; NMR SPECTROSCOPY; ORBITALS; PENTAFLUOROPHENYL; PORPHYRINOIDS; SPIN CROSSOVERS; SPIN TRANSITION; TEMPERATURE DEPENDENT; THERMODYNAMIC PARAMETER; WAVE NUMBERS; X-RAY STRUCTURE;

ENTHALPY; ENTROPY; EQUILIBRIUM CONSTANTS; NICKEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PORPHYRINS; PYRIDINE;

ORGANIC POLYMERS;

METALLOPORPHYRIN; NICKEL; PYRIDINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON SPIN RESONANCE; KINETICS; METHODOLOGY; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; KINETICS; METALLOPORPHYRINS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NICKEL; PYRIDINES;

EID: 77956096680     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000603     Document Type: Article

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