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Volumn 48, Issue 5, 2009, Pages 2215-2223

Synthesis and reactions of mono- and dinuclear Ni(I) thiolate complexes

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; AMINE OXIDE; CARBENE; DRUG DERIVATIVE; HETEROCYCLIC COMPOUND; METHANE; NICKEL; ORGANOMETALLIC COMPOUND; TEMPO; THIOL DERIVATIVE;

EID: 64549114151     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic802276w     Document Type: Article
Times cited : (69)

References (59)
  • 1
    • 84954622546 scopus 로고    scopus 로고
    • Sigel, A, Sigel, H, Sigel, R. K. O, Eds, John Wiley & Sons, Ltd, Chichester, U.K, Metal Ions in Life Science
    • Nickel and Its Surprising Impact in Nature; Sigel, A., Sigel, H., Sigel, R. K. O., Eds.; John Wiley & Sons, Ltd.: Chichester, U.K., 2007; Metal Ions in Life Science, Vol. 2.
    • (2007) Nickel and Its Surprising Impact in Nature , vol.2
  • 3
    • 0000151612 scopus 로고
    • (a) Stile, M. J. Org. Chem. 1994, 59, 5381-5385.
    • (1994) J. Org. Chem , vol.59 , pp. 5381-5385
    • Stile, M.1
  • 22
    • 12244255093 scopus 로고    scopus 로고
    • -1. See: (a) Craft, J. L.; Mandimutsira, B. S.; Fujita, K.; Riordan, C. G.; Brunold, T. C. Inorg. Chem. 2003, 42, 859-867.
    • -1. See: (a) Craft, J. L.; Mandimutsira, B. S.; Fujita, K.; Riordan, C. G.; Brunold, T. C. Inorg. Chem. 2003, 42, 859-867.
  • 34
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Göttingen, Germany
    • Sheldrick, G. M. SHELX97; University of Göttingen: Göttingen, Germany, 1997.
    • (1997) SHELX97
    • Sheldrick, G.M.1
  • 40
    • 64549127678 scopus 로고    scopus 로고
    • The Ni-C(18) and Ni-C(21) distances, 2.529(2) and 2.538(2) Å, are substantially longer than those of the Ni-C(16) and Ni-C(17) bonds.
    • The Ni-C(18) and Ni-C(21) distances, 2.529(2) and 2.538(2) Å, are substantially longer than those of the Ni-C(16) and Ni-C(17) bonds.
  • 41
    • 64549153513 scopus 로고    scopus 로고
    • Only a poor simulation for the complicated hyperfine coupling appearing at 77 K could be attained, even considering the interactions of the unpaired electron with only the other nuclei of the ligands including the phosphorous and the protons in the η-mesityl group. It may suggest substantial delocalization of the unpaired Ni d electron over the ligands. The EPR spectrum is shown in the Supporting Information.
    • Only a poor simulation for the complicated hyperfine coupling appearing at 77 K could be attained, even considering the interactions of the unpaired electron with only the other nuclei of the ligands including the phosphorous and the protons in the η-mesityl group. It may suggest substantial delocalization of the unpaired Ni d electron over the ligands. The EPR spectrum is shown in the Supporting Information.
  • 43
    • 64549104545 scopus 로고    scopus 로고
    • See the Supporting Information for the structural details of 6
    • See the Supporting Information for the structural details of 6.
  • 50
    • 64549156014 scopus 로고    scopus 로고
    • 2 (9) was confirmed by X-ray structural analysis. The structural details are described in the Supporting Information. Power and coworkers have reported a similar Ni(II) thiolate.
    • 2 (9) was confirmed by X-ray structural analysis. The structural details are described in the Supporting Information. Power and coworkers have reported a similar Ni(II) thiolate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.