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We assume that 4-fluorostyrene facilitates the reductive elimination step during the catalytic cycle. Its presence is essential for the Cl/Zn-exchange. Apparently, 4-fluorostyrene is not consumed during the reaction, as shown by GC analysis using an internal standard
-
We assume that 4-fluorostyrene facilitates the reductive elimination step during the catalytic cycle. Its presence is essential for the Cl/Zn-exchange. Apparently, 4-fluorostyrene is not consumed during the reaction, as shown by GC analysis using an internal standard.
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47
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note
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2Zn(Oct)MgCl as an exchange reagent we have observed a constant increase of the formation of octene during the course of the reaction. This elimination was observed only if an organic chloride is added to the mixture of the exchange reagent (zincate) and the catalytic system.
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