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Volumn 127, Issue 35, 2005, Pages 12236-12237

Cycloisomerization of enynes catalyzed by iron(0)-ate complexes

Author keywords

[No Author keywords available]

Indexed keywords

FERROCENE; IRON COMPLEX;

EID: 24644523532     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0532739     Document Type: Article
Times cited : (76)

References (41)
  • 24
    • 24644448066 scopus 로고    scopus 로고
    • note
    • It should be mentioned that the available mechanistic information does not allow us to rule alternative mechanisms out. Notably, the formation of allyliron species (by allylic C-H activation) instead of the putative metallacyclic intermediates could also explain the observed results.
  • 37
    • 0037125488 scopus 로고    scopus 로고
    • and literature cited therein
    • (d) [Rh]: Lei, A.; He, M.; Zhang, X. J. Am. Chem. Soc. 2002, 124, 8198 and literature cited therein.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 8198
    • Lei, A.1    He, M.2    Zhang, X.3
  • 39
    • 24644499263 scopus 로고    scopus 로고
    • note
    • For the assignment of the stereochemistry, cf. Supporting Information.
  • 40
    • 0001760155 scopus 로고
    • Precedence for the stereochemical switch from cis to trans on going to larger ring sizes is found in organopalladium chemistry, cf: Trost, B. M.; Grese, T. A. J. Am. Chem. Soc. 1991, 113, 7363.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 7363
    • Trost, B.M.1    Grese, T.A.2
  • 41
    • 24644496955 scopus 로고    scopus 로고
    • note
    • GC investigations show that the E-isomer does not result from equilibration but is the primary product of the reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.