Probing the intrinisic structure and dynamics of aminoborane coordination at late transition metal centers: Mono(σ-BH) binding in [CpRu(PR 3)2(H2BNCy2)]+

Journal of the American Chemical Society

Volumn 133, Issue 22, 2011, Pages 8494-8497

  Vidovic, Dragoslav ^a,b   Addy, David A ^a,b   Krämer, Tobias ^a,b   McGrady, John ^a,b   Aldridge, Simon ^a,b  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b Nanyang Technological University   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

AMINOBORANES; ANCILLARY LIGANDS; BACK-BONDING; BUILDING BLOCKES; DINITROGEN COMPLEXES; EXCHANGE DYNAMICS; GROUND-STATE STRUCTURES; LATE TRANSITION METALS; METAL CENTERS; POLYMERIC MATERIAL; STRUCTURE AND DYNAMICS;

OLEFINS; PHOSPHORUS COMPOUNDS; TRANSITION METALS;

BINDING ENERGY;

ALKENE; AMINOBORANE; BORANE DERIVATIVE; BORON; COORDINATION COMPOUND; HYDROGEN; LIGAND; NITROUS OXIDE; PHOSPHINE; POLYMER; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON; ELECTRONICS; ENERGY TRANSFER; ISOELECTRONIC; MOLECULAR DYNAMICS; MOLECULAR PROBE; POLYMERIZATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 79957985716     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja203051d     Document Type: Article

References (51)

1. For recent reviews of relevant BN-containing materials, see: Clark, T. J.; Lee, K.; Manners, I. Chem. Eur. J. 2006, 12, 8634-8648
2. Marder, T. B. Angew. Chem., Int. Ed. 2007, 46, 8116-8118
3. Stephens, F. H.; Pons, V.; Baker, R. T. Dalton Trans. 2007, 2613-2626
4. Hamilton, C. W.; Baker, R. T.; Staubitz, A.; Manners, I. Chem. Soc. Rev. 2009, 38, 279-293
5. Staubitz, A.; Robertson, A. P. M.; Sloan, M. E.; Manners, I. Chem. Rev. 2010, 110, 4023-4078
6. Staubitz, A.; Robertson, A. P. M.; Manners, I. Chem. Rev. 2010, 110, 4079-4124
7. Alcaraz, G.; Sabo-Etienne, S. Angew. Chem., Int. Ed. 2010, 49, 7170-7179
8. Staubitz, A.; Soto, A. P.; Manner, I. Angew. Chem., Int. Ed. 2008, 47, 6212-6214
9. Staubitz, A.; Sloan, M. E.; Robertson, A. P. M.; Friedrich, A.; Schneider, S.; Gates, P. J.; auf der Günne, J. M.; Manners, I. J. Am. Chem. Soc. 2010, 132, 13332-13345
10. For an early spectroscopic report examining aminoborane interactions with transition metals, see: Schmid, G. Chem. Ber. 1970, 103, 528-533
11. Pons, V.; Baker, R. T.; Szymczak, N. K.; Heldebrant, D. J.; Lineham, J. C.; Matus, M. H.; Grant, D. J.; Dixon, D. A. Chem. Commun. 2008, 6597-6599
12. Alcaraz, G.; Vendier, L.; Clot, E.; Sabo-Etienne, S. Angew. Chem., Int. Ed. 2010, 49, 918-920
13. Tang, C. Y.; Thompson, A. L.; Aldridge, S. Angew. Chem., Int. Ed. 2010, 49, 921-925
14. Tang, C. Y.; Thompson, A. L.; Aldridge, S. J. Am. Chem. Soc. 2010, 132, 10578-10591
15. Alcaraz, G.; Chaplin, A. B.; Stevens, C. J.; Clot, E.; Vendier, L.; Weller, A. S.; Sabo-Etienne, S. Organometallics 2010, 29, 5591-5595
16. Stevens, C. J.; Dallanegra, R.; Chaplin, A. B.; Weller, A. S.; Macgregor, S. A.; Ward, B.; McKay, D.; Alcaraz, G.; Sabo-Etienne, S. Chem. Eur. J. 2011, 17, 3011-3020
17. For studies of catalytic systems for the dehydrogenation of B/N-based materials based on group 9 metals, see, for example: Jaska, C. A.; Temple, K.; Lough, A. J.; Manners, I. J. Am. Chem. Soc. 2003, 125, 9424-9434
18. Jaska, C. A.; Manners, I. J. Am. Chem. Soc. 2004, 126, 9776-9785
19. Jaska, C. A.; Clark, T. J.; Clendenning, S. B.; Grozea, D.; Turak, A.; Lu, Z.-H.; Manners, I. J. Am. Chem. Soc. 2005, 127, 5116-5124
20. Denney, M. C.; Pons, V.; Hebden, T. J.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 12048-12049
21. Fulton, J. L.; Linehan, J. C.; Autrey, T.; Balasubramanian, M.; Chen, Y.; Szymczak, N. K. J. Am. Chem. Soc. 2007, 129, 11936-11949
22. Hebden, T. J.; Penney, M. C.; Pons, V.; Piccoli, P. M. B.; Koetzle, T. F.; Schulz, A. J.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Am. Chem. Soc. 2008, 130, 10812-10820
23. Dietrich, B. L.; Goldberg, K. I.; Heinekey, D. M.; Autrey, T.; Linehan, J. C. Inorg. Chem. 2008, 47, 8583-8585
24. Douglas, T. M.; Chaplin, A. B.; Weller, A. S. J. Am. Chem. Soc. 2008, 130, 14432-14433
25. Rousseau, R.; Schenter, G. K.; Fulton, J. L.; Linehan, J. C.; Engelhard, M. H.; Autry, T. J. Am. Chem. Soc. 2009, 131, 10516-10524
26. Douglas, T. M.; Chaplin, A. B.; Weller, A. S.; Yang, X.; Hall, M. B. J. Am. Chem. Soc. 2009, 131, 15440-15456
27. Sloan, M. E.; Clark, T. J.; Manners, I. Inorg. Chem. 2009, 48, 2429-2435
28. Zarmakiran, M.; Özkar, S. Inorg. Chem. 2009, 48, 8955-8964
29. Dallanegra, R.; Chaplin, A. B.; Weller, A. S. Angew. Chem., Int. Ed. 2009, 48, 6875-6878
30. Chaplin, A. B.; Weller, A. S. Inorg. Chem. 2010, 49, 1111-1121
31. Chaplin, A. B.; Weller, A. S. Angew. Chem., Int. Ed. 2010, 49, 581-584
32. For other transition-metal-based catalysts, see, for example: Clark, T. J.; Russell, C. A.; Manners, I. J. Am. Chem. Soc. 2006, 128, 9582-9583
33. Keaton, R. J.; Blacquiere, J. M.; Baker, R. T. J. Am. Chem. Soc. 2007, 129, 1844-1845
34. Pun, D.; Lobhovsky, E.; Chirik, P. J. Chem. Commun. 2007, 3297-3299
35. Jiang, Y.; Berke, H. Chem. Commun. 2007, 3571-3573
36. Pons, V.; Baker, R. T.; Szymczak, N. K.; Heldebrant, D. J.; Linehan, J. C.; Matus, M. H.; Grant, D. J.; Dixon, D. A. Chem. Commun. 2008, 6597-6599
37. Blaquiere, N.; Diallo-Garcia, S.; Gorelsky, S. I.; Black, D. A.; Fagnou, K. J. Am. Chem. Soc. 2008, 130, 14034-14035
38. Jiang, Y.; Blacque, O.; Fox, T.; Frech, C. M.; Berke, H. Organometallics 2009, 28, 5493-5504
39. Friedrich, A.; Drees, M.; Schneider, S. Chem. Eur. J. 2009, 15, 10339-10342
40. Käss, M.; Friedrich, A.; Drees, M.; Schneider, S. Angew. Chem., Int. Ed. 2009, 48, 905-907
41. Sloan, M. E.; Staubitz, A.; Clark, T. J.; Russell, C. A.; Lloyd-Jones, G. C.; Manners, I. J. Am. Chem. Soc. 2010, 132, 3831-3841
42. de los Ríos, I.; Tenorio, M. J.; Padilla, J.; Puerta, M. C.; Valerga, P. Organometallics 1996, 15, 4565-4574
43. Shaw, M. J.; Bryant, S. W.; Rath, N. Eur. J. Inorg. Chem. 2007, 3943-3946
44. 2Ru: C, 54.76; H, 5.45; N, 0.85. Found: C, 54.77; H, 5.47; N, 0.71.
45. Euzenat, L.; Horhant, D.; Ribourdouille, Y.; Duriez, C.; Alcaraz, G.; Vaultier, M. Chem. Commun. 2003, 2280-2281
46. -3. CSD reference: 819705.
47. 2BMes ligand has also been reported, featuring a Ru-B separation of 1.921(2) Å and a Ru•••B-C angle of 172.3(2)°: Hesp, K. D.; Kannemann, F. O.; Rankin, M. A.; McDonald, R.; Ferguson, M. J.; Stradiotto, M. Inorg. Chem. 2011, 50, 2431-2444
48. 1-bound four-coordinate amineborane, see: Kawano, Y.; Hashiva, M.; Shimoi, M. Organometallics 2006, 25, 4420-4426
49. For a recent review of σ borane complexes, see: Lin, Z. Struct. Bonding (Berlin) 2008, 130, 123-148
50. + fragment lies perpendicular to the HOMO: Schilling, B. E. R.; Hoffmann, R.; Lichtenberger, D. J. Am. Chem. Soc. 1979, 101, 585-591
51. Schlecht, S.; Hartwig, J. F. J. Am. Chem. Soc. 2000, 122, 9435-9443