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Volumn 47, Issue 19, 2008, Pages 8583-8585

Iridium-catalyzed dehydrogenation of substituted amine boranes: Kinetics, thermodynamics, and implications for hydrogen storage

Author keywords

[No Author keywords available]

Indexed keywords


EID: 54149092929     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801161g     Document Type: Article
Times cited : (150)

References (22)
  • 4
    • 14944371586 scopus 로고    scopus 로고
    • The American Physical Society
    • The American Physical Society. The Hydrogen Initiative (http://www.aps.org/public_affairs/index.cfm).
    • The Hydrogen Initiative
  • 5
    • 54149119271 scopus 로고    scopus 로고
    • U.S. DOE. Basic Research Needs for the Hydrogen Economy (http://www.sc.doe.gov/bes/reports/files/NHE_rpt.pdf).
    • U.S. DOE. Basic Research Needs for the Hydrogen Economy (http://www.sc.doe.gov/bes/reports/files/NHE_rpt.pdf).
  • 12
    • 54149116459 scopus 로고    scopus 로고
    • Preliminary report of this work: Tumas, W. DOE Hydrogen Program Annual Review, 2007 (http://www.hydrogen.energy.gov/pdfs/review07/st24tumas.pdf).
    • Preliminary report of this work: Tumas, W. DOE Hydrogen Program Annual Review, 2007 (http://www.hydrogen.energy.gov/pdfs/review07/st24tumas.pdf).
  • 18
    • 54149119074 scopus 로고    scopus 로고
    • The product distributions described result from reactions carried out in dilute THF solutions. Recent observations by Manners and co-workers suggest that the use of concentrated amine borane solutions results in high-molecular-weight polymers (Manners, I. Private communication). See also: Staubitz, A.; Presa Soto, A.; Manners, I. Angew. Chem., Int. Ed. 2008, 47, 6212.
    • The product distributions described result from reactions carried out in dilute THF solutions. Recent observations by Manners and co-workers suggest that the use of concentrated amine borane solutions results in high-molecular-weight polymers (Manners, I. Private communication). See also: Staubitz, A.; Presa Soto, A.; Manners, I. Angew. Chem., Int. Ed. 2008, 47, 6212.


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