Unusual reactivity of a disilyne with 4-dimethylaminopyridine: Formation of an intramolecularly N-coordinated silylene and its isomerization to a zwitterionic silyl anion

Journal of the American Chemical Society

Volumn 133, Issue 19, 2011, Pages 7352-7354

  Yamaguchi, Torahiko ^a   Sekiguchi, Akira ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

4-DIMETHYLAMINOPYRIDINE; ROOM TEMPERATURE; SI-N BONDS; SILYL ANIONS; SILYLENES; THERMALLY STABLE; TRIMETHYLSILYL; ZWITTERIONIC STRUCTURE;

COORDINATION REACTIONS;

4 DIMETHYLAMINOPYRIDINE; AMPHOLYTE; DISILYNE; HYDROGEN; SILICON; SILICONE DERIVATIVE; SILYLENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ISOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 79955920170     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja202605x     Document Type: Article

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