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4
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Z. Rappoport, Y. Apeloig, Eds. (Wiley, Chichester, UK), chap. 5
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M. Weidenbruch, The Chemistry of Organic Silicon Compounds, Z. Rappoport, Y. Apeloig, Eds. (Wiley, Chichester, UK, 2001), vol. 3, chap. 5.
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Weidenbruch, M.1
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5
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E. Wiberg, Lehrbuch der Anorganischen Chemie, A. F. Holleman, E. Wiberg, Eds. (W. de Gruyter, Berlin, Germany, eds. 22 and 23, 1943).
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Wiberg, E.1
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10
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37049108639
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A. G. Brook, F. Abdesaken, B. Gutekunst, G. Gutekunst, R. K. Kallury, J. Chem. Soc. Chem. Commun. 1981, 191 (1981).
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Brook, A.G.1
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Gutekunst, G.4
Kallury, R.K.5
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11
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0034639901
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2-, is described in L. Pu, B. Twamley, P. P. Power, J. Am. Chem. Soc. 122, 3524 (2000).
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Pu, L.1
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12
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0037140739
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3-, is described in A. D. Philips, R. J. Wright, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 124, 5930 (2002).
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Philips, A.D.1
Wright, R.J.2
Olmstead, M.M.3
Power, P.P.4
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13
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0036266419
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2 is described in M. Stender, A. D. Phillips, R. J. Wright, P. P. Power, Angew. Chem. Int. Ed. Engl. 41, 1785 (2002).
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Stender, M.1
Phillips, A.D.2
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Power, P.P.4
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19
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4544359774
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-
note
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29Si NMR signal at δ = 91.5 ppm, which was ascribed to a Si≡Si triple-bond resonance.
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-
-
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20
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4544240204
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note
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8 (50 mg, 0.370 mmol) were placed in a glass tube and degassed. Dry oxygen-free THF (2 ml) was introduced by vacuum transfer and the mixture was allowed to warm from -78°C to room temperature overnight with stirring. The solution turned an intense green color. The solvent was replaced by hexane, and then the resulting potassium salt and graphite were filtered off in a glove box (a box equipped with gloves in which air- and moisture-sensitive compounds can be handled). After evaporation of the solvent, pentane was added and the solution was cooled at -30°C to give emerald green crystals of 2 (53 mg, 73%).
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21
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4544378645
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note
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-1] 259, 10300; 328, 5800; 483, 120; and 690, 14.
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-
-
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22
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33748215890
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M. Kira, T. Maruyama, C. Kabuto, K. Ebata, H. Sakurai, Angew. Chem. Int. Ed. Engl. 33, 1489 (1994).
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Angew. Chem. Int. Ed. Engl.
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, pp. 1489
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Kira, M.1
Maruyama, T.2
Kabuto, C.3
Ebata, K.4
Sakurai, H.5
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24
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4544375940
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note
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2 = 0.1096 for all reflections. More crystallographic data are available at the Cambridge Crystallographic database, accession code and deposition no. CCDC 245523.
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27
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0242267598
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M. Ichinohe, M. Toyoshima, R. Kinjo, A. Sekiguchi, J. Am. Chem. Soc. 125, 13328 (2003).
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Ichinohe, M.1
Toyoshima, M.2
Kinjo, R.3
Sekiguchi, A.4
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28
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0036241224
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N. Wiberg, W. Niedermayer, G. Fischer, H. Nöth, M. Suter, Eur. J. Inorg. Chem. 2002, 1066 (2002).
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Wiberg, N.1
Niedermayer, W.2
Fischer, G.3
Nöth, H.4
Suter, M.5
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29
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4544307639
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note
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Supported by a Grant-in-Aid for Scientific Research (Nos. 134078204, 16205008, and 16550028) from the Ministry of Education, Science and Culture of Japan, and Center of Excellence program. We thank S. Nagase for helpful discussions and advice.
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