Unsymmetrically substituted disilyne Dsi2iPrSi- Si≡Si-SiNpDsi2 (Np = CH2tBu): Synthesis and characterization

Journal of the American Chemical Society

Volumn 132, Issue 47, 2010, Pages 16768-16770

  Murata, Yoshitaka ^a   Ichinohe, Masaaki ^a   Sekiguchi, Akira ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

SILICON ATOMS; SYNTHESIS AND CHARACTERIZATIONS; TRANS-BENT STRUCTURES; TRIPLE BONDS;

BOND LENGTH; X RAY CRYSTALLOGRAPHY;

SILICON;

SILICON DERIVATIVE;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; HYBRIDIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 78649528512     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1091744     Document Type: Article

References (34)

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28. For the experimental procedures and spectral data for new compounds in Scheme 1, a disilyne 1b, and 6 and crystal data for 2, see the Supporting Information.
29. 2 (1b) was synthesized by the reductive debromination of the corresponding tetrabromo-precursor (see Supporting Information).
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