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Volumn 13, Issue 9, 2011, Pages 2388-2391

Copper-catalyzed synthesis of 2,4-disubstituted allenoates from α-diazoesters

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; ALLENE; AZO COMPOUND; AZOESTER; COPPER;

EID: 79955598119     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol2006242     Document Type: Article
Times cited : (89)

References (64)
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    • Azine dimer 6, was independently synthesized by treating 2 with N -hydroxyphthalimide in the presence of rhodium(II) acetate dimer. Dimethyl 2,3-diphenylfumarate was also formed in this reaction.
    • Azine dimer 6, was independently synthesized by treating 2 with N -hydroxyphthalimide in the presence of rhodium(II) acetate dimer. Dimethyl 2,3-diphenylfumarate was also formed in this reaction.
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    • With phenyl propargyl sulfide, ethyl α-diazopropionate gave ethyl α-allenyl-α-(phenylthio)propionate (85%), ethyl α- diazobutyrate gave ethyl α-allenyl-α-(phenylthio)butyrate (95%), and methyl α-diazo-α-phenylacetate gave methyl α-allenyl-α- (phenyl)propionate (77%).
    • With phenyl propargyl sulfide, ethyl α-diazopropionate gave ethyl α-allenyl-α-(phenylthio)propionate (85%), ethyl α- diazobutyrate gave ethyl α-allenyl-α-(phenylthio)butyrate (95%), and methyl α-diazo-α-phenylacetate gave methyl α-allenyl-α- (phenyl)propionate (77%).


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