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Volumn 17, Issue 20, 2011, Pages 5561-5577

Electron-rich iron/ruthenium arylalkynyl complexes for third-order nonlinear optics: Redox-switching between three states

Author keywords

density functional calculations; heterometallic complexes; nonlinear optics; organometallic compounds; redox switching

Indexed keywords

ANALOGOUS COMPLEXES; BIRADICAL STRUCTURES; CARBON RICH; DENSITY-FUNCTIONAL CALCULATIONS; DINUCLEAR; ELECTRON-RICH; EXPERIMENTAL EVIDENCE; HETEROMETALLIC COMPLEXES; HETERONUCLEAR; INTERVALENCE CHARGE-TRANSFER; MIXED-VALENT; NEAR-INFRARED RANGE; NON-LINEAR OPTICAL PROPERTIES; OPTICAL MODULATION; ORGANOMETALLIC COMPOUNDS; OXIDIZED STATE; REDOX STATE; REDOX SWITCHING; STRUCTURAL DATA; THEORETICAL STUDY; THIRD-ORDER; THIRD-ORDER NON-LINEARITY; THIRD-ORDER NONLINEAR OPTICS;

EID: 79955589650     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003427     Document Type: Article
Times cited : (64)

References (105)
  • 3
    • 70349782203 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2009, 48, 3244-3266
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 3244-3266
  • 24
    • 79955602179 scopus 로고    scopus 로고
    • For selected examples, see
    • For selected examples, see
  • 40
    • 70349675504 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2009, 48, 7867-7870
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 7867-7870
  • 44
    • 33751210317 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 7376-7379.
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 7376-7379
  • 46
    • 79955598303 scopus 로고    scopus 로고
    • note
    • II-alkynyl complex, must have been totally tautomerized to this complex during the reaction.
  • 50
    • 0032479247 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1998, 37, 1714-1717.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 1714-1717
  • 68
    • 79955571809 scopus 로고    scopus 로고
    • unpublished results
    • F. Paul, unpublished results.
    • Paul, F.1
  • 69
    • 79955584116 scopus 로고    scopus 로고
    • HOMO-LUMO gaps are overestimated because of the use of a hybrid functional, including a Hartree-Fock exchange, which artificially destabilizes the virtual orbitals
    • HOMO-LUMO gaps are overestimated because of the use of a hybrid functional, including a Hartree-Fock exchange, which artificially destabilizes the virtual orbitals.
  • 71
    • 79955588586 scopus 로고    scopus 로고
    • note
    • g* sets of orbitals. This accounts for the new electronic excitations detected for this particular complex at low energy, which correspond to transitions from the highest HOMOs to this orbital.
  • 80
    • 79955577933 scopus 로고    scopus 로고
    • note
    • That is, near 800 nm, which is of biological importance as it is the wavelength for maximum transparency of tissue, and 1300 nm, which is of importance in telecommunications as it is the wavelength of maximum transparency for silica.
  • 81
    • 79955642212 scopus 로고    scopus 로고
    • note
    • Real parts of the cubic hyperpolarizabilities are quite sensitive to small differences in the energies of the absorption bands of the compounds, which renders any comparison between the measured values for the different compounds quite difficult.
  • 83
    • 79955597883 scopus 로고    scopus 로고
    • 2 values is needed to reliably compare the performances of these complexes
    • 2 values is needed to reliably compare the performances of these complexes.
  • 96
    • 79955609865 scopus 로고    scopus 로고
    • SHELX97-2. Program for the refinement of crystal structures, Univ. of Göttingen, Germany
    • G. M. Sheldrick, SHELX97-2. Program for the refinement of crystal structures, Univ. of Göttingen, Germany, 1997.
    • (1997)
    • Sheldrick, G.M.1
  • 98
    • 79955585245 scopus 로고    scopus 로고
    • PLATON: A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands
    • A. L. Spek, PLATON: A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 1998.
    • (1998)
    • Spek, A.L.1
  • 104
    • 79955580670 scopus 로고    scopus 로고
    • Schrodinger, 6.0 ed., LLC, New York, 2005
    • Schrodinger, 6.0 ed., LLC, New York, 2005.
  • 105
    • 79955621722 scopus 로고    scopus 로고
    • Spartan'08 for Macintosh, v.1.0.1, Wavefunction Inc., Irvine (USA) 2006
    • Spartan'08 for Macintosh, v.1.0.1, Wavefunction Inc., Irvine (USA) 2006


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.