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Volumn 24, Issue 22, 2005, Pages 5464-5478

Electron-rich piano-stool iron σ-acetylides. Electronic structures of arylalkynyl iron(III) radical cations

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; ELECTRONIC STRUCTURE; ELECTRONS; FREE RADICALS; PARAMETER ESTIMATION; POSITIVE IONS; PROBABILITY DENSITY FUNCTION; SPECTROSCOPIC ANALYSIS; SUBSTITUTION REACTIONS;

EID: 27544472326     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0505108     Document Type: Article
Times cited : (112)

References (86)
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    • note
    • CN value observed in the solid-state infrared spectrum of this complex suggests that the cyano bond is strengthened upon oxidation, not weakened. A shortening and not a lengthening of this bond should therefore be observed in the crystal structure. Whether this discrepancy is an artifact originating from the comparably large uncertainty in these bond lengths or results from a specific vibronic coupling involving the CN unit is presently unknown, (b) We thank a reviewer for this interesting comment.
  • 45
    • 27544483477 scopus 로고    scopus 로고
    • note
    • 6]. The reported extinction coefficients remain nevertheless approximate.
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    • Oxford University Press: Oxford, U.K.
    • Atkins, P. W. Physical Chemistry, 6th ed.; Oxford University Press: Oxford, U.K., 1998; p 501.
    • (1998) Physical Chemistry, 6th Ed. , pp. 501
    • Atkins, P.W.1
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    • 27544486576 scopus 로고    scopus 로고
    • note
    • 8 resulting in a diminished acetylide bond order and v(C=C) value.
  • 80
    • 27544442093 scopus 로고    scopus 로고
    • Flükiger, P.; Lüthi, H. P.; Portmann, S.; Weber, J. Swiss Center for Scientific Computing (CSCS), 2000-2001
    • Flükiger, P.; Lüthi, H. P.; Portmann, S.; Weber, J. Swiss Center for Scientific Computing (CSCS), 2000-2001.
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    • 0031059866 scopus 로고    scopus 로고
    • Carter, C. W., Sweet, R. M., Eds.; Academic Press: London
    • Otwinowski, Z.; Minor, W. In Methods in Enzymology; Carter, C. W., Sweet, R. M., Eds.; Academic Press: London, 1997; Vol. 276, pp 307-326.
    • (1997) Methods in Enzymology , vol.276 , pp. 307-326
    • Otwinowski, Z.1    Minor, W.2
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    • Nonius, B. V. Kappa CCD Software; Enraf-Nonius, Delft, The Netherlands, 1999
    • Nonius, B. V. Kappa CCD Software; Enraf-Nonius, Delft, The Netherlands, 1999.
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    • 0003872738 scopus 로고
    • Kynoch Press: Birmingham, U.K., (present distributor: D. Reidel, Dordrecht, The Netherlands)
    • Reidel: D. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, U.K., 1974; Vol. IV (present distributor: D. Reidel, Dordrecht, The Netherlands).
    • (1974) International Tables for X-ray Crystallography , vol.4
    • Reidel, D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.