Lattice strains in the ligand framework in the octahedral metal cluster compounds as the origin of their instability

Chemistry of Materials

Volumn 23, Issue 7, 2011, Pages 1901-1914

  Levi, Elena ^a   Aurbach, Doron ^a  

^a BAR ILAN UNIVERSITY   (Israel)

Author keywords

bond valences; Cluster compounds; lattice strains; material stability

Indexed keywords

BOND VALENCE ANALYSIS; BOND VALENCE MODEL; BOND VALENCES; BOND-VALENCE SUM; CHALCOGENS; CLUSTER CENTERS; CLUSTER COMPOUNDS; DIELECTRIC MEDIUM; ELECTRON POPULATION; ELECTROSTATIC FIELD; ELECTROSTATIC INTERACTIONS; INTERSTITIALS; ION INSERTION; LATTICE STRAIN; LATTICE STRAINS; MATERIAL INSTABILITY; MATERIAL STABILITY; MATERIAL STABILIZATION; METAL CLUSTER; METAL CLUSTER COMPOUND; MOLECULAR ORBITAL DIAGRAMS; NEW MODEL; NONUNIFORM; POLARIZING POWER; REDUCED OXIDATION; STABILIZATION MECHANISMS; STRUCTURAL UNIT; VALENCE ELECTRON;

ELECTROSTATICS; MATERIALS; MOLECULAR ORBITALS; MOLYBDENUM; NEGATIVE IONS; RHENIUM; STABILIZATION; TRANSITION METALS;

LIGANDS;

EID: 79953692119     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm103617e     Document Type: Article

References (79)

1. Cotton, F. A. Inorg. Chem. 1964, 3, 1217
2. Metal Clusters in Chemistry; Braunstein, P.; Oro, L. A.; Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999.
3. Prokopuk, N.; Shriver, D. F. In Advances in Inorganic Chemistry; Sykes, A. G., Ed.; Academic Press: San Diego, CA, 1999; Vol. 46, pp 1 - 49.
4. Gray, T. G. Coord. Chem. Rev. 2003, 243, 213
5. Yvon, K. In Current Topics in Material Science; Kaldis, E., Ed.; Elsevier/North-Holland: Amsterdam, The Netherlands, 1979; Vol. 3.
6. Topics in Current Physics: Superconductivity in Ternary Compounds I; Fisher, Ø.; Maple, M. B., Eds.; Springer-Verlag: Berlin, Germany, 1982.
7. Pena, O.; Sergent, M. Prog. Solid State Chem. 1989, 19, 165
8. Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.; Turgeman, R.; Cohen, Y.; Moskovich, M.; Levi, E. Nature 2000, 407, 724
9. Levi, E.; Gofer, Y.; Aurbach, D. Chem. Mater. 2010, 22, 860
10. Schollhorn, R. In Inclusion Compounds; Atwood, J. L., Ed.; Academic Press: London, U.K., 1984; Vol. 1.
11. Levi, E.; Gershinsky, G.; Aurbach, D.; Isnard, O.; Ceder, G. Chem. Mater. 2009, 21, 1390
12. Levi, E.; Gershinsky, G.; Aurbach, D.; Isnard, O. Inorg. Chem. 2009, 48, 8751
13. Mihailovic, D. Prog. Mater. Sci. 2009, 54, 309
14. Saito, T.; Imoto, H. Bull. Chem. Soc. Jpn. 1996, 69, 2403
15. Mironov, Y. V.; Virovets, A. V.; Naumov, N. G.; Ikorskii, V. N.; Fedorov, V. E. Chem.-Eur. J. 2000, 6, 1361
16. Gabriel, J.-C. P.; Boubeker, K.; Uriel, S.; Batail, P. Chem. Rev. 2001, 101, 2037
17. Selby, H. D.; Roland, B. K.; Zheng, Z. Acc. Chem. Res. 2003, 36, 933
18. Welch, E. J.; Long, J. R. in Progress in Inorganic Chemistry; Karlin, K. D., Ed.; John Wiley & Sons, Inc.: New York, 2005; Vol. 54, pp 1 - 45.
19. Pilet, G.; Perrin, A. C. R. Chim. 2005, 8, 1728
20. Cordier, S.; Kirakci, K.; Mery, D.; Perrin, C.; Astruc, D. Inorg. Chim. Acta 2006, 359, 1705
21. Lee, S. C.; Holm, R. H. Angew. Chem., Int. Ed. Engl. 1990, 29, 840
22. Hughbanks, T. Prog. Solid State Chem. 1989, 19, 329
23. Structural and electronic paradigms in cluster chemistry; Mingos, D. M. P., Ed.; Springer-Verlag: Berlin, Heidelberg, Germany, 1997.
24. Corbett, J. D. Inorg. Chem. 2000, 39, 5178
25. Simon, A. Phil. Trans. R. Soc. A 2010, 368, 1285
26. Perrin, A.; Perrin, C.; Sergent, M. J. Less-Common Met. 1988, 137, 241
27. Perrin, C. J. Alloys Compd. 1997, 262-263, 10
28. Levi, E.; Aurbach, D. Chem. Mater. 2010, 22, 3678
29. Brown, I. D. The chemical bond in inorganic chemistry: the bond valence model; Oxford University Press: New York, 2006.
30. Brese, N. E.; O'Keeffe, M. Acta Crystallogr. 1991, B47, 192
31. Thorp, H. H. Inorg. Chem. 1992, 31, 1585
32. Palenik, G. J. Inorg. Chem. 1997, 36 (122) 3394-4888
33. Thorp, H. H. Inorg. Chem. 1998, 37, 5690
34. Palenik, G. J. Can. J. Chem. 2006, 84, 99
35. Corbett, J. D. J. Solid State Chem. 1981, 37 (335) 39-56
36. Gougeon, P.; Salloum, D.; Cuny, J.; Polles, L.; Floch, M.; Gautier, R.; Potel, M. Inorg. Chem. 2009, 48, 8337
37. Schafer, H.; Schnering, H.-G.; Tillack, J.; Kuhnen, F.; Wohrle, H.; Baumann, H. Z. Anorg. Allg. Chem. 1967, 353, 281
38. Peppenhorst, A.; Keller, H.-L. Z. Anorg. Allg. Chem. 1996, 622, 663
39. Kirakci, K.; Cordier, S.; Perrin, C. Z. Anorg. Allg. Chem. 2005, 631, 411
40. Wang, P.; Xu, W.; Zheng, Y.-Q. Solid State Sci. 2003, 5, 573
41. Perrin, C.; Potel, M.; Sergent, M. Acta Crystallogr., Sect. C 1983, 39, 415
42. Perrin, C.; Sergent, M.; Traon, F.; Traon, A. J. Solid State Chem. 1978, 25, 197
43. Cordier, S.; Naumov, N. G.; Salloum, D.; Paul, F.; Perrin, C. Inorg. Chem. 2004, 43, 219
44. Preetz, W.; Harder, K.; Schnering, H. G.; Kliche, G.; Peters, K. J. Alloys Compd. 1992, 283, 413
45. Preetz, W.; Bublitz, D.; Schnering, H. G.; Sassmannshausen, J. Z. Anorg. Allg. Chem. 1994, 620, 234
46. Bruckner, P.; Preetz, W.; Punjer, M. Z. Anorg. Allg. Chem. 1997, 623, 8
47. Bronger, W.; Kanert, M.; Ioevenich, M.; Schmitz, D. Z. Anorg. Allg. Chem. 1993, 619, 2015
48. Bronger, W.; Ioevenich, M.; Schmitz, D. J. Alloys Compd. 1994, 216, 25
49. Bronger, W.; Ioevenich, M. J. Alloys Compd. 1994, 216, 29
50. Bronger, W.; Miessen, H.-J.; Neugroschel, R.; Schmitz, D.; Spangenberg, M. Z. Anorg. Allg. Chem. 1985, 525, 41
51. Bronger, W.; Ioevenich, M.; Schmitz, D.; Schuster, T. Z. Anorg. Allg. Chem. 1990, 587, 91
52. Bronger, W.; Miessen, H.-J. J. Less-Common Met. 1982, 83, 29
53. Bronger, W.; Miessen, H.-J.; Schmitz, D. J. Less-Common Met. 1983, 95, 275
54. Bronger, W.; Schuster, T. Z. Anorg. Allg. Chem. 1990, 587, 74
55. Bronger, W.; Koppe, C.; Schmitz, D. Z. Anorg. Allg. Chem. 1997, 623, 239
56. Huan, G.; Greaney, M.; Tsai, P. P.; Greenblatt, M. Inorg. Chem. 1989, 28, 2448
57. Klaiber, F.; Petter, W. J. Solid State Chem. 1983, 46, 112
58. Harbrecht, B.; Selmer, A. Z. Anorg. Allg. Chem. 1994, 620, 1861
59. Fischer, C.; Alonso-Vante, N.; Fiechter, S.; Tributsch, H.; Reck, G.; Schulz, W. J. Alloys Compd. 1992, 178, 305
60. Speziali, N. L.; Berger, H.; Leicht, G.; Sanjines, R.; Chapuis, G.; Levy, F. Mater. Res. Bull. 1988, 23, 1597
61. Leduc, L.; Perrin, A.; Sergent, M. Acta Crystallogr., Sect. C 1983, 39, 1503
62. Pinheiro, C. B.; Speziali, N. L.; Berger, H. Acta Crystallogr., Sect. C 1997, 53, 1178
63. Leduc, L.; Perrin, A.; Sergent, M.; Traon, F.; Pilet, J. C.; Traon, A. Mater. Lett. 1985, 3, 209
64. Perricone, A.; Slougui, A.; Perrin, A. Solid State Sci. 1999, 1, 657
65. Zietlow, T. C.; Schaefer, W. P.; Sadeghi, B.; Hua, N.; Gray, H. B. Inorg. Chem. 1986, 25, 2195
66. Imoto, H.; Simon, A. Inorg. Chem. 1982, 21, 308
67. Simon, A.; Schnering, H.-G.; Schafer, H. Z. Anorg. Allg. Chem. 1968, 361, 235
68. Bajan, B.; Meyer, H.-J. Z. Anorg. Allg. Chem. 1997, 623, 791
69. Bajan, B.; Balzer, G.; Meyer, H.-J. Z. Anorg. Allg. Chem. 1997, 623, 1723
70. Hughbanks, T.; Corbett, J. D. Inorg. Chem. 1988, 27, 2022
71. Zhang, J.; Corbett, J. D. Inorg. Chem. 1991, 30, 431
72. Adams, S. Acta Crystallogr., Sect. B 2001, 57, 278
73. Brown, I. D. Chem. Rev. 2009, 109, 6858
74. Ehm, L.; Dera, P.; Knorr, K.; Winkler, B.; Krimmel, A.; Bouvier, P. Phys. Rev. B 2005, 72, 14113
75. Baranovski, V. I.; Korolkov, D. V. Polyhedron 2004, 23, 1519
76. Baranovski, V. I.; Korolkov, D. V. Russ. Chem. Bull., Int. Ed. 2005, 54, 2705
77. Arratia-Perez, R.; Hernandez-Acevedo, L. Chem. Phys. Lett. 1997, 277, 223
78. Arratia-Perez, R.; Hernandez-Acevedo, L. J. Chem. Phys. 1999, 110, 2529
79. Tulsky, E. G.; Long, J. R. Chem. Mater. 2001, 13, 1149