Metal clusters inside out

Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences

Volumn 368, Issue 1915, 2010, Pages 1285-1299

  Simon, Arndt ^a  

^a MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

Author keywords

Clusters; Condensed clusters; Hydride halides; Rare earths; Subnitrides; Suboxides

Indexed keywords

ALKALI METALS; ALKALINE EARTH METALS; ALKALINITY; LIGANDS; RARE EARTH ELEMENTS; RARE EARTHS;

ALKALINE EARTH; CLUSTER COMPOUNDS; CLUSTERS; ENDOHEDRALS; GENERAL TRENDS; LANTHANIDES; LIGAND SHELLS; METAL CLUSTER; PERIODIC TABLE; SOLID STATE CHEMISTRY; SUBNITRIDES; VALENCE ELECTRON CONCENTRATION;

METALS;

EID: 77950220021     PISSN: 1364503X     EISSN: None     Source Type: Journal    
DOI: 10.1098/rsta.2009.0271     Document Type: Review

References (41)

1. Addison, C. C., Pulham, R. J. & Trevillion, E. A. 1975 Reactions between barium and nitrogen in liquid sodium: solubility studies. J. Chem. Soc. Dalton 20, 2082-2085. (doi:10.1039/dt9750002082)
2. Braun, T. P. & Simon, A. 1996 Stabilization of octahedral thorium clusters by interstitial hydrogen. Chem. Europ. J. 2, 511-515. (doi:10.1002/chem.19960020509)
3. 15 (x = 5, 7). J. Am. Chem. Soc. 118, 7203-7208. (doi:10.1021/ ja954016e)
4. 2O. Ark. Kem. Mineral. Geol. 20, 1-16.
5. Chevrel, R. & Sergent, M. 1986 From three-dimensional to one-dimensional cluster Mo6 chalcogenides. In Crystal chemistry and properties of materials with quasi-one-dimensional structures (ed. J. Rouxel), pp. 315-373. Dordrecht, The Netherlands: Reidel.
6. Corbett, J. D. 1981 Extended metal-metal bonding in halides of the early transition metals. Acc. Chem. Res. 14, 239-246. (doi:10.1021/ar00068a003)
7. Cotton, F. A. 1964 Metal atom clusters in oxide systems. Inorg. Chem. 3, 1217-1220. (doi:10.1021/ic50019a003)
8. 2. Synthesis, structure, and the bonding of dicarbon. Inorg. Chem. 26, 1933-1940. (doi:10.1021/ic00259a025)
9. 11 und des Interstitialhydrids HNb. Ein Beitrag zur Cluster-bulk-Analogie. Z. Anorg. Aallg. Chem. 1513, 46-56. (doi:10.1002/zaac. 19845130606)
10. 4. Angew. Chem. Int. Ed. 48, 2415-2417. (doi:10.1002/anie.200805736)
11. 3. J. Less-common Met. 71, 135-145. (doi:10.1016/0022-5088 (80) 90109-5)
12. 12 cations. Theoret. Chim. Acta 13, 211-212. (doi:10.1007/BF00527353)
13. Kienle, L., Schaloske, M. C., Mattausch, Hj., Duppel, V. & Simon, A. 2008 Discoveries in real crystals of rare earth metal compounds by electron microscopy-lamellar intergrowth and domains of phasoids. Solid State Sci. 10, 401-407. (doi:10.1016/j.solidstatesciences. 2007.11.027)
14. Köhler, J., Svensson, G. & Simon, A. 1992 Oxoniobates containing metal clusters. Angew. Chem. Int. Ed. Engl. 31, 1437-1456. (doi:10.1002/anie. 199214371)
15. 20 with Ln = La, Ce. Z. Anorg. Allg. Chem. 632, 1661-1670. (doi:10.1002/zaac.200500493)
16. McCarley, R. E. 1990 Metal clusters in the solid state. In Metal-metal-bonds and clusters in chemistry and catalysis (ed. J. P. Fackler Jr), pp. 91-102. New York, NY: Plenum Press.
17. Oeckler, O., Weber, Th., Kienle, L., Mattausch, Hj. & Simon, A. 2005 Cluster disorder and ordering principles in Al-stabilized 'LaI'. Angew. Chem. Int. Ed. 44, 3917-3921. (doi:10.1002/anie.200500594)
18. 3N; an extension of alkali metal suboxide chemistry. Angew. Chem. Int. Ed. Engl. 31, 1519-1521. (doi:10.1002/anie.199215191)
19. 2 NX (M = Ca, Sr, Ba; X = H, Cl or Br). Solid State Sci. 4, 575-584. (doi:10.1016/S1293-2558 (02) 01300-6)
20. Rengade, E. 1909 Sur les sous-oxydes de caesium. C. R. Hebd. Séances Acad. Sci. 148, 1199-1202.
21. Schäfer, H. & Schnering, H. G. 1964 Metall-Metall-Bindungen bei niederen Halogeniden, Oxyden und Oxydhalogeniden schwerer Übergangsmetalle. Angew. Chem. 76, 833-849. (doi:10.1002/ange.19640762002)
22. Schäfer, H., von Schnering, H. G., Niehues, K.-J. & Nieder-Vahrenholz, H. G. 1965 Niobfluoride. J. Less-common Met. 9, 95-104.
23. 8]. Z. Anorg. Allg. Chem. 1355, 311-322. (doi:10.1002/zaac.19673550511)
24. Simon, A. 1979 Structure and bonding with alkali metal suboxides. Struct. Bond. 36, 81-127. (doi:10.1007/BFb0116562)
25. Simon, A. 1981 Condensed metal clusters. Angew. Chem. Int. Ed. Engl. 20, 1-22. (doi:10.1002/anie.198100013)
26. Simon, A. 1995 Discrete and condensed transition metal clusters in solids. In Clusters and colloids (ed. G. Schmidt), pp. 376-458. Weinheim, Germany: VCH.
27. Simon, A. 1997 Group 1 and 2 suboxides and subnitrides-metals with atomic size holes and tunnels. Coord. Chem. Rev. 163, 253-270. doi:10.1016/S0010-8545 (97) 00013-1)
28. Simon, A. 2004 Alkali and alkaline earth metal suboxides and subnitrides. In Molecular clusters of the main group elements (eds M. Driess & N. Nöth), pp. 246-266. Weinheim, Germany: Wiley-VCH.
29. 6. J. Chem. Soc. Faraday Trans. 92, 2117-2123. (doi:10.1039/ft9969202117)
30. 9: the first Li/Ba subnitride. Inorg. Chem. 5, 10786-10789. (doi:10.1021/ic0613816)
31. 6. Z. Anorg. Allg. Chem. 633, 2296-2299. (doi:10.1002/zaac.200700192)
32. 3N. Solid State Chem. 180, 1889-1893. (doi:10.1016/j.jssc.2007.04. 012)
33. 6: new representatives of the subnitride family. Z. Anorg. Allg. Chem. 634, 629-632. (doi:10.1002/zaac. 200700472)
34. x (E = N, H; x = 0-1). Z. Anorg. Allg. Chem. 634, 849-852. (doi:10.1002/zaac.200700520)
35. 3 structure type. Angew. Chem. Int. Ed. Engl. 33, 689-691. (doi:10.1002/anie.199406891)
36. 3N: a one-dimensional void metal? J. Am. Chem. Soc. 117, 1996-1999. (doi:10.1021/ja00112a012)
37. 6-a nanodispersion of a salt in a metal. Angew. Chem. Int. Ed. Engl. 35, 552-554. (doi:10.1002/anie.199605521)
38. 3N-a new binary nitride of an alkaline earth metal. Z. Anorg. Allg. Chem. 624, 228-232. (doi:10.1002 /(SICI) 1521-3749 (199802) 624:2<228::AID-ZAAC228> 3.0. CO;2-8)
39. Svensson, G., Köhler, J. & Simon, A. 1999 Discrete and condensed clusters in low valent niobium oxides. In metal clusters in chemistry (eds P. Braunstein, L. A. Oro & P. R. Raithby), pp. 1509-1550. Weinheim, Germany: Wiley-VCH.
40. 6 series. Eur. J. Inorg. Chem. 5, 1189-1193. (doi:10.1002/1099-0682 (200105) 2001:5<1189::AID-EJIC1189>3.0. CO;2-J)
41. +. J. Am. Chem. Soc. 72, 5477-5486. (doi:10.1021/ ja01168a028)