Bond Valence Sums in Coordination Chemistry Using Oxidation State Independent R0 Values. A Simple Calculation of the Oxidation State of Titanium in Complexes Containing Ti-N, Ti-O, and Ti-Cl Bonds

Inorganic Chemistry

Volumn 36, Issue 16, 1997, Pages 3394-3397

  Palenik, Gus J ^a  

^a UNIVERSITY OF FLORIDA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001117354     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970239p     Document Type: Article

References (29)

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9. O'Keeffe, M.; Brese, N. E. J. Am. Chem. Soc. 1991, 113, 3226.
10. JADWIU is tetrakis(ethyl acetate-O)magnesium(II)-bis(μ-chloro)-trichlorohydroxotitanium(IV). Giunchi, G.; Albizzati, E.; Malpezzi, L.; Gianetti, E. Inorg. Chim. Acta 1988, 147, 159.
11. BAXFUB is tetrakis(ethyl acetate-O)magnesium(II)-bis(μ-chloro)-tetrachlorotitanium(IV). Bart, J. C. J.; Bassi, I. W.; Calcaterra, M.; Albizzati, E.; Giannini U.; Parodi, S. Z. Anorg. Allg. Chem. 1981, 482, 121.
12. 2trimethylphosphine imido)dichlorotitanium(IV)) tetraphenylborate. Rübenstahl, T.; Weller, F.; Dehnicke, K.; Fenske, D.; Baum, G. Z. Anorg. Allg. Chem. 1994, 620, 1741.
13. PIXTEX is (1,4,7-trimethyl-1,4,7-triazacyclononane)bis(isocyanato)-peroxotitanium(IV). Jeske, P.; Haselhorst, G.; Weyhermüller, T.; Weighardt, K.; Nuber, B. Inorg. Chem. 1994, 33, 2462.
14. Brown, I. D. J. Solid State Chem. 1991, 90, 155.
15. Withers, R. L.; Thompson, J. G.; Rae, A. D. J. Solid State Chem. 1991, 94, 404.
16. YEXCAF is dichloro(tert-butylimido)(tetramethylethylenediamine)-titanium(IV), and YEXCEJ is dichloro(tert-butylimido)(diisopropyl-ethylenediamine)titanium(IV). Lewkebandara, T. S.; Sheridan, P. H.; Heeg, M. J.; Rheigold, A. L.; Winter, C. H. Inorg. Chem. 1994, 33, 5879.
17. CTMSIA is chlorotris(bis(trimethylsilyl)amido)titanium(IV). Airoldi, C.; Bradley, D. C.; Chudzynska, H.; Hursthouse, M. B.; Malik, K. M. A.; Raithby, P. R. J. Chem. Soc., Dalton Trans. 1991, 2010.
18. 2-2,2-dimethyl-1-(trimethylsilyl)-1-aza-3-azonia-2-silapropane-N,N, N')[bis(trimethylsilyl)-imido]titanium(IV)]. OvchiAiroldi, C.; Bradley, D. C.; Chudzynska, H.; Hursthouse, M. B.; Malik, K. M. A.; Raithby, P. R. J. Chem. Soc., Dalton Trans. 1991, 2010.
19. 2-3,3′-bis(dimethylbutylsilyl)binaphthyl-2,2′-diolato)- bis{tris(isopropoxy)titanium(IV)}. Boyle, T. J.; Barnes, D. L.; Heppert, J. A.; Morales, L.; Takusagawa, F.; Connolly, J. W. Organometallics 1992, 11, 1112.
20. YUXBIC is dichlorobis(triphenylphosphaniminato-N)titanium. Rubenstahl, F.; Weller, F.; Wocadlo, S.; Massa, W.; Dehnicke, K. Z. Anorg. Allg. Chem. 1995, 621, 953.
21. 3 and was incorrectly named in the CSD file and not named in the original paper. Hasselbring, R.; Leichtweis, I.; Noltemeyer, M.; Roesky, H. W.; Schmidt, H.-G.; Herzog, A. Z. Anorg. Allg. Chem. 1993, 619, 1543.
22. JOHBAJ is bis(tetramethylethylenediamine)lithium(I) dichlorodi(bis-{trimethylsilyl}amido)titanate(III). Beydoun, N.; Duchateau, R.; Gambarotta, S. J. Chem. Soc., Chem. Commun. 1992, 244.
23. 2-diazo)bis(chlorobis(pyridine)(bis{trimethylsilyl}amido)-titanium) as given in the CSD file but was formulated in ref 22 as a dinitrogen, not a diazo species.
24. 2-diazo)bis(chlorotetramethylethylenediamine((trimethylsilyl)amido} titanium) as given in the CSD file but was formulated as a dinitrogen, not a diazo species. Duchateau, R.; Gambarotta, S.; Beydoun, N.; Bensimon, C. J. Am. Chem. Soc. 1991, 113, 8986.
25. Churchill, M. R.; Washerman, H. J. Inorg. Chem. 1982, 21, 218.
26. 2-dichloro)bis(chloro[glyoxal bis{tert-butylimine}]-titanium) in the CSD file and dichloroglyoxal bis(tert-butylimine)-titanium in the following: tom Dieck, H.; Rieger, H. J.; Fendesak, G. Inorg. Chim. Acta 1990, 177, 191.
27. FODXIF is bis(2,2′-bipyridyl)bis(2,6-bis{isopropyl}phenoxo)titanium, Durfee, L. D.; Fanwick, P. E.; Rothwell, I. P.; Folting, K.; Huffman, J. C. J. Am. Chem. Soc. 1987, 109, 4720.
28. BULXIP is methoxy(tetraphenylporphyrinato)titanium(III). Boreham, C. J.; Buisson, G.; Duee, E.; Jordanov, J.; Latour, J.-M.; Marchon, J.-C. Inorg. Chim. Acta 1983, 70, 77.
29. McKarns, P. J.; Yap, G. P. A.; Rheingold, A. L.; Winter, C. H. Inorg. Chem. 1996, 35, 5968.