Synthesis and characterization of Cs2Mo6X 14 (X = Br or I) hexamolybdenum cluster halides: Efficient Mo 6 cluster precursors for solution chemistry syntheses

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 631, Issue 2-3, 2005, Pages 411-416

  Kirakci, Kaplan ^a   Cordier, Stéphane ^a,b   Perrin, Christiane ^a  

^a CNRS   (France)

^b Laboratoire de Chimie du Solide et Inorganique Moleculaire de Rennes   (France)

Author keywords

Crystal structures; Molybdenum halides; Octahedral cluster

Indexed keywords

ANION; BROMINE; CESIUM; HALIDE; HEXANE; IODINE; MOLYBDENUM COMPLEX;

ARTICLE; CLUSTER ANALYSIS; CORRELATION ANALYSIS; CRYSTAL STRUCTURE; CRYSTALLIZATION; ENERGY YIELD; MOLECULAR INTERACTION; PARAMETER; REACTION ANALYSIS; SOLID STATE; STEREOCHEMISTRY; STRUCTURE ANALYSIS; TECHNIQUE; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 14844314523     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/zaac.200400281     Document Type: Article

References (38)

1. H. Schäfer, H. G. von Schnering, Angew. Chem. 1964, 76, 833.
2. Blomstrand, J. Prakt. Chem. 1859, 77, 88.
3. C. Brosset, Ark. Kemi Mineral. Geol. 1945, 20 A, (no. 7).
4. H. G. von Schnering, Z Anorg. Allg. Chem. 1971, 385, 75.
5. M. Potel, C. Perrin, A. Perrin, M. Sergent, Mat. Res. Bull. 1986, 21, 1239.
6. S. Böschen, H.-L. Keller, Z. Kristallogr. 1992, 200, 305.
7. A. Flemström, S. Lidin, Z. Kristallogr. 2001, 216, 41.
8. A. Peppenhorst, H.-L. Keller, Z. Anorg. Allg. Chem. 1996, 622, 663.
9. S. Cordier, N. Naumov, D. Salloum, F. Paul, C. Perrin, Inorg. Chem. 2004, 43, 219.
10. P. C. Healey, D. L. Kepert, D. Taylor, A. H. White, J. Chem. Soc., Dalton Trans. 1973, 646.
11. (a) C. S. Weinert, C. L. Stern, D. W. Shriver, Inorg. Chem. 2000, 39, 240;
12. (b) D. J. Johnston, D. C. Gaswick, C. L. Stern, D. W. Shriver, Inorg. Chem. 1992, 31 1869;
13. (c) M. W. Wilier, J. R. Long, C. C. McLauchlan, R. H. Holm, Inorg. Chem. 1998, 37, 328.
14. F. Ueno, A. Simon, Acta Crystallogr. 1985, C41, 308.
15. S. Cordier, C. Perrin, M. Sergent, Z. Anorg. Allg. Chem. 1993, 619, 621.
16. H. Imoto, J. D. Corbett, Inorg. Chem. 1980, 19, 1241.
17. S. Cordier, C. Perrin, J. Solid State Chem. 2004, 177, 1017.
18. M. O'Keffee, N. E. Brese, J. Am. Chem. Soc. 1991, 113, 3225.
19. G. Pilet, Thesis of Rennes 1 University, 2003, N° 2875.
20. Y.-Q. Zheng, K. Petres, Y. Grin, H. G. von Schnering, Z. Anorg. Allg. Chem. 1998, 624, 506.
21. R. P. Shannon, Acta Crystallogr. 1976, A32, 751.
22. S. Cordier, D. Astruc, C. Perrin et al., work in progress.
23. H. Schäfer, H. G. von Schnering, J. Tillack, F. Kuhnen, H. Wöhrle, H. Baumann, Z. Anorg. Allg. Chem. 1967, 353, 281.
24. (a) A. W. Maverick, Jan S. Najdzionek, D. MacKenzie, D. G. Nocera, H. B. Gray, J. Am. Chem. Soc. 1983, 105, 1878;
25. (b) W. Preetz, D. Bublitz, H. G. von Schnering, J. Sassmannshausen, Z. Anorg. Allg. Chem. 1994, 620, 234;
26. (c) F. A. Cotton, R. M. Wing and R. A. Zimmerman, Inorg. Chem. 1967, 6, 11.
27. (a) J. C. Sheldon, J. Chem. Soc. 1962, 410;
28. (b) W. C. Dorman, R. E. McCarley, Inorg. Chem. 1974, 13(2), 491.
29. P. Brückner, W. Preetz, M. Pünjer, Z. Anorg. Allg. Chem. 1997, 623, 8.
30. Nonius. COLLECT. DENZO, SCALEPACK, SORTAV: KappaCCD Program Package; Nonius B.V.: Delft, The Netherlands, 1999.
31. R. H. Blessing, Acta Crystallogr. 1995, A51, 33.
32. N. W. Alcock, Cryst. Computing 1970, p271.
33. R. E. Marsh, Acta Crystallogr. 1999, B51, 897.
34. G. Cascarano, A. Altomare, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, D. Siliqi, M. C. Burla, G. Polidori, M. Camalli, Acta Crystallogr. 1996, A52, C-79
35. G. M. Sheldrick, SHELXL-97: Program for the Refinement of Crystal Structure; University of Göttingen: Göttingen, 1997.
36. P. Thompson, D. E. Cox, J. B. Hastings, J. Appl. Cryst. 1987, 20, 79.
37. J. Rodriguez-Carvajal, FULLPROF: A Program for Rietveld Refinement and Pattern Matching Analysis. Abstracts of the Satellite Meeting on Powder Diffraction of the XV Congress of the IUCr, p. 127, Toulouse, France (1990).
38. T. Roisnel, J. Rodríguez-Carvajal J., Materials Science Forum, Proceedings of the Seventh European Powder Diffraction Conference 2000, 118, Ed. R. Delhez and E. J. Mittenmeijer.