Chemistry of hexanuclear rhenium chalcohalide clusters

Chemical Reviews

Volumn 101, Issue 7, 2001, Pages 2037-2066

  Gabriel, Jean Christophe P ^a   Boubekeur, Kamal ^a   Uriel, Santiago ^a,b   Batail, Patrick ^a  

^a CNRS   (France)

^b UNIVERSITAT JAUME I   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CLUSTER CORE SYNTHESIS;

COORDINATION REACTIONS; MOLECULAR STRUCTURE; MONOMERS; NEGATIVE IONS; POLYMERS; SYNTHESIS (CHEMICAL);

RHENIUM COMPOUNDS;

EID: 0035412747     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr980058k     Document Type: Review

References (170)

1. Opalovskii, A.A.; Fedorov, V.E.; Lobkov, E.U. Russ. J. Inorg. Chem. 1971, 16, 790.
2. Opalovskii, A.A.; Fedorov, V.E.; Lobkov, E.U.; Erenburg, B.G. Russ. J. Inorg. Chem. 1971, 16, 1685.
3. Leduc, L.; Perrin, A.; Sergent, M. C. R. Acad. Sci. Paris, Ser. 2 1983, 296, 961.
4. Batail, P.; Ouahab, L.; Pénicaud, A.; Lenoir, C.; Perrin, A. C. R. Acad. Sci. Ser. 2 1987, 304, 1111.
5. (5) Complementary approaches are currently emerging; see: (a) Sayettat, J.; Bull, L.M.; Gabriel, J.-C.P.; Jobic, S.; Camerel, F.; Marie, A.-M.; Fourmigué, M.; Batail, P.; Brec, R.; Inglebert, R.-L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1711.
6. (b) Kolesnichenko, V.; Swenson, D.C.; Messerle, L. Inorg. Chem. 1998, 37, 3257.
7. (b) Kolesnichenko, V.; Messerle, L. Inorg. Chem. 1998, 37, 3660.
8. (c) Kolesnichenko, V.; Luci, J.J.; Swenson, D.C.; Messerle, L. J. Am. Chem. Soc. 1998, 120, 13260.
9. See also the seminal ongoing work of Roesky and co-workers on the chemistry on soluble metal fluorides: (d) Walawalkar, M.G.; Roesky, H.W.; Murugavel R. Acc. Chem. Res. 1999, 32, 117.
10. (e) Yu, P.; Müller, P.; Roesky, H.W.; Noltemeyer, M.; Demsar, A.; Uson, I. Angew. Chem., Int. Ed. Engl. 1999, 38, 3319.
11. (a) Bronger, W.; Koppe, C.; Loevenich, M.; Schmitz, D.; Schuster, T. Z. Anorg. Chem. Allg. Chem. 1997, 623, 695.
12. (b) Bronger, W.; Koppe, C.; Schmitz, D. Z. Anorg. Chem. Allg. Chem. 1997, 623, 239.
13. (c) Bronger, W.; Loevenich, M.; Schmitz, D. J. Alloys Compd. 1994, 216, 25.
14. (d) Bronger, W.; Loevenich, M. J. Alloys Compds. 1994, 216, 29.
15. (e) Bronger, W.; Kanert, M.; Loevenich, M.; Schmitz, D. Z. Anorg. Chem. Allg. Chem. 1993, 619, 2015.
16. (f) Lutz, H.D.; Muller, B.; Bronger, W.; Loevenich, M. J. Alloys Compds. 1993, 190, 181.
17. (g) Bronger W.; Schuster, T. Z. Anorg. Chem. Allg. Chem. 1990, 587, 74.
18. (h) Bronger, W.; Loevenich, M.; Schmitz, D.; Schuster, T. Z. Anorg. Chem. Allg. Chem. 1990, 587, 91.
19. Saito, T. J. Chem. Soc., Dalton Trans. 1999, 97.
20. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
21. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
22. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
23. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
24. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
25. See also the yearly reviews based on Chemical Abstracts searches, covering most rhenium compounds, with a focus on organometallic ones, and for the period 1991-1996: (a) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1994, 94, 127. (b) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 1. (c) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1995, 95, 207. (d) Vires, J.C.; Lynam, M. Coord. Chem. Rev. 1997, 162, 3319. (e) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 169, 201. (g) Vites, J.C.; Lynam, M. Coord. Chem. Rev. 1998, 172, 357.
26. Perrin, A.; Sergent, M. New. J. Chem. 1988, 12, 337.
27. 2 source.
28. Preliminary structural data: (a) Perrin, A.; Sergent, M. Bull. Soc. Chim. Fr. 1980, 11-12, 66.
29. (b) Leduc, L.; Perrin, A.; Sergent, M. Bull. Soc. Chim. Fr. 1981, 11-12, I-399.
30. For a full report of the structure, see: Leduc, L.; Perrin, A.; Sergent, M. Acta Crystallogr. 1983, C59, 1503.
31. 8 (X = S, Se), see: Perrin, A.; Sergent, M.; Fisher, Ø. Mater. Res. Bull. 1978, 13, 259.
32. (a) Spangenberg, M.; Brönger, W. Angew. Chem., Int. Ed. Engl. 1978, 17, 368.
33. (b) Chen, S.; Robinson, W.R. J. Chem. Soc., Chem. Commun. 1978, 20, 879.
34. Leduc, L. Ph.D. Thesis, University of Rennes I, Rennes, France, 1983.
35. Pilet, J.-C.; Le Traon, F.; Le Traon, A.; Perrin, C.; Perrin, A.; Leduc, L.; Sergent, M. Surf Sci. 1985, 156, 359.
36. Schäfer, H.; von Schnering, H.G. Angew. Chem. 1964, 20, 833.
37. Leduc, L.; Padiou, J.; Perrin, A.; Sergent, M. J. Less-Common Met. 1983, 95, 73.
38. Leduc, L.; Perrin, A.; Sergent, M.; Le Traon, F.; Pilet, J.-C.; Le Traon, A. Mater. Lett. 1985, 3, 209.
39. Fedorov, V.E.; Mishchenko, A.V.; Kalesov, B.A.; Gubin, S.P.; Slovokhotov, Yu.L.; Struchkov, Yu.T. Bull. Acad. Sci. USSR, Chem. Sci. 1984, 9, 1976.
40. Fedorov, V.E.; Mishchenko, A.V.; Kolesov, B.A.; Gubin, S.P.; Slovokhotov, Yu.L.; Struchkov, Yu.T. Koord. Khim. 1985, 11, 980.
41. Gabriel, J.-C. Ph.D. Thesis, University of Paris-Sud, Orsay, France, 1993.
42. Gabriel, J.-C.; Boubekeur, K.; Batail, P. Inorg. Chem. 1993, 32, 2894.
43. Mironov, Y.V.; Cody, J.A.; Ibers, J.A. Acta Crystallogr. 1996, C52, 281.
44. Yarovoi, S.S.; Mironov, Yu.I.; Mironov, Yu.V.; Virovets, A.V.; Fedorov, V.E.; Paek, U-Hyon; Shin, Sung Chul; Seo, Moo-Lyong Mater. Res. Bull. 1997, 32, 1271.
45. Mironov, Y.V.; Pell, M.A.; Ibers, J.A. Inorg. Chem. 1996, 35, 2709.
46. Müller, A.; Krickemeyer, E.; Bögge, H. Angew. Chem., Int. Ed. Engl. 1986, 25, 485.
47. Müller, A.; Krickemeyer, E.; Bögge, H. Z. Anorg. Allg. Chem. 1987, 554, 61.
48. Schulz Lang, E.; Abram, U.; Strähle, J. Z. Anorg. Allg. Chem. 1996, 622, 251.
49. Mironov, Y.V.; Albrecht-Schmitt, T.E.; Ibers, J.A. Inorg. Chem. 1997, 36, 944.
50. Fedin, V.P.; Fedorov, V.E.; Imoto, H.; Saito, T. Polyhedron 1997, 16, 1615.
51. For a full report of the structure, see: Perrin, A.; Leduc, L.; Potel, M.; Sergent, M. Mater. Res. Bull. 1990, 25, 1227.
52. (a) von Schnering, H.G. Z. Anorg. Allg. Chem. 1971, 385, 75.
53. (b) Potel, M.; Perrin, C.; Perrin, A.; Sergent, M. Mater. Res. Bull. 1986, 21, 1239.
54. Slougui, A.; Perrin, A.; Sergent, M. Acta Crystallogr. 1992, C48, 1917.
55. Lenain, S.; Gabriel, J.-C.P., Batail, P. Unpublished results.
56. Boubekeur, K. Ph.D. Thesis, University of Rennes I, Rennes, France, 1989.
57. Uriel, S.; Boubekeur, K.; Gabriel, J.-C.; Batail, P.; Orduna, J. Bull. Soc. Chim. Fr. 1996, 133, 783.
58. Healy, P.C.; Kepert, D.L.; Taylor, D.; White, A.H. J. Chem. Soc., Dalton Trans. 1973, 6, 646.
59. Fedin, V.P.; Imoto, H.; Saito, T.; Fedorov, V.E.; Mironov, Y.V.; Yarovoi, S.S. Polyhedron 1996, 15, 1229.
60. 8] crystallizes in the cubic system, space group Pn3̄ (No. 201), with α = 13.433 Å: Slougui, A.; Ferron, S.; Perrin, A.; Sergent, M. J. Cluster Sci. 1997, 8, 349.
61. Perricone, A.; Slougui, A.; Perrin, A. Solid State Sci. 1999, 1, 657.
62. 8]. This therefore indicates that iron-based salts of octahedral rhenium cluster anions could be soluble: Retailleau, T.; Gabriel, J.-C.P.; Boubekeur, K.; Batail, P. Unpublished results.
63. Guitbaud, C.B.; Boubekeur, K.; Gabriel, J.-C.P.; Batail, P. C. R. Acad. Sci. Ser. 2c 1998, 1, 765.
64. (a) Slougui, A.; Perrin, A.; Sergent, M. J. Solid State Chem. 1999, 147, 358.
65. (b) Yarovoi, S.S.; Mironov, Yu.V.; Solodovnikov, S.F.; Virovets, A.V.; Fedorov, V.E. Mater. Res. Bull. 1999, 34, 1245.
66. Long, J.R.; Williamson, A.S.; Holm, R.H. Angew. Chem., Int. Ed. Engl. 1995, 34, 226.
67. Long, J.R.; McCarty, L.S.; Holm, R.H. J. Am. Chem. Soc. 1996, 118, 4603.
68. Fedin, V.P.; Virovets, A.A.; Sykes, A.G. Inorg. Chim. Acta 1998, 271, 228.
69. Perrin, A.; Leduc, L.; Sergent, M. Eur. J. Solid State Inorg. Chem. 1991, 28, 919.
70. Yaghi, O.M.; Scott, M.J.; Holm, R.H. Inorg. Chem. 1992, 31, 4778.
71. 13] (M = Ag, Na): see ref 33b.
72. (b) Full description of the structure: Boeschen, S.; Keller, H.L. Z. Kristallogr. 1991, 196, 159.
73. Schäfer, H.; von Schnering, H.G.; Tillack, J.; Kuhnen, F.; Wohrle, H.; Baumann, H. Z. Anorg. Allg. Chem. 1967, 353, 281.
74. Sheldon, J.C. J. Chem. Soc. 1960, 1007.
75. Le Nagard, N.; Perrin, A.; Sergent, M.; Levy-Clement, C. Mater. Res. Bull. 1985, 20, 835.
76. Hughbanks, T.; Hoffmann, R. J. Am. Chem. Soc. 1983, 105, 1150.
77. Fischer, C.; Colell, H.; Tributsch, H. Surf. Sci. Lett. 1993, 280, L267.
78. Mironov, Y.V.; Pell, M.A.; Ibers, J.A. Angew. Chem., Int. Ed. Engl. 1997, 35, 2854.
79. Pinheiro, C.B.; Speziali, N.L.; Berger, H. Acta. Crystallogr. C 1997, 53, 1178.
80. Speziali, N.L.; Berger, H.; Leicht, G.; Sanjinés, R.; Chapuis, G.; Lévy, F. Mater. Res. Bull. 1988, 23, 1597.
81. Fisher, C.; Alonso-Vante, N.; Fiechter, S.; Tributsch, H.; Reck, G.; Schultz, W.J. J. Alloys Compd. 1992, 178, 305.
82. Fisher, C.; Fiechter, S.; Tributsch, H.; Reck, G.; Schultz, B. Ber. Bunsen-Ges. Phys. Chem. 1992, 96, 1652.
83. The general formula encompasses, for n < l/2, cationic species which remain to be discovered.
84. (62) Page 78 of ref 15.
85. Bronger, W.; Miessen, H.-J.; Müller, P.; Neugroschel, R. J. Less-Common Met. 1985, 105, 303.
86. Simon, F.; Boubekeur, K.; Gabriel, J.-C.P.; Batail, P. J. Chem. Soc., Chem. Commun. 1998, 845-846.
87. Tulsky, E.G.; Long, J.R. Chem. Mater. 2001, 13, in press.
88. Typically, high-temperature solid-state syntheses of hexanuclear rhenium chalcohalide clusters are carried out in our laboratory in ca. 0.4 g pellets/sealed batch tube, and several (up to 6) tubes are treated in a single oven cycle. See refs 23 and 37 for detailed procedures.
89. Ouahab, L.; Batail, P.; Perrin, C.; Garrigou-Lagrange, C. Mater. Res. Bull. 1986, 21, 1223.
90. Uriel, S.; Boubekeur, K.; Batail, P.; Orduna, J.; Perrin, A. New J. Chem. 2001, 25, 737.
91. Perrin, A. New. J. Chem. 1990, 14, 561.
92. Guilbaud, C.B. Ph.D. Thesis, University of Nantes, Nantes, France, 1998.
93. O'Keeffe, M.; Eddaoudi, M.; Li, H.; Reineke, T.; Yaghi, O.M. J. Solid State Chem. 2000, 153, 3-20.
94. Boubekeur, K.; Batail, P. Unpublished results.
95. Lee, S.C.; Holm, R.H. Angew. Chem., Int. Ed. Engl. 1990, 29, 840.
96. Uriel, S.; Boubekeur, K.; Batail, P.; Orduna, J.; Canadell, E. Inorg. Chem. 1995, 34, 5307.
97. Uriel, S.; Boubekeur, K.; Batail, P.; Orduna, J. Angew. Chem., Int. Ed. Engl. 1996, 35, 1544.
98. Gabriel, J.-C.P.; Boubekeur, K.; Batail, P. Unpublished result.
99. Guirauden, A.; Johannsen, I.; Batail, P.; Coulon, C. Inorg. Chem. 1993, 32, 2446 and references therein.
100. Zheng, Z.; Long, J.R.; Holm, R.H. J. Am. Chem. Soc. 1997, 119, 2163.
101. .3- (Q = chalcogen, X = halogen) as shown for X = Cl and Q = S.
102. Willer, M.W.; Long, J.R.; McLauchlan, C.C.; Holm, R.H. Inorg. Chem. 1998, 37, 328.
103. Wang, R.; Zheng, Z. J. Am. Chem. Soc. 1999, 121, 3549.
104. 2+ (py-R = pyridine or 4-hydroxypyridine) are reported in a footnote of ref 81.
105. Zheng, Z.; Holm, R.H. Inorg. Chem. 1997, 36, 5173.
106. Zheng, Z.; Gray, T.G.; Holm, R.H. Inorg. Chem. 1999, 38, 4888.
107. Chen, Z.-N.; Yoshimura, T.; Abe, M.; Sasaki, Y.; Ishizaka, S.; Kim, H.-B.; Kitamura, N. Angew. Chem., Int. Ed. Engl. 2001, 40, 239.
108. Selby, H.D.; Zheng, Z.; Gray, T.G.; Holm, R.H. Inorg. Chim. Acta 2001, 312, 205.
109. Yoshimura, T.; Ishizaka, S.; Umakoshi, K.; Sasaki, Y.; Kim, H.-B.; Kitamura, N. Chem. Lett. 1999, 697.
110. Yoshimura, T.; Umakoshi, K.; Sasaki, Y.; Sykes, A.G. Inorg. Chem. 1999, 38, 5557.
111. Decker, A.; Simon, F.; Boubekeur, K.; Fenske, D.; Batail, P. Z. Anorg. Allg. Chem. 2000, 626 (1), 309.
112. 5+. Both arguments are in favor of an increased susceptibility to μ-halide exchange for the reduced cluster cores. There is, however, a lack of experimental evidence for the latter mechanism at the present stage of development of the chemistry.
113. 1= 2.750 + 0.6 log(7/12) = 2.609 Å.
114. Allmann, R. Monatsh. Chem. 1975, 106, 779. Donnay, G.; Donnay, J.H. Acta Crystallogr. 1973, B29, 1417.
115. Allmann, R. Monatsh. Chem. 1975, 106, 779. Donnay, G.; Donnay, J.H. Acta Crystallogr. 1973, B29, 1417.
116. (a) Ebihara, M.; Toriumi, K.; Saito, K. Inorg. Chem. 1988, 27, 13.
117. (b) Ebihara, M.; Toriumi, K.; Sasaki, Y.; Saito, K. Gazz. Chim. Ital. 1995, 125, 87.
118. 3- (Q = S, Te): (c) Michel, J.B.; McCarley, R.E. Inorg. Chem. 1982, 21, 1864.
119. (d) Ebihara, M.; Imai, T.; Kawamura, T. Acta Crystallogr., Sect. C 1995, 51, 1743.
120. Ebihara, M.; Isobe, K.; Sasaki, Y.; Saito, K. Inorg. Chem. 1992, 31, 1644.
121. Geometrical disorder arises from the random distribution in the packing within the crystal of all different geometric isomers. Orientational disorder arises from random orientation of only one geometric isomer.
122. Fedorov, V.E.; Podberezskaya, N.V.; Mischenko, A.V.; Khudorozko, G.F.; Asanov, I.P. Mater. Res. Bull. 1986, 21, 1335.
123. Mironov, Y.V.; Virovets, A.V.; Fedorov, V.E.; Podberezskaya, N.V. Polyhedron 1995, 14, 3171.
124. a}: Slougui, A.; Mironov, Y.V.; Perrin, A.; Fedorov, V.E. Croat. Chem. Acta 1995, 68, 885.
125. a}: Mironov, Y.V.; Cody, J.A.; Albrecht-Schmitt, T.E.; Ibers, J.A. J. Am. Chem. Soc. 1997, 119, 493.
126. Naumov, N.G.; Virovets, A.V.; Podberezskaya, N.V.; Fedorov, V.E. Zh. Strukt. Khim. 1997, 38, 1020.
127. Beauvais, L.G.; Shores, M.P.; Long, J.R. Chem. Mater. 1998, 10, 3783.
128. Mironov, Y.V.; Fedorov, V.E.; McLauchlan, C.C.; Ibers, J.A. Inorg. Chem. 2000, 39, 1809.
129. Naumov, N.G.; Virovets, A.V.; Sokolov, N.S.; Artemkina, S.B.; Fedorov, V.E. Angew. Chem., Int. Ed. Engl. 1998, 37, 1943.
130. Naumov, N.G.; Artemkina, S.B.; Virovets, A.V.; Fedorov, V.E. J. Solid State Chem. 2000, 153, 195.
131. This compound contains accessible cubelike cavities: Shores, M.P.; Beauvais, L.G.; Long, J.R. Inorg. Chem. 1999, 38, 1648.
132. Shores, M.P.; Beauvais, L.G.; Long, J.R. J. Am. Chem. Soc. 1999, 121, 775.
133. Bennett, M.V.; Shores, M.P.; Beauvais, L.G.; Long, J.R. J. Am. Chem. Soc. 2000, 122, 6664.
134. Beauvais, L.G.; Shores, M.P.; Long, J.R. J. Am. Chem. Soc. 2000, 122, 2763.
135. A review of the principles of the electrocrystallization technique and its application to the synthesis of electroactive molecular solids is to be found in the following: Batail, P.; Boubekeur, K.; Fourmigué, M.; Gabriel, J.-C.P. Chem. Mater. 1998, 10, 3005.
136. Yoshimura, T.; Ishizaka, S.; Sasaki, Y.; Kim, H.-B.; Kitamura, N.; Naumov, N.G.; Sokolev, M.N.; Fedorov, V.E. Chem. Lett. 1999, 1121.
137. 1/2 values were given vs Ag/AgCl.
138. Yoshimura, T.; Umakoshi, K.; Sasaki, Y.; Ishizaka; S.; Kim, H.-B.; Kitamura, N. Inorg. Chem. 2000, 39, 1765.
139. Guilbaud, C.; Deluzet, A.; Domercq, B.; Molinié, P.; Coulon, C.; Boubekeur, K.; Batail, P. Chem. Commun. 1999, 1867.
140. Gray, T.G.; Rudzinski, C.M.; Nocera, D.G.; Holm, R.H. Inorg. Chem. 1999, 38, 5932.
141. 6] acetonitrile solution in the presence of oxygen: Deluzet, A.; Pansu, R.; Batail, P. Unpublished materials. Also, in Figure 3 of ref 115, the band at 796 nm upon excitation at 393 nm is an experimental artifact.
142. Arratia-Pérez, R.; Hernández-Acevedo, L. J. Chem. Phys. 1999, 110, 2529.
143. Arratia-Pérez, R.; Hernández-Acevedo, L. J. Chem. Phys. 1999, 111, 168.
144. (a) Johnston, D.H.; Gaswick, D.C.; Lonergan, M.C.; Stern, C.L.; Shriver, D.F. Inorg. Chem. 1992, 31, 1869.
145. (b) Holadi, H.A.; Hung, H.; Shriver, D.F. Inorg. Chim. Acta 1992, 198-200, 245.
146. See ref 52 and refs 13 and 14 therein.
147. Certain, D.; Lissillour, R. Z. Phys. D 1986, 3, 411.
148. Batail, P.; Boubekeur, K.; Fourmigué, M.; Dolbecq, A.; Gabriel, J.-C.; Guirauden, A.; Livage, C.; Uriel, S. New J. Chem. 1994, 18, 999.
149. (a) Batail, P.; Livage, C.; Parkin, S.S.P.; Coulon, C.; Martin, J.D.; Canadell, E. Angew. Chem., Int. Ed. Engl. 1991, 30, 1498.
150. (b) Coulon, C.; Livage, C.; Gonzalvez, L.; Boubekeur, K.; Batail, P. J. Phys. I (Paris) 1993, 3, 1153.
151. (a) Pénicaud, A.; Boubekeur, K.; Batail, P.; Canadell, E.; Auban-Senzier, P.; Jérome, D. J. Am. Chem. Soc. 1993, 115, 4101.
152. (b) Canadell, E. Chem. Mater. 1998, 10, 2770.
153. Deluzet, A. Ph.D. Thesis, University of Nantes, Nantes, France, 2000.
154. Deluzet, A.; Guilbaud, C.; Boubekeur, K.; Batail, P.; Auban-Senzier, P.; Jérôme, D. Submitted for publication.
155. Pénicaud, A.; Lenoir, C.; Batail, P.; Coulon, C.; Perrin, A. Synth. Met. 1989, 32, 25.
156. Dolbecq, A.; Boubekeur, K.; Batail, P.; Canadell, E.; Auban-Senzier, P.; Coulon, C.; Lerstrup, K.; Bechgaard, K. J. Mater. Chem. 1995, 5, 1707.
157. Deluzet, A.; Batail, P.; Misaki, Y.; Auban-Senzier, P.; Canadell, E. Adv. Mater. 2000, 12, 436.
158. Perruchas, S.; Deluzet, A.; Boubekeur, K.; Batail, P.; Misaki, Y.; Canadell, E.; Auban-Senzier, P.; Jérôme, D. Unpublished results.
159. Mussell, R.D.; Nocera, D.G. Inorg. Chem. 1990, 29, 3711.
160. Ebihara, M.; Kawamura, T.; Isobe, K.; Saito, K. Bull. Chem. Soc. Jpn. 1994, 67, 3119.
161. Saito, T.; Yamamoto, N.; Nagase, T.; Tsuboi, T.; Kobayashi, K.; Yamagata, T.; Imoto, H.; Unoura, K. Inorg. Chem. 1990, 29, 764.
162. Maverick, A.W.; Gray, H.B. J. Am. Chem. Soc. 1981, 103, 1298.
163. Maverick, A.W.; Najdzionek, J.S.; MacKenzie, D.; Nocera, D.G.; Gray, H.B. J. Am. Chem. Soc. 1983, 105, 1878.
164. Jackson, J.A.; Turro, C.; Newsham, M.D.; Nocera, D.G. J. Phys. Chem. 1990, 94, 4500.
165. Zietlow, T.C.; Nocera, D.G.; Gray, H.B. Inorg. Chem. 1986, 25, 1351.
166. Renault, A.; Pouget, J.-P.; Parkin, S.S.P.; Torrance, J.B.; Ouahab, L.; Batail, P. MCLC S & T, Sect. B: Nonlinear Opt. 1988, 161, 329.
167. Boubekeur, K.; Lenoir, C.; Batail, P.; Carlier, R.; Tallec, A.; Le Paillard, M.-P.; Lorcy, D.; Robert, A. Angew. Chem., Int. Ed. Engl. 1994, 33, 1379.
168. Gabriel, J.-C.; Johannsen, I.; Batail, P.; Coulon C. Acta. Crystallogr. C 1993, 49, 1052.
169. Dolbecq, A.; Boubekeur, K.; Batail, P.; Canadell, E.; Auban-Senzier, P.; Coulon, C.; Lerstrup, K.; Bechgaard, K. J. Mater. Chem. 1995, 5, 1707.
170. Renault, A.; Talham, D.; Canceill, J.; Batail, P.; Collet, A.; Lajzerowicz, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1249.