Mechanism of carbon-halogen bond reductive cleavage in activated alkyl halide initiators relevant to living radical polymerization: Theoretical and experimental study

Journal of the American Chemical Society

Volumn 133, Issue 16, 2011, Pages 6254-6264

  Isse, Abdirisak A ^a   Gennaro, Armando ^a   Lin, Ching Yeh ^b   Hodgson, Jennifer L ^b   Coote, Michelle L ^b   Guliashvili, Tamaz ^c  

^a UNIVERSITY OF PADOVA   (Italy)

^b AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^c GE Water and Process Technologies   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ACTIVATION STEPS; ALKYL HALIDES; BOND DISSOCIATION; CARBON-CENTERED RADICALS; CARBON-HALOGEN BOND; DISSOCIATIVE ELECTRON TRANSFERS; DONOR-ACCEPTORS; ELECTRON TRANSFER; EXPERIMENTAL INVESTIGATIONS; EXPERIMENTAL STUDIES; LEAVING GROUPS; LIVING RADICAL POLYMERIZATION; RADICAL ANIONS; REDUCTIVE CLEAVAGE; SET-LRP; SINGLE ELECTRON TRANSFER;

ACETONITRILE; ALKYLATION; ATOM TRANSFER RADICAL POLYMERIZATION; ELECTRON TRANSITIONS; NEGATIVE IONS; PHOTODISSOCIATION; POLYMERIZATION; SPHERES; TRANSIENTS;

FREE RADICAL REACTIONS;

ACETONITRILE; CARBON; HALIDE; HALOGEN;

ARTICLE; CHEMICAL BOND; DECOMPOSITION; ELECTRON; ELECTRON TRANSPORT; LIVING RADICAL POLYMERIZATION; POLYMERIZATION; SPIKE;

EID: 79953284563     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja110538b     Document Type: Article

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