-
2
-
-
0000821227
-
-
Bernasconi, C. F., Ed.; Wiley; New York
-
(b) Andrieux, C. P.; Savéant, J.-M. In Electrochemical Reactions in Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry; Bernasconi, C. F., Ed.; Wiley; New York, 1986; Vol. VI/4E, Part 2, pp 305-390.
-
(1986)
Electrochemical Reactions in Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry
, vol.4-6 E
, Issue.2 PART
, pp. 305-390
-
-
Andrieux, C.P.1
Savéant, J.-M.2
-
3
-
-
77956772881
-
Single Electron Transfer and Nucleophilic Substitution
-
Bethel, D., Ed.; Academic Press: New York
-
(a) Savéant, J.-M. Single Electron Transfer and Nucleophilic Substitution. In Advances in Physical Organic Chemistry; Bethel, D., Ed.; Academic Press: New York, 1990; Vol. 26, pp 1-130.
-
(1990)
Advances in Physical Organic Chemistry
, vol.26
, pp. 1-130
-
-
Savéant, J.-M.1
-
4
-
-
0001697560
-
-
(b) Lund, H.; Daasberg, K.; Lund, T.; Pedersen, S. U. Acc. Chem. Res. 1995, 28, 313.
-
(1995)
Acc. Chem. Res.
, vol.28
, pp. 313
-
-
Lund, H.1
Daasberg, K.2
Lund, T.3
Pedersen, S.U.4
-
7
-
-
0002010399
-
Intramolecular Photochemical Electron Transfer (PET)-Induced Bond Cleavage Reactions in some Sulfonium Salts Derivatives
-
Mariano, P. S., Ed.; JAI Press: New York
-
(b) Saeva, F. D. Intramolecular Photochemical Electron Transfer (PET)-Induced Bond Cleavage Reactions in some Sulfonium Salts Derivatives. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. 4, pp. 1-25.
-
(1994)
Advances in Electron Transfer Chemistry
, vol.4
, pp. 1-25
-
-
Saeva, F.D.1
-
8
-
-
0000759953
-
-
(c) Arnold, B. R.; Scaiano, J. C.; McGimpsey, W. G. J. Am. Chem. Soc. 1992, 114, 9978.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 9978
-
-
Arnold, B.R.1
Scaiano, J.C.2
McGimpsey, W.G.3
-
9
-
-
0029326002
-
-
(d) Chen, L.; Farahat, M. S.; Gan, H.; Farid, S.; Whitten, D. G. J. Am. Chem. Soc. 1995, 117, 6399.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 6399
-
-
Chen, L.1
Farahat, M.S.2
Gan, H.3
Farid, S.4
Whitten, D.G.5
-
17
-
-
0001887557
-
Dissociative Electron Transfer
-
Mariano, P. S., Ed.; JAI Press: New York
-
(c) Savéant, J.-M. Dissociative Electron Transfer. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. 4, pp. 53-116.
-
(1994)
Advances in Electron Transfer Chemistry
, vol.4
, pp. 53-116
-
-
Savéant, J.-M.1
-
19
-
-
1542411152
-
-
(b) Andrieux, C. P.; LeGorande, A.; Savéant, J.-M. J. Am. Chem. Soc. 1992, 114, 6892.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 6892
-
-
Andrieux, C.P.1
LeGorande, A.2
Savéant, J.-M.3
-
22
-
-
0029929090
-
-
(a) Anne, A.; Fraoua, S.; Moiroux, J.; Savéant, J.-M. J. Am. Chem. Soc. 1996, 118, 3938.
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 3938
-
-
Anne, A.1
Fraoua, S.2
Moiroux, J.3
Savéant, J.-M.4
-
23
-
-
0030861477
-
-
(b) Andersen, M. L.; Long, W.; Wayner, D. D. M. J. Am. Chem. Soc. 1997, 119, 6590.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 6590
-
-
Andersen, M.L.1
Long, W.2
Wayner, D.D.M.3
-
25
-
-
84920311046
-
-
See the section devoted to this question and footnote 29 in ref 10b
-
(a) See the section devoted to this question and footnote 29 in ref 10b.
-
-
-
-
27
-
-
0007437054
-
-
Workentin, M. S.; Maran, F.; Wayner, D. D. M. J. Am. Chem. Soc. 1995, 117, 2120.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 2120
-
-
Workentin, M.S.1
Maran, F.2
Wayner, D.D.M.3
-
28
-
-
84920311045
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-
note
-
(a) The reaction is assumed to be adiabatic, and at the same time, the avoided crossing energy is assumed to be small enough for the intersection of the two diabatic curves to give the activation energy with a reasonable accuracy,
-
-
-
-
29
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-
84920311044
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-
note
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(b) Since the reactions we discuss occur in solution, the small difference between free energy and free enthalpy may be neglected.
-
-
-
-
32
-
-
84976413581
-
Theory of Electron Transfer Reactions: Insights and Hindsights
-
Lippard, S. J., Ed.; Wiley: New York
-
(b) Sutin, N. Theory of Electron Transfer Reactions: Insights and Hindsights. Progress in Inorganic Chemistry; Lippard, S. J., Ed.; Wiley: New York, 1983; Vol. 30, pp 441 -497.
-
(1983)
Progress in Inorganic Chemistry
, vol.30
, pp. 441-497
-
-
Sutin, N.1
-
35
-
-
33845278996
-
-
(a) Lexa, D.; Savéant, J.-M.; Su, K. B.; Wang, D. L. J. Am. Chem. Soc. 1988, 110, 7617.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 7617
-
-
Lexa, D.1
Savéant, J.-M.2
Su, K.B.3
Wang, D.L.4
-
36
-
-
0000496367
-
-
(b) Daasbjerg, K.; Pedersen, S. U.; Lund, H. Acta Chem Scand. 1991, 45, 424.
-
(1991)
Acta Chem Scand.
, vol.45
, pp. 424
-
-
Daasbjerg, K.1
Pedersen, S.U.2
Lund, H.3
-
37
-
-
84920311043
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note
-
17b However, the thermochemical data required for a quantitative analysis are lacking. The negative values found for the activation entropy (-1, -0.35, and -0.6 meV/K, respectively) indicates that, in eq 7 or 14, the fragmentation entropy term is overcompensated by the solvation entropy term,
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-
-
-
38
-
-
0039907488
-
-
(b) Andrieux, C. P.; Delgado, G.; Savéant, J.-M. J. Electroanal. Chem. 1993, 348, 123.
-
(1993)
J. Electroanal. Chem.
, vol.348
, pp. 123
-
-
Andrieux, C.P.1
Delgado, G.2
Savéant, J.-M.3
-
41
-
-
84971074097
-
-
(b) Cox, B. G.; Hedvig, G. R.; Parker, A. J.; Watts, D. W. Aust. J. Chem. 1974, 27, 477.
-
(1974)
Aust. J. Chem.
, vol.27
, pp. 477
-
-
Cox, B.G.1
Hedvig, G.R.2
Parker, A.J.3
Watts, D.W.4
-
42
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-
84920311042
-
-
note
-
19 with correction for the change in the standard state from the gas phase to the liquid phase (1 atm and 1 mol/L, respectively) which amounts to decreasing each of the S̊,s by R/F ln(22.4) = 0.268 meV/(mol K).
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-
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-
43
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33845374004
-
-
Andrieux, C. P.; Gallardo, I.; Savéant, J.-M.; Su, K. B. J. Am. Chem. Soc. 1986, 108, 638.
-
(1986)
J. Am. Chem. Soc.
, vol.108
, pp. 638
-
-
Andrieux, C.P.1
Gallardo, I.2
Savéant, J.-M.3
Su, K.B.4
-
44
-
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84920311041
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note
-
Br• = -128.1 J/(mol K).
-
-
-
-
46
-
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33847085663
-
-
Andrieux, C. P.; Blocman, C.; Dumas-Bouchiat, J.-M.; M'Halla, F.; Savéant, J.-M. J. Am. Chem. Soc. 1980, 102, 3806.
-
(1980)
J. Am. Chem. Soc.
, vol.102
, pp. 3806
-
-
Andrieux, C.P.1
Blocman, C.2
Dumas-Bouchiat, J.-M.3
M'Halla, F.4
Savéant, J.-M.5
-
49
-
-
4243921184
-
-
Anxolabéhère, E.; Lexa, D.; Momenteau, M.; Savéant, J.-M. J. Phys. Chem. 1992, 96, 9348.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 9348
-
-
Anxolabéhère, E.1
Lexa, D.2
Momenteau, M.3
Savéant, J.-M.4
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