Expeditious synthesis of 2,3,6-trisubstituted 2 H -1,3-oxazin-4(3 H)-ones via the tertiary amine-induced reaction of 2-diazo-3-oxoalkanals and imines under mild conditions

Synthesis

Volumn , Issue 6, 2011, Pages 887-894

  Qi, Hengzhen ^a   Zhang, Jiantao ^a   Xu, Jiaxi ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

2 diazo 3 oxoalkanal; acylketene; amine induced reaction; cycloaddition; Diels Alder reaction; imine; oxazinone

Indexed keywords

2-DIAZO-3-OXOALKANAL; ACYLKETENE; DIELS-ALDER REACTION; IMINE; OXAZINONES;

CYCLOADDITION; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; REGIOSELECTIVITY;

SYNTHESIS (CHEMICAL);

1 BENZOYL 11 METHYL 1H METHYL 1H AZETO[1,2 D]DIBENZO[B,F][1,4]OXAZEPIN 2(12B H) ONE; 13 METHYL 2 PHENYLDIBENZO[B,F][1,3]OXAZINO[3,2D][1,4]OXAZEPIN 4 ONE; 13 METHYLDIBENZO[B,F][1,3]OXAZINO[3,2 D][1,4]OXAZEPIN 4(14B H); 2 DIAZO 3 OXOALKANAL DERIVATIVE; 2 FUR 2 YL 3 (4 METHOXYPHENYL) 6 PHENYL 2H 1,3 OXAZIN 4(3H) ONE; 2 PHENYL 6,7 DIHYDRO[1,3]OXAZINO[2,3 A]ISOQUINOLIN 4(11B H) ONE; 2,6 DIPHENYL 3 (1 PHENYLETHYL) 2H 1,3 OXAZIN 4(3H) ONE; 2H 1,3 OXAZIN 4(3H) ONE DERIVATIVE; 3 (4 METHOXYSTYRYL) 2,6 DIPHENYL 2H 1,3 OXAZIN 4(3H) ONE; 3 BENZYL 2,5 DIPHENYL 2H 1,3 OXAZIN 4(3H) ONE; 3 BENZYL 2,6 DIPHENYL 2H 1,3 OXAZIN 4(3H) ONE; 3 ISOPROPYL 2 (4 METHOXYPHENYL) 6 PHENYL 2H 1,3 OXAZIN 4(3H) ONE; 3 ISOPROPYL 2 (4 NITROPHENYL) 6 PHENYL 2H 1,3 OXAZIN 4(3H) ONE; ALPHA DIAZO BETA DIKETONE DERIVATIVE; ALPHA DIAZO BETA OXOALKANAL DERIVATIVE; IMINE; ORGANIC COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIELS ALDER REACTION; HIGH TEMPERATURE; SYNTHESIS;

EID: 79952454519     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258439     Document Type: Article

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