Chiral iridium spiro aminophosphine complexes: Asymmetric hydrogenation of simple ketones, structure, and plausible mechanism

Chemistry - An Asian Journal

Volumn 6, Issue 3, 2011, Pages 899-908

  Xie, Jian Bo ^a   Xie, Jian Hua ^a   Liu, Xiao Yan ^a   Zhang, Qian Qian ^a   Zhou, Qi Lin ^a  

^a NANKAI UNIVERSITY   (China)

Author keywords

aminophosphines; asymmetric catalysis; hydrogenation; iridium; ketones

Indexed keywords

ACTIVE SPECIES; AMINOPHOSPHINE LIGANDS; AMINOPHOSPHINES; AROMATIC KETONES; ARYL KETONES; ASYMMETRIC CATALYSIS; ASYMMETRIC HYDROGENATION; CHIRAL ALCOHOLS; EFFICIENT CATALYSTS; HIGH ACTIVITY; HIGH ENANTIOSELECTIVITY; HYDROGENATION REACTIONS; IRIDIUM COMPLEX; IRIDIUM DIHYDRIDE; KEY FACTORS; MILD REACTION CONDITIONS; NMR SPECTROSCOPY; PHENYL RINGS; PLAUSIBLE MECHANISMS; TERT-BUTYL GROUP; TURNOVER FREQUENCY; TURNOVER NUMBER;

CATALYSIS; CATALYSTS; ENANTIOSELECTIVITY; HYDROGENATION; IRIDIUM; KETONES; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS;

IRIDIUM COMPOUNDS;

EID: 79951993225     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201000716     Document Type: Article

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