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For transfer hydrogenation without bases: (a) Mizushima, E.; Yamaguchi, M.; Yamagishi, T. Chem. Lett. 1997, 237. (b) Eceraere, K.; Scheffler, J.-L.; Mortreux. A.; Carpentier, J.-F. Tetrahedron Lett. 2001, 42, 1899. (c) Cadierno, V.; Crochet, P.; Diez, J.; Garcia-Garrido, S. E.; Gimeno, J. Organometallics 2004, 23, 4836. (d) Dahlenburg, L.; Götz, R. Inorg. Chim. Acta 2004, 357, 2875. (e) For asymmetric transfer hydrogenation of acetophenone without bases with Ru complex: Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285. (f) For asymmetric transfer hydrogenation of m-trifluoromethylacetophenone without bases: Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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For transfer hydrogenation without bases: (a) Mizushima, E.; Yamaguchi, M.; Yamagishi, T. Chem. Lett. 1997, 237. (b) Eceraere, K.; Scheffler, J.-L.; Mortreux. A.; Carpentier, J.-F. Tetrahedron Lett. 2001, 42, 1899. (c) Cadierno, V.; Crochet, P.; Diez, J.; Garcia-Garrido, S. E.; Gimeno, J. Organometallics 2004, 23, 4836. (d) Dahlenburg, L.; Götz, R. Inorg. Chim. Acta 2004, 357, 2875. (e) For asymmetric transfer hydrogenation of acetophenone without bases with Ru complex: Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285. (f) For asymmetric transfer hydrogenation of m-trifluoromethylacetophenone without bases: Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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For transfer hydrogenation without bases: (a) Mizushima, E.; Yamaguchi, M.; Yamagishi, T. Chem. Lett. 1997, 237. (b) Eceraere, K.; Scheffler, J.-L.; Mortreux. A.; Carpentier, J.-F. Tetrahedron Lett. 2001, 42, 1899. (c) Cadierno, V.; Crochet, P.; Diez, J.; Garcia-Garrido, S. E.; Gimeno, J. Organometallics 2004, 23, 4836. (d) Dahlenburg, L.; Götz, R. Inorg. Chim. Acta 2004, 357, 2875. (e) For asymmetric transfer hydrogenation of acetophenone without bases with Ru complex: Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285. (f) For asymmetric transfer hydrogenation of m-trifluoromethylacetophenone without bases: Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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For transfer hydrogenation without bases: (a) Mizushima, E.; Yamaguchi, M.; Yamagishi, T. Chem. Lett. 1997, 237. (b) Eceraere, K.; Scheffler, J.-L.; Mortreux. A.; Carpentier, J.-F. Tetrahedron Lett. 2001, 42, 1899. (c) Cadierno, V.; Crochet, P.; Diez, J.; Garcia-Garrido, S. E.; Gimeno, J. Organometallics 2004, 23, 4836. (d) Dahlenburg, L.; Götz, R. Inorg. Chim. Acta 2004, 357, 2875. (e) For asymmetric transfer hydrogenation of acetophenone without bases with Ru complex: Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285. (f) For asymmetric transfer hydrogenation of m-trifluoromethylacetophenone without bases: Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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For transfer hydrogenation without bases: (a) Mizushima, E.; Yamaguchi, M.; Yamagishi, T. Chem. Lett. 1997, 237. (b) Eceraere, K.; Scheffler, J.-L.; Mortreux. A.; Carpentier, J.-F. Tetrahedron Lett. 2001, 42, 1899. (c) Cadierno, V.; Crochet, P.; Diez, J.; Garcia-Garrido, S. E.; Gimeno, J. Organometallics 2004, 23, 4836. (d) Dahlenburg, L.; Götz, R. Inorg. Chim. Acta 2004, 357, 2875. (e) For asymmetric transfer hydrogenation of acetophenone without bases with Ru complex: Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285. (f) For asymmetric transfer hydrogenation of m-trifluoromethylacetophenone without bases: Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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18244381119
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note
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3). The mixture was stirred at 70°C for 30 min. To this solution was added the substrate (0.5 mmol), and the mixture was then stirred at the expected temperature. Samples were taken out of the reaction solution after the given time, passed through a column of silica, and analyzed by GC.
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